K. V. Taira, T. Crepy, and . Imamoto, Enantioselective conjugate addition of diethylzinc to cyclic enones catalyzed by copper complexes of methylene-bridged P-chirogenic diphosphines, Chirality, vol.108, issue.5, pp.386-392, 2002.
DOI : 10.1002/chir.10099

L. Feringa, Phosphoramidites:?? Marvellous Ligands in Catalytic Asymmetric Conjugate Addition, Accounts of Chemical Research, vol.33, issue.6, pp.346-353, 2000.
DOI : 10.1021/ar990084k

S. Johnson and D. A. Evans, Chiral Bis(oxazoline) Copper(II) Complexes:?? Versatile Catalysts for Enantioselective Cycloaddition, Aldol, Michael, and Carbonyl Ene Reactions, Accounts of Chemical Research, vol.33, issue.6, pp.325-335, 2000.
DOI : 10.1021/ar960062n

S. J. Mizutani, A. H. Degrado, and . Hoveyda, Cu-Catalyzed Asymmetric Conjugate Additions of Alkylzinc Reagents to Acyclic Aliphatic Enones, Journal of the American Chemical Society, vol.124, issue.5, pp.779-781, 2002.
DOI : 10.1021/ja0122849

C. G. Arena, V. Casili, and F. Faraone, New chiral amino-phosphoramidite and bisphosphoramidite ligands derived from (R,R)-1,2-diaminocyclohexane: application in Cu-catalyzed asymmetric conjugate addition of diethylzinc to 2-cyclohexenone, 41 Enones cycliques, pp.2127-2130, 2003.
DOI : 10.1016/S0957-4166(03)00447-6

A. C. Breit, P. Laungani, S. Scafato, G. Labano, C. Cunsolo et al., Copper-catalyzed enantioselective conjugate addition of dialkylzinc reagents to enones with new peptidyl phosphane ligands, Tetrahedron: Asymmetry, vol.14, issue.24, pp.3823-3826, 2003.
DOI : 10.1016/j.tetasy.2003.10.002

H. Tokunaga, Y. Ueno, T. Shimomura, and . Seo, Formation of Boroxine: Its Stability and Thermodynamic Parameters in Solution, HETEROCYCLES, vol.57, issue.5, pp.787-790, 2002.
DOI : 10.3987/COM-02-9464

T. Takaya, H. Senda, M. Kurushima, T. Ogasawara, and . Hayashi, Rhodium-catalyzed asymmetric 1,4-addition of arylboron reagents to ??,??-unsaturated esters, Tetrahedron: Asymmetry, vol.10, issue.20, pp.4047-4056, 1999.
DOI : 10.1016/S0957-4166(99)00417-6

M. Sakuma, R. Sakai, N. Itooka, and . Miyaura, )-binap, The Journal of Organic Chemistry, vol.65, issue.19, pp.5951-5955, 2000.
DOI : 10.1021/jo0002184

N. Sakuma and . Miyaura, Rhodium(I)-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to ??,??-Unsaturated Amides, The Journal of Organic Chemistry, vol.66, issue.26, pp.8944-8946, 2001.
DOI : 10.1021/jo010747n

M. Senda, T. Ogasawara, and . Hayashi, )-pyridinones. Asymmetric Synthesis of 4-Aryl-2-piperidinones, The Journal of Organic Chemistry, vol.66, issue.21, pp.6852-6856, 2001.
DOI : 10.1021/jo0103930

H. M. De-vries and B. L. Feringa, Enantioselective conjugate addition of diethylzinc to chalcone catalyzed by Co(acac)2 and chiral amino alcohols, Tetrahedron: Asymmetry, vol.8, issue.9, pp.1377-1378, 1997.
DOI : 10.1016/S0957-4166(97)00144-4

S. Kim, S. Matsugana, J. Das, A. Sekine, T. Ohshima et al., Stable, Storable, and Reusable Asymmetric Catalyst:?? A Novel La-linked-BINOL Complex for the Catalytic Asymmetric Michael Reaction, Journal of the American Chemical Society, vol.122, issue.27, pp.6506-6507, 2000.
DOI : 10.1021/ja001036u

S. Taylor and E. N. Jacobsen, Enantioselective Michael Additions to ??,??-Unsaturated Imides Catalyzed by a Salen???Al Complex, Journal of the American Chemical Society, vol.125, issue.37, pp.11204-11205, 2003.
DOI : 10.1021/ja037177o

H. Ikariya, M. Wang, and . Watanabe, Asymmetric Michael reactions of ??-substituted acetates with cyclic enones catalyzed by multifunctional chiral Ru amido complexes, Journal of Organometallic Chemistry, vol.689, issue.8, pp.1377-1381, 2004.
DOI : 10.1016/j.jorganchem.2003.12.002

M. Stafford, M. Township, . County, U. G. Brevet, F. Pawelke et al., (e) T. Chivers, Can, J. Chem. J. Organomet. Chem, vol.48, issue.178, pp.3856-3859, 1965.

J. Frohn, H. Franke, P. Fritzen, and V. V. Bardin, (Fluoroorgano)fluoroboranes and -fluoroborates I: synthesis and spectroscopic characterization of potassium fluoroaryltrifluoroborates and fluoroaryldifluoroboranes, Journal of Organometallic Chemistry, vol.598, issue.1, pp.127-135, 2000.
DOI : 10.1016/S0022-328X(99)00690-7

J. P. Heck and . Nolley, Revue : (c) I. P. Beletskaya, J. Org. Chem. A. V. Cheprakov, Chem. Rev, vol.14, issue.100, pp.2320-2322, 1972.

K. Tamao, K. Sumitani, M. J. Kumadab-)-r, J. P. Corriu, and . Masse, Selective carbon-carbon bond formation by cross-coupling of Grignard reagents with organic halides. Catalysis by nickel-phosphine complexes, Revue : (c) M. Kumada, pp.4374-4376, 1972.
DOI : 10.1021/ja00767a075

K. Miyaura, A. Yamada, T. Suzuki, and . Lett, Revues : (b), Chem. Rev. J. Organomet. Chem. Tetrahedron, vol.20, issue.58, pp.3457-3458, 1979.

E. Negishi, A. O. King, and N. Okukado, Revue : (b) E. Negishi, J. Org. Chem. Acc. Chem. Res. Tetrahedron, vol.42, issue.48, pp.1821-1823, 1977.

M. Trost and T. J. Fullerton, New synthetic reactions. Allylic alkylation, Journal of the American Chemical Society, vol.95, issue.1, pp.292-294, 1973.
DOI : 10.1021/ja00782a080

S. S. Azarian, C. Dua, D. R. Eaborn, and . Walton, Revue : (b), J. Organomet. Chem. Angew. Chem. Int. Ed. Engl, vol.129, issue.50, pp.55-55, 1976.

C. Hallberg, . Westerlind, . Chem, and . Lett, Revue : (b) Y. Hatanaka, T. Hiyama, Synlett, Pure Appl. Chem, vol.66, pp.845-853, 1982.

B. M. Trost, F. D. Toste, and A. B. Pinkerton, Non-Metathesis Ruthenium-Catalyzed C???C Bond Formation, Chemical Reviews, vol.101, issue.7, pp.2067-2096, 2001.
DOI : 10.1021/cr000666b

K. Sakai, J. Ide, O. Oda, N. Nakamura, T. Lettb et al., Synthetic studies on prostanoids 1 synthesis of methyl 9-oxoprostanoate, Tetrahedron Letters, vol.13, issue.13, pp.1287-1290, 1972.
DOI : 10.1016/S0040-4039(01)84569-X

P. Wang, S. H. Noheda, J. Bergens, B. Whelan, and . Bosnich, Revue : (e) B. Bosnich, J. Am. Chem. Soc. Acc. Chem. Res, vol.116, issue.31, pp.1821-1830, 1994.

