S. C. Bergmeier, The Synthesis of Vicinal Amino Alcohols, Tetrahedron, vol.56, issue.17, pp.2561-2576, 1996.
DOI : 10.1016/S0040-4020(00)00149-6

N. Okamoto, O. Hara, K. Makino, and Y. Hamada, Diastereoselective Synthesis of All Stereoisomers of ??-Methoxytyrosine, a Component of Papuamides, The Journal of Organic Chemistry, vol.67, issue.26, pp.9210-9213, 2002.
DOI : 10.1021/jo0258352

K. Umezawa, Y. Nakazawa, H. Ikeda, S. Naganawa, and . Kondo, )-3-Hydroxy-3-methylproline, The Journal of Organic Chemistry, vol.64, issue.9, pp.3034-3038, 1999.
DOI : 10.1021/jo981512n

J. C. Panek and C. E. Masse-angew, Total Synthesis of (+)-Lactacystin, Angewandte Chemie International Edition, vol.38, issue.8, pp.1093-1095, 1999.
DOI : 10.1002/(SICI)1521-3773(19990419)38:8<1093::AID-ANIE1093>3.0.CO;2-U

P. Labeeuw, J. P. Phansavath, and . Genet, Total synthesis of sulfobacin A through dynamic kinetic resolution of a racemic ??-keto-??-amino ester hydrochloride, et références citées, pp.1899-1908, 2004.
DOI : 10.1016/j.tetasy.2004.05.004

E. Merino, S. Castillo, F. L. Franco, and T. Merchan, Nucleophilic additions of Grignard reagents to N-benzyl-2,3-O-isopropylidene-D-glyceraldehyde nitrone (BIGN). Synthesis of (2S,3R) and (2S,3S)-3-phenylisoserine, Tetrahedron, vol.54, issue.40, pp.12301-12322, 1998.
DOI : 10.1016/S0040-4020(98)00741-8

J. Kudyba, J. Raczko, and . Jurczak, )-8-Phenylmenthyl Glyoxylate, The Journal of Organic Chemistry, vol.69, issue.8, pp.2844-2850, 2004.
DOI : 10.1021/jo0358269

H. Lee, J. Yoon, S. H. Chung, and Y. S. Lee, Efficient asymmetric synthesis of 2,3-diamino-3-phenylpropanoic acid derivatives, Tetrahedron, vol.57, issue.11, pp.2139-2145, 2001.
DOI : 10.1016/S0040-4020(01)00090-4

M. Wang, H. C. Kolb, and K. B. Sharpless, Large-Scale and Highly Enantioselective Synthesis of the Taxol C-13 Side Chain through Asymmetric Dihydroxylation, The Journal of Organic Chemistry, vol.59, issue.17, pp.5104-5105, 1994.
DOI : 10.1021/jo00096a072

M. Pasto, A. Moyano, A. Pericas, and A. , Riera Tetrahedron: Asymmetry, pp.243-262, 1994.

V. A. Hamamoto, M. Mamedov, N. Kitamoto, S. Hayashi, and . Tsuboi, Chemoenzymatic synthesis of the C-13 side chain of paclitaxel (Taxol) and docetaxel (Taxotere), Tetrahedron: Asymmetry, vol.11, issue.22, pp.4485-4497, 2000.
DOI : 10.1016/S0957-4166(00)00418-3

G. Cardillo, L. Gentilucci, A. Tolomelli, and C. Tomasini, -Benzoylphenylisoserine Methyl Ester, The Journal of Organic Chemistry, vol.63, issue.7, pp.2351-2353, 1996.
DOI : 10.1021/jo9714066
URL : https://hal.archives-ouvertes.fr/tel-00010477

D. Cabon, M. Buisson, R. Larcheveque, and . Azerad, Stereospecific preparation of glycidic esters from 2-chloro-3-hydroxyesters. Application to the synthesis of (2R,3S)-3-phenylisoserine, Tetrahedron: Asymmetry, vol.6, issue.9, pp.2211-2218, 1995.
DOI : 10.1016/0957-4166(95)00295-Z