M. Imai, K. Tanaka, Y. Tanaka, N. Yamamoto, M. Imai-ogata et al., Double-Chelation-Assisted Rh-Catalyzed Intermolecular Hydroacylation between Salicylaldehydes and 1,4-Penta- or 1,5-Hexadienes, The Journal of Organic Chemistry, vol.69, issue.4, pp.1144-1150, 2004.
DOI : 10.1021/jo035395u

T. Makino and K. Itoh, Rhodium Complex-Catalyzed Cycloisomerization of Allenenes:?? Exo and Endo Cyclization Depending on the Auxiliary Ligands, The Journal of Organic Chemistry, vol.69, issue.2, pp.395-405, 2004.
DOI : 10.1021/jo035551x

I. J. Fairlamb, Asymmetric Cycloisomerization of 1,6- and 1,7-Enynes by Transition-Metal Catalysts, Angewandte Chemie International Edition, vol.43, issue.9, pp.1048-1052, 2004.
DOI : 10.1002/anie.200301699

M. P. Yeh, W. Tsao, J. Ho, C. Tai, D. Chiou et al., Rhodium(I)-Catalyzed Intramolecular Cyclohexadienyl Pauson???Khand Reaction:?? Facile Approach to Tricarbocycles, Organometallics, vol.23, issue.4, pp.792-799, 2004.
DOI : 10.1021/om030634p

N. Jeong, Rhodium(I)-Catalyzed Asymmetric Intramolecular Pauson???Khand-Type Reaction, Journal of the American Chemical Society, vol.122, issue.28, pp.6771-6772, 2000.
DOI : 10.1021/ja0007049

M. S. Kharasch and P. O. Tawneyz, Factors Determining the Course and Mechanisms of Grignard Reactions. II. The Effect of Metallic Compounds on the Reaction between Isophorone and Methylmagnesium Bromide, Journal of the American Chemical Society, vol.63, issue.9, pp.2308-2316, 1941.
DOI : 10.1021/ja01854a005

J. Munch-petersen, Conjugate Additions of Grignard Reagents to ??,??-Unsaturated Esters, The Journal of Organic Chemistry, vol.22, issue.2, pp.170-174, 1957.
DOI : 10.1021/jo01353a021

A. Alexakis, J. Frutos, and P. Mangeney, Chiral phosphorus ligands for the asymmetric conjugate addition of organocopper reagents, Tetrahedron: Asymmetry, vol.4, issue.12, pp.2427-2430, 1993.
DOI : 10.1016/S0957-4166(00)82216-8

S. Murahashi and S. G. Davies, Alexakis, Transition Metal Catalysed Reactions, IUPAC Blackwell Science, pp.303-321, 1999.

E. Nakamura and S. Mori, Wherefore Art Thou Copper? Structures and Reaction Mechanisms of Organocuprate Clusters in Organic Chemistry, Angewandte Chemie, vol.121, issue.462, pp.3750-3771, 2000.
DOI : 10.1002/1521-3773(20001103)39:21<3750::AID-ANIE3750>3.0.CO;2-L

A. Alexakis, C. Benhaim, S. Rosset, and M. Humam, Dramatic Improvement of the Enantiomeric Excess in the Asymmetric Conjugate Addition Reaction Using New Experimental Conditions, Journal of the American Chemical Society, vol.124, issue.19, pp.5262-5263, 2002.
DOI : 10.1021/ja025598k

S. Taira, K. V. Crepy, and T. Imamoto, Enantioselective conjugate addition of diethylzinc to cyclic enones catalyzed by copper complexes of methylene-bridged P-chirogenic diphosphines, Chirality, vol.108, issue.5, pp.386-392, 2002.
DOI : 10.1002/chir.10099

B. L. Feringa, Phosphoramidites:?? Marvellous Ligands in Catalytic Asymmetric Conjugate Addition, Accounts of Chemical Research, vol.33, issue.6, pp.346-353, 2000.
DOI : 10.1021/ar990084k

J. S. Johnson and D. A. Evans, Chiral Bis(oxazoline) Copper(II) Complexes:?? Versatile Catalysts for Enantioselective Cycloaddition, Aldol, Michael, and Carbonyl Ene Reactions, Accounts of Chemical Research, vol.33, issue.6, pp.325-335, 2000.
DOI : 10.1021/ar960062n

H. Mizutani, S. J. Degrado, and A. H. Hoveyda, Cu-Catalyzed Asymmetric Conjugate Additions of Alkylzinc Reagents to Acyclic Aliphatic Enones, Journal of the American Chemical Society, vol.124, issue.5, pp.779-781, 2002.
DOI : 10.1021/ja0122849

C. G. Arena, V. Casili, F. Faraoneb-)-b, A. C. Breit, and J. H. Laungani-fu, New chiral amino-phosphoramidite and bisphosphoramidite ligands derived from (R,R)-1,2-diaminocyclohexane: application in Cu-catalyzed asymmetric conjugate addition of diethylzinc to 2-cyclohexenone, Tetrahedron: Asymmetry, vol.14, issue.15, pp.2127-2130, 2003.
DOI : 10.1016/S0957-4166(03)00447-6

P. Iuliano, S. Scafato-liang, H. Gao, Y. Wan, H. Hu et al., Application of deoxycholic acid-based copper???phosphite complexes as ligands in the enantioselective conjugate addition of diethylzinc to acyclic enones, Tetrahedron: Asymmetry, vol.14, issue.5, pp.611-618, 2003.
DOI : 10.1016/S0957-4166(03)00044-2

A. Mandoli, M. Calamante, B. L. Feringa, and P. Salvadori, An insoluble polymer-bound phosphoramidite for the copper-catalysed enantioselective 1,4-addition of ZnEt2 to 2-cyclohexenone, Tetrahedron: Asymmetry, vol.14, issue.23, pp.3647-3650, 2003.
DOI : 10.1016/j.tetasy.2003.08.004

I. J. Krauss and J. L. Leighton, Highly Practical and Enantioselective Cu-Catalyzed Conjugate Addition of Alkylzinc Reagents to Cyclic Enones at Ambient Temperature, Organic Letters, vol.5, issue.18, pp.3201-3203, 2003.
DOI : 10.1021/ol034983r

A. J. Duursma, B. L. Minaard, and . Feringa, -Amino Acids, Aldehydes, and Alcohols, Journal of the American Chemical Society, vol.125, issue.13, pp.3700-3701, 2002.
DOI : 10.1021/ja029817d
URL : https://hal.archives-ouvertes.fr/inria-00611801

S. Degrado, H. Mitzutani, and A. H. Hoveyda, Efficient Cu-Catalyzed Asymmetric Conjugate Additions of Alkylzincs to Trisubstituted Cyclic Enones, Journal of the American Chemical Society, vol.124, issue.45, pp.13362-13363, 2002.
DOI : 10.1021/ja021081x

T. Wanatabe, T. F. Knopfel, and E. M. Carreira, Asymmetric Conjugate Addition Reactions of Meldrum's Acid Derived Acceptors Employing Chiral Phosphoramidite Ligands, Organic Letters, vol.5, issue.24, pp.4557-4558, 2003.
DOI : 10.1021/ol035575q

M. Schinnerl, M. Seitz, A. Kaiser, and O. Reiser, to Carbonyl Compounds, Organic Letters, vol.3, issue.26, pp.4259-4262, 2001.
DOI : 10.1021/ol016925g

S. Degrado, H. Mizutani, and A. H. Hoveyda, Modular Peptide-Based Phosphine Ligands in Asymmetric Catalysis:?? Efficient and Enantioselective Cu-Catalyzed Conjugate Additions to Five-, Six-, and Seven-Membered Cyclic Enones, Journal of the American Chemical Society, vol.123, issue.4, pp.755-756, 1997.
DOI : 10.1021/ja003698p

M. Nakagawa, Y. Kanai, K. Nagaoka, and . Tomioka-tetrahedron, An external chiral amidophosphine ligand for asymmetric conjugate addition of organocopper, Tetrahedron, vol.54, issue.35, pp.10295-10307, 1998.
DOI : 10.1016/S0040-4020(98)00485-2

. Acad, Sciences of the USA, pp.5834-5838, 2004.