2. Hz and 3. , 1.7-2.0 (m, 1H, H g ), 1.44 (s, 9H, pp.3-5390

H. Chiralcel and O. , 95:5 hexane:iso-propanol, 1.0 mL/min, l = 254 nm, t R (S) 14

H. , H. Im, 2. , and H. , 49 (m, 1H, H r ), 3.26-3.39 (m, 2H, H r' and H e ), 3.24 (s, 3H, H n ), 3.18-3.21 (m, 1H, pp.63-66

H. , H. Im, 1. , 2. , 1. et al., 36 (s, 3H, H v ), 3.24 (s, 3H, H n ), 3.24-3.44 (m, 4H, H r and H e ), 2.69 (s, 3H, pp.63-67

M. Breuer, K. Ditrich, T. Habicher, B. Hauer, M. Kesseler et al., Industrial Methods for the Production of Optically Active Intermediates, Angewandte Chemie International Edition, vol.43, issue.7, pp.788-824, 2004.
DOI : 10.1002/anie.200300599

N. Asymmetric, C. In-organic, . Synthesis, E. N. Wiley, A. Jacobsen et al., Yamamoto Comprehensive Asymmetric Catalysis I-III, Springler: New York, 1999. c) I. Ojima Catalytic Asymmetric Synthesis, 1994.

K. Stecher, Faber Synthesis 1997, 1-16. e) V. Ratovelomanana-Vidal, J.P. Genet Can. J. Chem. Pellissier Tetrahedron, vol.78, issue.59, pp.846-851, 2000.

K. Koh, R. N. Ben, and T. Durst, Reaction of (R)-pantolactone esters of alpha-bromoacids with amines a remarkable synthesis of optically active alpha-amino esters, Tetrahedron Letters, vol.34, issue.28, pp.4473-4476, 1993.
DOI : 10.1016/0040-4039(93)88062-N

R. N. Ben and T. Durst, Synthesis of Optically Active ??-Amino Esters via Dynamic Kinetic Resolution:?? A Mechanistic Study, The Journal of Organic Chemistry, vol.64, issue.21, pp.7700-7706, 1999.
DOI : 10.1021/jo9811625

P. Camps, F. Perez, and N. Soldevilla, (R)- and (S)-3-hydroxy-4,4-dimethyl-1-phenyl-2-pyrrolidinone as chiral auxiliaries for the asymmetric synthesis of ??-hydroxy acids, Tetrahedron: Asymmetry, vol.8, issue.11, pp.1877-1894, 1997.
DOI : 10.1016/S0957-4166(97)00176-6

P. Camps, F. Perez, N. Soldevilla, and M. Borrego, (R)- and (S)-3-Hydroxy-4,4-dimethyl-1-phenyl-2-pyrrolidinone as chiral auxiliaries in the enantioselective preparation of ??-amino acids, Tetrahedron: Asymmetry, vol.10, issue.3, pp.493-509, 1999.
DOI : 10.1016/S0957-4166(99)00018-X

H. Kubo, M. Kubota, K. Takahashi, and . Nunami, Dynamic Kinetic Resolution Utilizing 2-Oxoimidazolidine-4-carboxylate as a Chiral Auxiliary:?? Stereoselective Alkylation of ??-Bromo Amides with Malonic Ester Enolates, The Journal of Organic Chemistry, vol.62, issue.17, pp.5830-5837, 1997.
DOI : 10.1021/jo970484q

G. Santos, S. X. Candeias, C. A. Afonso, K. Jenkins, S. Caddick et al., Rationalising diastereoselection in the dynamic kinetic resolution of ??-haloacyl imidazolidinones: a theoretical approach, Tetrahedron, vol.57, issue.30, pp.6607-6614, 2001.
DOI : 10.1016/S0040-4020(01)00551-8