A. Alexakis and S. , Tandem Enantioselective Conjugate Addition???Cyclopropanation. Application to Natural Products Synthesis, The Journal of Organic Chemistry, vol.67, issue.25, pp.8753-8757, 2002.
DOI : 10.1021/jo026262w

L. A. Arnold, R. Naasz, A. J. Minaard, and B. L. Feringa, Methyl Ester Based on a Tandem 1,4-Addition???Aldol Reaction, The Journal of Organic Chemistry, vol.67, issue.21, pp.7244-7254, 2002.
DOI : 10.1021/jo025987x

M. Sakai, H. Hayashi, and N. Miyaura, Rhodium-Catalyzed Conjugate Addition of Aryl- or 1-Alkenylboronic Acids to Enones, Organometallics, vol.16, issue.20, pp.4229-4231, 1997.
DOI : 10.1021/om9705113

R. Itooka, Y. Iguchi, and N. Miyaura, Rhodium-Catalyzed 1,4-Addition of Arylboronic Acids to ??,??-Unsaturated Carbonyl Compounds:?? Large Accelerating Effects of Bases and Ligands, The Journal of Organic Chemistry, vol.68, issue.15, pp.6000-6004, 2003.
DOI : 10.1021/jo0207067

J. Ramnauth, O. Poulain, S. S. Bratovanov, S. Rakhit, and S. P. Maddaford, -Glycoside Formation by a Rhodium(I)-Catalyzed 1,4-Addition of Arylboronic Acids to Acetylated Enones Derived from Glycals, Organic Letters, vol.3, issue.16, pp.2571-2573, 2001.
DOI : 10.1021/ol016245d

Y. Takaya, M. Ogasawara, T. Hayashi, M. Sakai, and N. Miyaura, Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryl- and Alkenylboronic Acids to Enones, Journal of the American Chemical Society, vol.120, issue.22, pp.5579-5580, 1998.
DOI : 10.1021/ja980666h

Y. Takaya, M. Ogasawara, and T. Hayashi, Asymmetric 1,4-addition of phenylboronic acid to 2-cyclohexenone catalyzed by Rh(I)/binap complexes, Chirality, vol.393, issue.5-6, pp.469-471, 2000.
DOI : 10.1002/(SICI)1520-636X(2000)12:5/6<469::AID-CHIR29>3.0.CO;2-H

T. Hayashi, M. Takahashi, Y. Takaya, and M. Ogasawara, Catalytic Cycle of Rhodium-Catalyzed Asymmetric 1,4-Addition of Organoboronic Acids. Arylrhodium, Oxa-??-allylrhodium, and Hydroxorhodium Intermediates, Journal of the American Chemical Society, vol.124, issue.18, pp.5052-5058, 2002.
DOI : 10.1021/ja012711i

Y. Tokunaga, H. Ueno, Y. Shimomura, and T. Seo, Formation of Boroxine: Its Stability and Thermodynamic Parameters in Solution, HETEROCYCLES, vol.57, issue.5, pp.787-790, 2002.
DOI : 10.3987/COM-02-9464

Y. Takaya, T. Senda, H. Kurushima, M. Ogasawara, and T. Hayashi, Rhodium-catalyzed asymmetric 1,4-addition of arylboron reagents to ??,??-unsaturated esters, Tetrahedron: Asymmetry, vol.10, issue.20, pp.4047-4056, 1999.
DOI : 10.1016/S0957-4166(99)00417-6

S. Sakuma, M. Sakai, R. Itooka, and N. Miyaura, )-binap, The Journal of Organic Chemistry, vol.65, issue.19, pp.5951-5955, 2000.
DOI : 10.1021/jo0002184

S. Sakuma and N. Miyaura, Rhodium(I)-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to ??,??-Unsaturated Amides, The Journal of Organic Chemistry, vol.66, issue.26, pp.8944-8946, 2001.
DOI : 10.1021/jo010747n

T. Senda, M. Ogasawara, and T. Hayashi, )-pyridinones. Asymmetric Synthesis of 4-Aryl-2-piperidinones, The Journal of Organic Chemistry, vol.66, issue.21, pp.6852-6856, 2001.
DOI : 10.1021/jo0103930

T. Hayashi, T. Senda, Y. Takaya, and M. Ogasawara, Rhodium-Catalyzed Asymmetric 1,4-Addition to 1-Alkenylphosphonates, Journal of the American Chemical Society, vol.121, issue.49, pp.11591-11592, 1999.
DOI : 10.1021/ja993184u

T. Hayashi, T. Senda, and M. Ogasawara, Rhodium-Catalyzed Asymmetric Conjugate Addition of Organoboronic Acids to Nitroalkenes, Journal of the American Chemical Society, vol.122, issue.43, pp.10716-10717, 2000.
DOI : 10.1021/ja002805c

Y. Ma, C. Song, C. Ma, Z. Sun, Q. Chai et al., Asymmetric Addition of Aryl Boron Reagents to Enones with Rhodium Dicyclophane Imidazolium Carbene Catalysis, Angewandte Chemie International Edition, vol.42, issue.47, pp.5871-5874, 2003.
DOI : 10.1002/anie.200352679

T. Hayashi, K. Ueyama, N. Tokugana, and K. Yoshida, A Chiral Chelating Diene as a New Type of Chiral Ligand for Transition Metal Catalysts:?? Its Preparation and Use for the Rhodium-Catalyzed Asymmetric 1,4-Addition, Journal of the American Chemical Society, vol.125, issue.38, pp.11508-11509, 2003.
DOI : 10.1021/ja037367z

K. Yoshida, M. Ogasawara, and T. Hayashi, -Ar-9BBN) to ??,??-Unsaturated Ketones, The Journal of Organic Chemistry, vol.68, issue.5, pp.1901-1905, 2003.
DOI : 10.1021/jo020659i
URL : https://hal.archives-ouvertes.fr/hal-00908568

K. Yoshida, M. Ogasawara, and T. Hayashi, A New Type of Catalytic Tandem 1,4-Addition???Aldol Reaction Which Proceeds through an (Oxa-??-allyl)rhodium Intermediate, Journal of the American Chemical Society, vol.124, issue.37, pp.10984-10985, 2002.
DOI : 10.1021/ja0271025

D. A. Cauble, J. D. Gipson, and M. J. Krische, Diastereo- and Enantioselective Catalytic Carbometallative Aldol Cycloreduction:?? Tandem Conjugate Addition???Aldol Cyclization, Proc. Nat. Acad. Sciences of the, pp.1110-1111, 2003.
DOI : 10.1021/ja0211095

C. J. Chapman, K. J. Wadsworth, and C. G. Frost, Enantioselective rhodium-catalysed addition of boronic acids using C2-symmetric aryl diphosphite ligands, Journal of Organometallic Chemistry, vol.680, issue.1-2, pp.206-211, 2003.
DOI : 10.1016/S0022-328X(03)00349-8

A. Mori, Y. Danda, T. Fujii, K. Hirabayashi, and K. Osakada, Hydroxorhodium Complex-Catalyzed Carbon???Carbon Bond-Forming Reactions of Silanediols with ??,??-Unsaturated Carbonyl Compounds. Mizoroki-Heck-Type Reaction vs Conjugate Addition, Journal of the American Chemical Society, vol.123, issue.43, pp.10774-10775, 2001.
DOI : 10.1021/ja015928l

S. Oi, A. Taira, Y. Honma, and Y. Inoue, Asymmetric 1,4-Addition of Organosiloxanes to ??,??-Unsaturated Carbonyl Compounds Catalyzed by a Chiral Rhodium Complex, Organic Letters, vol.5, issue.1, pp.97-99, 2003.
DOI : 10.1021/ol0272904

Y. Otomaru and T. Hayashi, Rhodium-catalyzed asymmetric 1,4-addition of alkenylsilanes generated by hydrosilylation of alkynes: a one-pot procedure where a rhodium/(S)-binap complex catalyzes the two successive reactions, Tetrahedron: Asymmetry, vol.15, issue.17, pp.2647-2651, 2004.
DOI : 10.1016/j.tetasy.2004.07.003

B. Cetinkaya, M. F. Lappert, J. Mcmeeking, and D. E. Palmer, Reactions of trialkyltin acetylides with some low oxidation state transition metal complexes: Oxidative addition, oxidative cleavage, and alkynylation, Journal of Organometallic Chemistry, vol.34, issue.2, pp.37-40, 1972.
DOI : 10.1016/S0022-328X(00)88271-6

T. Hayashi, N. Tokunaga, K. Yoshida, and J. W. Han, Rhodium-Catalyzed Asymmetric 1,4-Addition of Aryltitanium Reagents Generating Chiral Titanium Enolates:?? Isolation as Silyl Enol Ethers, Journal of the American Chemical Society, vol.124, issue.41, pp.12102-12103, 2002.
DOI : 10.1021/ja027663w

K. Yoshida and T. Hayashi, -Substitution of Alkenyl Sulfones with Aryltitanium Reagents Catalyzed by Rhodium:?? Mechanistic Studies and Catalytic Asymmetric Synthesis of Allylarenes, Journal of the American Chemical Society, vol.125, issue.10, pp.2872-2873, 2003.
DOI : 10.1021/ja0295568
URL : https://hal.archives-ouvertes.fr/hal-00908568

A. Kakuuchi, T. Taguchi, and Y. Hanzawa, Rhodium-catalyzed 1,4-addition of alkenylzirconocene chlorides to electron deficient alkenes, Tetrahedron, vol.60, issue.6, pp.1293-1299, 2004.
DOI : 10.1016/j.tet.2003.08.073

W. Oppolzer, A. J. Kingma, and G. Poli, Asymmetric 1,4-additions of gilman reagents to ??,?? - disubstitoted (e)-enoylsultams / ???enolate??? protonations, Tetrahedron, vol.45, issue.2, pp.479-488, 1989.
DOI : 10.1016/0040-4020(89)80075-4

K. Oguma, M. Miura, T. Satoh, and M. Nomura, Merry-Go-Round Multiple Alkylation on Aromatic Rings via Rhodium Catalysis, Journal of the American Chemical Society, vol.122, issue.42, pp.10464-10465, 2000.
DOI : 10.1021/ja002601w

M. Lautens, A. Roy, K. Fukuoka, K. Fagnou, and B. Martin-matute, Rhodium-Catalyzed Coupling Reactions of Arylboronic Acids to Olefins in Aqueous Media, Journal of the American Chemical Society, vol.123, issue.22, pp.5358-5359, 2001.
DOI : 10.1021/ja010402m

T. Hayashi, K. Inoue, N. Taniguchi, and M. Ogasawara, Rhodium-Catalyzed Hydroarylation of Alkynes with Arylboronic Acids:?? 1,4-Shift of Rhodium from 2-Aryl-1-alkenylrhodium to 2-Alkenylarylrhodium Intermediate, Journal of the American Chemical Society, vol.123, issue.40, pp.9918-9919, 2001.
DOI : 10.1021/ja0165234

A. H. De-vries and B. L. Feringa, Enantioselective conjugate addition of diethylzinc to chalcone catalyzed by Co(acac)2 and chiral amino alcohols, Tetrahedron: Asymmetry, vol.8, issue.9, pp.1377-1378, 1997.
DOI : 10.1016/S0957-4166(97)00144-4

P. E. Tong, P. Lei, and A. S. Chan, Synthesis of N,N-dimethyl-2-amino-1,2-dicyclohexylethanol and its application in the enantioselective conjugate addition of diethylzinc to enones: a convenient upgrade of the chiral ligand via hydrogenation, Tetrahedron: Asymmetry, vol.12, issue.16, pp.2301-2304, 2001.
DOI : 10.1016/S0957-4166(01)00406-2

Y. S. Kim, S. Matsugana, J. Das, A. Sekine, T. Ohshima et al., Stable, Storable, and Reusable Asymmetric Catalyst:?? A Novel La-linked-BINOL Complex for the Catalytic Asymmetric Michael Reaction, Journal of the American Chemical Society, vol.122, issue.27, pp.6506-6507, 2000.
DOI : 10.1021/ja001036u

M. S. Taylor and E. N. Jacobsen, Enantioselective Michael Additions to ??,??-Unsaturated Imides Catalyzed by a Salen???Al Complex, Journal of the American Chemical Society, vol.125, issue.37, pp.11204-11205, 2003.
DOI : 10.1021/ja037177o

T. Ikariya, H. Wang, and M. Watanabe, Asymmetric Michael reactions of ??-substituted acetates with cyclic enones catalyzed by multifunctional chiral Ru amido complexes, Journal of Organometallic Chemistry, vol.689, issue.8, pp.1377-1381, 2004.
DOI : 10.1016/j.jorganchem.2003.12.002

S. Darses and J. Genet, Revue sur les trifluoro(organo)borates de potassium, Eur. J. Org. Chem, pp.4313-4327, 2003.

F. Pawelke, H. Heyder, . J. Bürgerg-)-d, H. Brauer, G. Bürger et al., Das bis(trifluoromethyl)-difluoroborat-anion, Journal of Organometallic Chemistry, vol.178, issue.1, pp.1-4, 1979.
DOI : 10.1016/S0022-328X(00)87855-9

E. Vedejs, R. W. Chapman, S. C. Fields, S. Lin, and M. R. Schrimpf, Conversion of Arylboronic Acids into Potassium Aryltrifluoroborates: Convenient Precursors of Arylboron Difluoride Lewis Acids, The Journal of Organic Chemistry, vol.60, issue.10, pp.3020-3027, 1995.
DOI : 10.1021/jo00115a016