H. Nozaki, T. Aratani, T. Toraya, and R. Noyori, Asymmetric syntheses by means of (???)-sparteine modified organometallic reagents, Tetrahedron, vol.27, issue.5, pp.905-913, 1971.
DOI : 10.1016/S0040-4020(01)92490-1

M. Schlosser and D. Limat, Sparteine-mediated .alpha.-lithiation of N-BOC-N-methylbenzylamine: Rapid racemization and subsequent deracemization., Journal of the American Chemical Society, vol.117, issue.49, pp.12342-12343, 1995.
DOI : 10.1021/ja00154a040

S. Thayumanavan, A. Basu, and P. , -ethylaniline, Journal of the American Chemical Society, vol.119, issue.35, pp.8209-8216, 1997.
DOI : 10.1021/ja970930r
URL : https://hal.archives-ouvertes.fr/hal-00987476

T. Wolfe and . Livinghouse, -Butylphenylphosphine???Borane with (???)-Sparteine, Journal of the American Chemical Society, vol.120, issue.20, pp.5116-5117, 1998.
DOI : 10.1021/ja973685k
URL : https://hal.archives-ouvertes.fr/hal-00159607

M. Amat, N. Canto, C. Llor, E. Escolano, E. Molins et al., Dynamic Kinetic Resolution of Racemic ??-Aryl-??-oxoesters. Enantioselective Synthesis of 3-Arylpiperidines, The Journal of Organic Chemistry, vol.67, issue.15, pp.5343-5351, 2002.
DOI : 10.1021/jo025894f

M. Amat, M. Canto, N. Llor, V. Ponzo, M. Pérez et al., Dynamic Kinetic Resolution and Desymmetrization of Enantiotopic Groups by Cyclodehydration of Racemic or Prochiral ??-Oxoesters with (R)-Phenylglycinol: Enantioselective Synthesis of Piperidines This work was supported by the DGICYT, Spain (BQU2000-0651), and the CUR, Generalitat de Catalunya (2001SGR-0084). We also thank the Ministry of Education, Culture, and Sport for fellowships to M.C. and M.P., as well as the CICYT, Spain, for a postdoctoral fellowship to V.P., Angewandte Chemie International Edition, vol.41, issue.2, pp.335-338, 2002.
DOI : 10.1002/1521-3773(20020118)41:2<335::AID-ANIE335>3.0.CO;2-Y

L. Tang and L. Deng, Dynamic Kinetic Resolution via Dual-Function Catalysis of Modified Cinchona Alkaloids:?? Asymmetric Synthesis of ??-Hydroxy Carboxylic Acids, Journal of the American Chemical Society, vol.124, issue.12, pp.2870-2871, 2002.
DOI : 10.1021/ja0255047

S. Brand, M. F. Jones, and C. M. Rayner, The first examples of dynamic kinetic resolution by enantioselective acetylation of hemithioacetals: An efficient synthesis of homochiral ??-Acetoxysulfides, Tetrahedron Letters, vol.36, issue.46, pp.8493-8496, 1995.
DOI : 10.1016/0040-4039(95)01748-7

H. Van-der-deen, A. S. Cuiper, R. P. Hof, A. Van-oeveren, B. L. Feringa et al., )-furanone and Pyrrolinone Synthons, Journal of the American Chemical Society, vol.118, issue.16, pp.3801-3803, 1996.
DOI : 10.1021/ja953812h

A. D. Cuiper, M. L. Kouwijzer, P. D. Grootenhuis, R. M. Kellog, and B. L. Feringa, Lipase B:?? Synthetic and Structural Aspects, The Journal of Organic Chemistry, vol.64, issue.26, pp.9529-9537, 1999.
DOI : 10.1021/jo991062e

M. Van-den-heuvel, A. D. Cuiper, H. Van-der-deen, R. M. Kellog, and B. L. Feringa, Optically active 6-acetyloxy-2H-pyran-3(6H)-one obtained by lipase catalyzed transesterification and esterification, Tetrahedron Letters, vol.38, issue.9, pp.1655-1658, 1997.
DOI : 10.1016/S0040-4039(97)00155-X