S. C. Vedejs, R. Fields, S. R. Hayashi, D. R. Hitchcock, M. R. Powell et al., Asymmetric Memory at Labile, Stereogenic Boron:?? Enolate Alkylation of Oxazaborolidinones, Journal of the American Chemical Society, vol.121, issue.11, pp.2460-2470, 1999.
DOI : 10.1021/ja983555r

H. J. Frohn, H. Franke, P. Fritzen, and V. V. Bardin, (Fluoroorgano)fluoroboranes and -fluoroborates I: synthesis and spectroscopic characterization of potassium fluoroaryltrifluoroborates and fluoroaryldifluoroboranes, Journal of Organometallic Chemistry, vol.598, issue.1, pp.127-135, 2000.
DOI : 10.1016/S0022-328X(99)00690-7

T. Ohmura, Y. Yamamoto, and N. Miyaura, )-1-Alkenylboron Compounds, Journal of the American Chemical Society, vol.122, issue.20, pp.4990-4991, 2000.
DOI : 10.1021/ja0002823

G. A. Molander, C. Yun, M. Ribagorda, and B. Biolatto, -Alkyl Suzuki???Miyaura Cross-Coupling Reactions with Air-Stable Potassium Alkyltrifluoroborates, The Journal of Organic Chemistry, vol.68, issue.14, pp.5534-5539, 2004.
DOI : 10.1021/jo0343331
URL : https://hal.archives-ouvertes.fr/hal-00869890

M. Xia and Z. C. Chen, Hypervalent Iodine in Synthesis XXXIII: Palladium-Catalyzed Cross-Coupling Reaction of Potassium Aryltrifluoroborates with Diaryliodonium Salts and Hydroxy(tosyloxy)iodobenzene, Synthetic Communications, vol.29, issue.14, pp.2457-2465, 1999.
DOI : 10.1021/ja00990a023

G. A. Molander, B. W. Katona, and F. Machrouki, Development of the Suzuki???Miyaura Cross-Coupling Reaction:?? Use of Air-Stable Potassium Alkynyltrifluoroborates in Aryl Alkynylations, The Journal of Organic Chemistry, vol.67, issue.24, pp.8416-8423, 2002.
DOI : 10.1021/jo0262356

G. Zhao, X. Li, and X. Wang, Enantioselective additions of diphenylzinc to aldehydes using chiral pyrrolidinylmethanol derivatives as catalysts, Tetrahedron: Asymmetry, vol.12, issue.3, pp.399-403, 2001.
DOI : 10.1016/S0957-4166(01)00074-X

A. Lightfoot, P. Schnider, and A. Pflatz, Enantioselective Hydrogenation of Olefins with Iridium-Phosphanodihydrooxazole Catalysts, Angewandte Chemie International Edition, vol.37, issue.20, pp.2897-2899, 1998.
DOI : 10.1002/(SICI)1521-3773(19981102)37:20<2897::AID-ANIE2897>3.0.CO;2-8

A. Miyashita, A. Yasuda, H. Takaya, K. Toriumi, T. Ito et al., Synthesis of 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (BINAP), an atropisomeric chiral bis(triaryl)phosphine, and its use in the rhodium(I)-catalyzed asymmetric hydrogenation of .alpha.-(acylamino)acrylic acids, Journal of the American Chemical Society, vol.102, issue.27, pp.7932-7934, 1980.
DOI : 10.1021/ja00547a020

R. Schmid, M. Cereghtti, B. Heiser, P. Schonholzer, H. Hansen et al., -diethylnerylamine, Helvetica Chimica Acta, vol.27, issue.4, pp.897-901, 1988.
DOI : 10.1002/hlca.19880710427
URL : https://hal.archives-ouvertes.fr/hal-00707648

M. J. Burk, J. E. Feaster, W. A. Nugent, and R. L. Harlow, Preparation and use of C2-symmetric bis(phospholanes): production of .alpha.-amino acid derivatives via highly enantioselective hydrogenation reactions, Journal of the American Chemical Society, vol.115, issue.22, pp.10125-10127, 1993.
DOI : 10.1021/ja00075a031

F. Robin, F. Mercier, L. Ricard, and F. Mathey, BIPNOR: A New, Efficient Bisphosphine Having Two Chiral, Nonracemizable, Bridgehead Phosphorus Centers for Use in Asymmetric Catalysis, Chemistry - A European Journal, vol.50, issue.8, pp.1365-1370, 1997.
DOI : 10.1002/chem.19970030824

A. Marinetti, S. Jus, J. Genet, and L. Ricard, Chiral 1,2-bis(phosphetano)ethanes, Journal of Organometallic Chemistry, vol.624, issue.1-2, pp.162-166, 2001.
DOI : 10.1016/S0022-328X(00)00910-4

H. B. Kagan and T. P. Dang, Brevet français pour l'IFP; FR7044632, 1970.

G. Michaud, M. Buillard, L. Ricard, J. Genet, and A. Marinetti, A Strategy for the Stereoselective Synthesis of Unsymmetric Atropisomeric Ligands: Preparation of NAPhePHOS, a New Biaryl Diphosphine, Chemistry - A European Journal, vol.8, issue.15, pp.3327-3330, 2002.
DOI : 10.1002/1521-3765(20020802)8:15<3327::AID-CHEM3327>3.0.CO;2-F

J. M. Brown, P. A. Chalonner, A. G. Kent, B. A. Murrer, P. N. Nicholson et al., The mechanism of asymmetric homogeneous hydrogenation. Solvent complexes and dihydrides from rhodium diphosphine precursors, Journal of Organometallic Chemistry, vol.216, issue.2, pp.263-276, 1981.
DOI : 10.1016/S0022-328X(00)85766-6

D. Heller, H. Drexler, A. Spannenberg, B. Heller, J. You et al., The Inhibiting Influence of Aromatic Solvents on the Activity of Asymmetric Hydrogenations We would like to thank the Deutsche Forschungsgemeinschaft as well as the Fonds der Chemischen Industrie for their generous support of this work. We are also indebted to Prof. Dr. U. Rosenthal and Dr. D. Selent for helpful discussions. Franz Hein prepared bis(??6-arene)-chromium(I)-complex cations already in 1919; their true structure as hexahapto complexes was only realized more than 35 years later., Angewandte Chemie International Edition, vol.41, issue.5, pp.777-780, 2002.
DOI : 10.1002/1521-3773(20020301)41:5<777::AID-ANIE777>3.0.CO;2-7

H. Stephen and T. , Stephen in Solubilities of inorganic and organic compounds, p.476, 1963.

C. Hansch, A. Leo, and R. W. Taft, Revue : (b), P. Hammett, J. Am. Chem. Soc. Chem. Rev, vol.59, issue.91, pp.96-103, 1937.

J. T. Romeo, L. A. Swain, and A. B. Bleeker, Cis-4-hydroxypipecolic acid and 2,4-cis-4,5-trans-4,5-dihydroxypipecolic acid from Calliandra, Phytochemistry, vol.22, issue.7, pp.1615-1617, 1983.
DOI : 10.1016/0031-9422(83)80098-3

P. L. Beaulieu, P. Lavallée, A. Abraham, P. C. Anderson, C. Boucher et al., Practical, Stereoselective Synthesis of Palinavir, a Potent HIV Protease Inhibitor, The Journal of Organic Chemistry, vol.62, issue.11, pp.3440-3448, 1997.
DOI : 10.1021/jo9702655

C. Nicolaou, T. Montagnon, P. S. Baran, and Y. Zhong, -Iodoxybenzoic Acid as a Chemospecific Tool for Single Electron Transfer-Based Oxidation Processes, Journal of the American Chemical Society, vol.124, issue.10, pp.2245-2258, 2002.
DOI : 10.1021/ja012127+
URL : https://hal.archives-ouvertes.fr/hal-00609055

F. Picard, E. Baston, W. Reichert, and R. W. Hartmann, Synthesis of N-substituted piperidine-4-(benzylidene-4-carboxylic acids) and evaluation as inhibitors of steroid-5??-reductase type 1 and 2, Bioorganic & Medicinal Chemistry, vol.8, issue.6, pp.1479-1487, 2000.
DOI : 10.1016/S0968-0896(00)00070-5

D. H. Hua, F. Zhang, J. Chen, and P. D. Robinson, Condensation of Lactams with 2-Aminoacetylaldehyde Diethyl Acetal. A One-Pot Synthesis of Bicyclic Imidazoles, The Journal of Organic Chemistry, vol.59, issue.17, pp.5084-5087, 1994.
DOI : 10.1021/jo00096a066

V. N. Goka, G. Schlewer, J. M. Linget, J. Chambon, and C. G. Wermuth, GABA-uptake inhibitors: construction of a general pharmacophore model and successful prediction of a new representative, Journal of Medicinal Chemistry, vol.34, issue.8, pp.2547-2561, 1991.
DOI : 10.1021/jm00112a032

H. Olpe, H. Demieville, W. L. Baltzer, W. Koella, P. Wolf et al., The biological activity of d-baclofen (Lipresal??), European Journal of Pharmacology, vol.52, issue.1, pp.133-137, 1978.
DOI : 10.1016/0014-2999(78)90032-8

V. V. Thakur, D. Nikalje, and A. Sudalai, Enantioselective synthesis of (R)-(???)-baclofen via Ru(II)???BINAP catalyzed asymmetric hydrogenation, Tetrahedron: Asymmetry, vol.14, issue.5, pp.581-586, 2003.
DOI : 10.1016/S0957-4166(03)00024-7

I. Baussane, C. Travers, and J. Royer, Asymmetric synthesis of 3-substituted pyrrolidones via ??-alkylation of a chiral non-racemic ??-lactam, Tetrahedron: Asymmetry, vol.9, issue.5, pp.797-804, 1998.
DOI : 10.1016/S0957-4166(98)00024-X

B. M. Trost and G. Dake, Nitrogen Pronucleophiles in the Phosphine-Catalyzed ??-Addition Reaction, The Journal of Organic Chemistry, vol.62, issue.17, pp.5670-5671, 1997.
DOI : 10.1021/jo970848e

K. Itoh and S. Kanemasa, Enantioselective Michael Additions of Nitromethane by a Catalytic Double Activation Method Using Chiral Lewis Acid and Achiral Amine Catalysts, Journal of the American Chemical Society, vol.124, issue.45, pp.13394-13395, 2002.
DOI : 10.1021/ja027313+

D. M. Barnes, J. Ji, M. G. Fickes, M. A. Fitzgerald, S. A. King et al., . Scope, Mechanism, and Further Application to the Synthesis of the Antidepressant Rolipram, Journal of the American Chemical Society, vol.124, issue.44, pp.13097-13105, 2002.
DOI : 10.1021/ja026788y

J. Barluenga, M. A. Fernandez-rodriguez, E. Aguilar, F. Fernandez-mari, A. Salinas et al., First Highly Regio- and Diastereoselective [3+2] Cycloaddition of Chiral Nonracemic Fischer Carbene Complexes with Azomethine Ylides: An Enantioselective Synthesis of (+)-Rolipram, Chemistry - A European Journal, vol.7, issue.16, pp.3533-3544, 2001.
DOI : 10.1002/1521-3765(20010817)7:16<3533::AID-CHEM3533>3.0.CO;2-E

E. J. Corey and C. J. Helal, Reduction of Carbonyl Compounds with Chiral Oxazaborolidine Catalysts: A New Paradigm for Enantioselective Catalysis and a Powerful New Synthetic Method, Angewandte Chemie International Edition, vol.37, issue.15, pp.1986-2012, 1998.
DOI : 10.1002/(SICI)1521-3773(19980817)37:15<1986::AID-ANIE1986>3.0.CO;2-Z

M. Kitamura, S. Suga, K. Kawai, and R. Noyori, Catalytic asymmetric induction. Highly enantioselective addition of dialkylzincs to aldehydes, Journal of the American Chemical Society, vol.108, issue.19, pp.6071-6072, 1986.
DOI : 10.1021/ja00279a083

C. Bolm, J. P. Hildebrand, K. Muñiz, and N. Hermanns, Catalyzed Asymmetric Arylation Reactions, Angewandte Chemie International Edition, vol.127, issue.18, pp.3284-3308, 2001.
DOI : 10.1002/1521-3773(20010917)40:18<3284::AID-ANIE3284>3.0.CO;2-U

C. Bolm, M. Kesselgruber, N. Hermanns, J. P. Hildebrand, and G. Raabe, Application of a Planar Chiral??5-Cyclopentadienylrhenium(I)tricarbonyl Complex in Asymmetric Catalysis: Highly Enantioselective Phenyl Transfer to Aldehydes, Angewandte Chemie International Edition, vol.92, issue.8, pp.1488-1490, 2001.
DOI : 10.1002/1521-3773(20010417)40:8<1488::AID-ANIE1488>3.0.CO;2-B

C. Bolm and J. Rudolph, Catalyzed Asymmetric Aryl Transfer Reactions to Aldehydes with Boronic Acids as Aryl Source, Journal of the American Chemical Society, vol.124, issue.50, pp.14850-14851, 2002.
DOI : 10.1021/ja028518l

). S. Kobayashi, H. Ishitani, S. Dahmen, S. Bräse, C. Wei et al., Réactions organocatalysées : (c), Chem. Rev. J. Am. Chem. Soc. J. Am. Chem. Soc, vol.99, issue.125, pp.1069-1094, 1999.

J. Li, H. Am, K. Fujihara, K. Nagai, ). Tomiokag et al., Réactions catalysées par des complexes du zirconium : (h), Chem. Soc. J. Am. Chem. Soc. J. Org. Chem. J. Am. Chem. Soc. J. Am. Chem. Soc, vol.124, issue.123, pp.5638-5639, 2000.

P. I. Dosa and G. C. Fu, to Ketones:?? Enantioselective Formation of Quaternary Stereocenters, Journal of the American Chemical Society, vol.120, issue.2, pp.445-446, 1998.
DOI : 10.1021/ja973169u

M. Sakai, M. Ueda, and N. Miyaura, Rhodium-Catalyzed Addition of Organoboronic Acids to Aldehydes, Angewandte Chemie International Edition, vol.37, issue.23, pp.3279-3281, 1998.
DOI : 10.1002/(SICI)1521-3773(19981217)37:23<3279::AID-ANIE3279>3.0.CO;2-M

M. Ueda and N. Miyaura, -butyl)phosphine in the Rhodium-Catalyzed Addition of Arylboronic Acids to Aldehydes, The Journal of Organic Chemistry, vol.65, issue.14, pp.4450-4452, 2000.
DOI : 10.1021/jo000187c
URL : https://hal.archives-ouvertes.fr/in2p3-00932021

S. Oi, M. Moro, H. Fukuhara, T. Kawanashi, and Y. Inoue, Rhodium-catalyzed addition of arylstannanes to carbon???heteroatom double bond, Tetrahedron, vol.59, issue.24, pp.4351-4361, 2003.
DOI : 10.1016/S0040-4020(03)00586-6

S. Oi, M. Moro, and Y. Inoue, Rhodium-Catalyzed Addition of Phenylmethyldifluorosilane to Aldehydes, Organometallics, vol.20, issue.6, pp.1036-1037, 2001.
DOI : 10.1021/om0009684

T. Hayashi and M. Ishegedani, Rhodium-Catalyzed Asymmetric Arylation of Imines with Organostannanes. Asymmetric Synthesis of Diarylmethylamines, Journal of the American Chemical Society, vol.122, issue.5, pp.976-977, 2000.
DOI : 10.1021/ja9927220

T. Hayashi and M. Ishegedani, Rhodium-catalyzed asymmetric arylation of ??,??-unsaturated imines with arylstannanes. Catalytic asymmetric synthesis of allylic amines, Tetrahedron, vol.57, issue.13, pp.2589-2595, 2001.
DOI : 10.1016/S0040-4020(01)00075-8

A. R. Chianese, X. Li, M. C. Janzen, J. W. Faller, and R. H. Crabtree, Rhodium and Iridium Complexes of N-Heterocyclic Carbenes via Transmetalation:?? Structure and Dynamics, Organometallics, vol.22, issue.8, pp.1663-1667, 2003.
DOI : 10.1021/om021029+

C. J. Li and Y. Meng, Grignard-Type Carbonyl Phenylation in Water and under an Air Atmosphere, Journal of the American Chemical Society, vol.122, issue.39, pp.9538-9539, 2000.
DOI : 10.1021/ja001699b

S. Gladiali, A. Dore, D. Fabbri, O. De-lucchi, and M. Manassero, Novel atropisomeric phosphorus ligands: 4,5-dihydro-3H-dinaphtho[2,1-c;1???,2???-e]phosphepine derivatives, Tetrahedron: Asymmetry, vol.5, issue.4, pp.511-521, 1994.
DOI : 10.1016/0957-4166(94)80005-7

V. V. Grushin and J. , Catalysis for Catalysis:?? Synthesis of Mixed Phosphine???Phosphine Oxide Ligands via Highly Selective, Pd-Catalyzed Monooxidation of Bidentate Phosphines, Journal of the American Chemical Society, vol.121, issue.24, pp.5831-5832, 1999.
DOI : 10.1021/ja990841+

R. Hulst, N. Koen-de-vries, and B. L. Feringa, ??-Phenylethylamine based chiral phospholidines; new agents for the determination of the enantiomeric excess of chiral alcohols, amines and thiols by means of 31P NMR, Tetrahedron: Asymmetry, vol.5, issue.4, pp.699-711, 1994.
DOI : 10.1016/0957-4166(94)80032-4

J. W. Labadie and J. K. Stille, Mechanisms of the palladium-catalyzed couplings of acid chlorides with organotin reagents, Journal of the American Chemical Society, vol.105, issue.19, pp.6129-6137, 1983.
DOI : 10.1021/ja00357a026

N. A. Burmagin, D. N. Korolev, T. Lett, M. Haddach, J. R. Mccarthy et al., Synthesis of unsymmetric ketones via ligandless Pd-catalyzed reaction of acyl chlorides with organoboranes, Tetrahedron Letters, vol.40, issue.15, pp.3057-3060, 1999.
DOI : 10.1016/S0040-4039(99)00364-0

I. Pérez, J. Pérez-sestelo, and L. A. Sarandeses, Atom-Efficient Metal-Catalyzed Cross-Coupling Reaction of Indium Organometallics with Organic Electrophiles, Journal of the American Chemical Society, vol.123, issue.18, pp.4155-4160, 2001.
DOI : 10.1021/ja004195m

L. S. Liebeskind and J. Sorgl, Thiol Ester???Boronic Acid Coupling. A Mechanistically Unprecedented and General Ketone Synthesis, Journal of the American Chemical Society, vol.122, issue.45, pp.11260-11261, 2000.
DOI : 10.1021/ja005613q

J. K. Stille, The Palladium-Catalyzed Cross-Coupling Reactions of Organotin Reagents with Organic Electrophiles[New Synthetic Methods(58)], Angewandte Chemie International Edition in English, vol.25, issue.6, pp.508-524, 1986.
DOI : 10.1002/anie.198605081

P. Knochel, M. C. Yeh, S. C. Berk, and J. Talbert, Synthesis and reactivity toward acyl chlorides and enones of the new highly functionalized copper reagents RCu(CN)ZnI, The Journal of Organic Chemistry, vol.53, issue.10, pp.2390-2392, 1988.
DOI : 10.1021/jo00245a057

C. Duplais, F. Bures, I. Sapountzis, T. J. Korn, G. Cahiez et al., An Efficient Synthesis of Diaryl Ketones by Iron-Catalyzed Arylation of Aroyl Cyanides, Angewandte Chemie International Edition, vol.43, issue.22, pp.2968-2970, 2004.
DOI : 10.1002/anie.200453696

I. Kazmierski, M. Bastienne, C. Gosmini, J. M. Paris, and J. Périchon, Convenient Processes for the Synthesis of Aromatic Ketones from Aryl Bromides and Carboxylic Anhydrides Using a Cobalt Catalysis, The Journal of Organic Chemistry, vol.69, issue.3, pp.936-942, 2004.
DOI : 10.1021/jo0352169

K. Oguma, M. Miura, T. Satoh, and M. Nomura, Rhodium-catalyzed coupling of sodium tetraphenylborate with acid anhydrides in the presence or absence of norbornene, Journal of Organometallic Chemistry, vol.648, issue.1-2, pp.297-301, 2002.
DOI : 10.1016/S0022-328X(01)01439-5

A. C. Echavarren and J. K. Stille, Palladium-catalyzed carbonylative coupling of aryl triflates with organostannanes, Journal of the American Chemical Society, vol.110, issue.5, pp.1557-1565, 1988.
DOI : 10.1021/ja00213a032

S. Kang, H. Ryu, and S. Lee, Preparation of triarylantimony(V) diacetates and palladium-catalyzed cross-coupling and carbonylative cross-coupling of triarylantimony(V) diacetates and dichlorides with organostannanes, Journal of Organometallic Chemistry, vol.610, issue.1-2, pp.38-41, 2000.
DOI : 10.1016/S0022-328X(00)00386-7

E. Moreira and G. Ortar, A concise synthesis of photoactivatable 4-Aroyl-l-phenylalanines, Bioorganic & Medicinal Chemistry Letters, vol.10, issue.16, pp.1815-1818, 2000.
DOI : 10.1016/S0960-894X(00)00344-9

T. Ishiyama, H. Kizaki, T. Hayashi, A. Suzuki, and N. Miyaura, Palladium-Catalyzed Carbonylative Cross-Coupling Reaction of Arylboronic Acids with Aryl Electrophiles:?? Synthesis of Biaryl Ketones, The Journal of Organic Chemistry, vol.63, issue.14, pp.4726-4731, 1998.
DOI : 10.1021/jo980417b

M. Ishikura and M. Terashima, Palladium-Catalyzed Carbonylative Cross-Coupling Reaction with Triethyl(1-methylindol-2-yl)borate: A Simple Route to 1-Methyl-2-indolyl Ketones, The Journal of Organic Chemistry, vol.59, issue.9, pp.2634-2637, 1994.
DOI : 10.1021/jo00088a060

T. Ohe, S. Motosufa, K. Ohe, and S. Uemura, Palladium(II)- and Rhodium(III)-Catalyzed Carbonylation Reaction of Aryltin Compounds, Bulletin of the Chemical Society of Japan, vol.74, issue.7, pp.1343-1348, 2001.
DOI : 10.1246/bcsj.74.1343

R. C. Larock and S. S. Hershberger, Mercury in organic chemistry. 18. Synthesis of symmetrical divinyl and diaryl ketones via rhodium-catalyzed carbonylation of vinyl- and arylmercurials, The Journal of Organic Chemistry, vol.45, issue.19, pp.3840-3846, 1980.
DOI : 10.1021/jo01307a022

K. K. Majumdar and C. Cheng, Ni(II)/Zn-Mediated Chemoselective Arylation of Aromatic Aldehydes:??? Facile Synthesis of Diaryl Carbinols, Organic Letters, vol.2, issue.15, pp.2295-2298, 2000.
DOI : 10.1021/ol006064w

Y. Huang, K. K. Majumdar, and C. Cheng, Nickel-Catalyzed Coupling of Aryl Iodides with Aromatic Aldehydes:?? Chemoselective Synthesis of Ketones, The Journal of Organic Chemistry, vol.67, issue.5, pp.1682-1684, 2002.
DOI : 10.1021/jo010289i

T. Ishiyama and J. Hartwig, -Pyrazyl Aldimines, Journal of the American Chemical Society, vol.122, issue.48, pp.12043-12044, 2000.
DOI : 10.1021/ja003306e
URL : https://hal.archives-ouvertes.fr/in2p3-00842900

C. Krug and J. F. Hartwig, Direct Observation of Aldehyde Insertion into Rhodium???Aryl and ???Alkoxide Complexes, Journal of the American Chemical Society, vol.124, issue.8, pp.1674-1679, 2002.
DOI : 10.1021/ja017401e

K. P. Vora, C. F. Lochow, R. G. Miller, B. Bosnich, and D. P. Fairlie, Rhodium catalyzed hydroacylation of ethylene with 4-pentenals. reactions of 4-hexenal-1-d, Journal of Organometallic Chemistry, vol.192, issue.2, pp.257-264, 1980.
DOI : 10.1016/S0022-328X(00)94430-9

A. W. Burgstahler, D. E. Walker, J. P. Kuebich, and R. L. Schowen, Synthesis of benzaldehyde-formyl-d from benzil, The Journal of Organic Chemistry, vol.37, issue.8, pp.1272-1273, 1972.
DOI : 10.1021/jo00973a048

R. Noyori, Asymmetric Catalysis: Science and Opportunities (Nobel Lecture 2001), Advanced Synthesis & Catalysis, vol.345, issue.12, pp.15-32, 2003.
DOI : 10.1002/adsc.200390002

O. N. Ed, J. Chapman, and . Shorter, Exner dans Correlation Analysis in Chemistry, 1978.

T. Morimoto and K. Kakiuchi, Evolution of Carbonylation Catalysis: No Need for Carbon Monoxide, Angewandte Chemie International Edition, vol.5, issue.42, pp.5580-5588, 2004.
DOI : 10.1002/anie.200301736

D. D. Perrin and W. L. , Armarego Purification of laboratory chemicals 3 rd Ed, 1988.

W. C. Still, M. Khan, and A. Mitra, Rapid chromatographic technique for preparative separations with moderate resolution, The Journal of Organic Chemistry, vol.43, issue.14, pp.2923-2928, 1978.
DOI : 10.1021/jo00408a041

C. S. Cho, S. Motofusa, K. Ohe, S. Uemura, and S. C. Shim, A New Catalytic Activity of Antimony(III) Chloride in Palladium(0)-Catalyzed Conjugate Addition of Aromatics to .alpha.,.beta.-Unsaturated Ketones and Aldehydes with Sodium Tetraphenylborate and Arylboronic Acids, The Journal of Organic Chemistry, vol.60, issue.4, pp.883-888, 1995.
DOI : 10.1021/jo00109a019

M. Balasabramanian and A. D. Souza, Dipole moments of some substituted cyclohexanones, Tetrahedron, vol.25, issue.15, pp.2973-2978, 1969.
DOI : 10.1016/S0040-4020(01)82830-1

D. P. Provencal and J. W. Leahy, Convenient Construction of Cyclopentanones via "Cyclopentannulation" of Carbonyls, The Journal of Organic Chemistry, vol.59, issue.18, pp.5496-5498, 1994.
DOI : 10.1021/jo00097a070

T. Shono, N. Kise, N. Uemuara, S. Moritomo, and E. Okazaki, Electroorganic chemistry. 124. Electroreductive intramolecular coupling of .alpha.-(.omega.-bromoalkyl) .beta.-keto esters, The Journal of Organic Chemistry, vol.55, issue.17, pp.5037-5041, 1990.
DOI : 10.1021/jo00304a014

S. Oi, M. Moro, H. Ito, Y. Honna, S. Migano et al., Rhodium-catalyzed conjugate addition of aryl- and alkenyl-stannanes to ??,??-unsaturated carbonyl compounds, Tetrahedron, vol.58, issue.1, pp.91-98, 2002.
DOI : 10.1016/S0040-4020(01)01128-0

P. Guerry and R. Neier, Reduktion von 4-Pyridinonen, Synthesis, vol.1984, issue.06, pp.485-487
DOI : 10.1055/s-1984-30874

A. P. Kozikowski and P. Park, Synthesis of streptazolin: use of the aza-Ferrier reaction in conjunction with the INOC process to deliver a unique but sensitive natural product, The Journal of Organic Chemistry, vol.55, issue.15, pp.4668-4682, 1990.
DOI : 10.1021/jo00302a036

H. J. Reich, Organoselenium chemistry. Conversion of ketones to enones by selenoxide syn elimination, Journal of the American Chemical Society, vol.97, issue.19, pp.5434-5447, 1975.
DOI : 10.1021/ja00852a019

O. Tsuge, S. Kanemasa, A. Hatado, and K. Matsuda, -Protonated Azomethine Ylides of Nonstabilized Type and Fluoride-Induced Generation of 2-Azaallyl Anions, Bulletin of the Chemical Society of Japan, vol.59, issue.8, pp.2537-2546, 1986.
DOI : 10.1246/bcsj.59.2537

P. Resende, W. P. Almeid-a, and F. Coelho, An efficient synthesis of (R)-(???)-baclofen, Tetrahedron: Asymmetry, vol.10, issue.11, pp.2113-2118, 1999.
DOI : 10.1016/S0957-4166(99)00235-9

J. H. Hall, F. E. Behr, and R. L. Reed, Cyclization of 2-azidobenzophenones to 3-phenylanthranils. Examples of an intramolecular 1,3-dipolar addition, Journal of the American Chemical Society, vol.94, issue.14, pp.4952-4958, 1972.
DOI : 10.1021/ja00769a027

J. Kim, M. A. Bogdan, and P. S. Mariano, Mechanistic analysis of the 3-methyllumiflavin-promoted oxidative deamination of benzylamine. A potential model for monoamine oxidase catalysis, Journal of the American Chemical Society, vol.115, issue.23, pp.10591-10595, 1993.
DOI : 10.1021/ja00076a017

M. S. Syamala, B. Nageswer-rao, and V. Ramamurthy, Modification of photochemical reactivity by cyclodextrin complexalion: product selectivity in photo-fries rearrangement, Tetrahedron, vol.44, issue.23, pp.7234-7242, 1988.
DOI : 10.1016/S0040-4020(01)86094-4