D. S. Tan, M. M. Günter, and D. G. Drueckhammer, Enzymatic Resolution Coupled with Substrate Racemization Using a Thioester Substrate, Journal of the American Chemical Society, vol.117, issue.35, pp.9093-9094, 1995.
DOI : 10.1021/ja00140a037

L. Haughton and J. M. , Williams Synthesis, pp.943-946, 2001.

M. A. Wegmans, M. A. Hacking, J. Rops, P. Pereira, F. Van-rantwijk et al., Dynamic kinetic resolution of phenylglycine esters via lipase-catalysed ammonolysis, Tetrahedron: Asymmetry, vol.10, issue.9, pp.1739-1750, 1999.
DOI : 10.1016/S0957-4166(99)00143-3

N. Berezina, V. Alphand, and R. Furstoss, Microbiological transformations. Part 51: The first example of a dynamic kinetic resolution process applied to a microbiological Baeyer???Villiger oxidation, Tetrahedron: Asymmetry, vol.13, issue.18, pp.1953-1955, 2002.
DOI : 10.1016/S0957-4166(02)00442-1

J. V. Allen and J. M. Williams, Dynamic kinetic resolution with enzyme and palladium combinations, Tetrahedron Letters, vol.37, issue.11, pp.1859-1862, 1996.
DOI : 10.1016/0040-4039(96)00136-0

O. Pamies and J. E. , Dynamic Kinetic Resolution of ??-Azido Alcohols. An Efficient Route to Chiral Aziridines and ??-Amino Alcohols, The Journal of Organic Chemistry, vol.66, issue.11, pp.4022-4025, 2001.
DOI : 10.1021/jo015579d

O. Pamies and J. E. , Enzymatic Kinetic Resolution and Chemoenzymatic Dynamic Kinetic Resolution of ??-Hydroxy Esters. An Efficient Route to Chiral ??-Lactones, The Journal of Organic Chemistry, vol.67, issue.4, pp.1261-1265, 2002.
DOI : 10.1021/jo016096c

O. Pamies and J. E. , Chemoenzymatic Dynamic Kinetic Resolution of ??-Halo Alcohols. An Efficient Route to Chiral Epoxides, The Journal of Organic Chemistry, vol.67, issue.25, pp.9006-9010, 2002.
DOI : 10.1021/jo026157m

H. Choi, Y. H. Kim, S. H. Nam, S. T. Shin, and M. J. Kim, Aminocyclopentadienyl Ruthenium Chloride: Catalytic Racemization and Dynamic Kinetic Resolution of Alcohols at Ambient Temperature, Angewandte Chemie International Edition, vol.54, issue.13, pp.2373-2376, 2002.
DOI : 10.1002/1521-3773(20020703)41:13<2373::AID-ANIE2373>3.0.CO;2-7

J. Kim, Y. I. Chung, Y. K. Choi, H. K. Lee, D. Kim et al., )-Selective Dynamic Kinetic Resolution of Secondary Alcohols by the Combination of Subtilisin and an Aminocyclopentadienylruthenium Complex as the Catalysts, Journal of the American Chemical Society, vol.125, issue.38, pp.11494-11495, 2003.
DOI : 10.1021/ja036766r

Y. K. Choi, J. H. Suh, D. Lee, I. T. Lim, J. Y. Jung et al., Dynamic Kinetic Resolution of Acyclic Allylic Acetates Using Lipase and Palladium, The Journal of Organic Chemistry, vol.64, issue.22, pp.8423-8424, 1999.
DOI : 10.1021/jo990956w

V. Jurkauskas and S. L. Buchwald, Dynamic Kinetic Resolution via Asymmetric Conjugate Reduction:?? Enantio- and Diastereoselective Synthesis of 2,4-Dialkyl Cyclopentanones, Journal of the American Chemical Society, vol.124, issue.12, pp.2892-2893, 2002.
DOI : 10.1021/ja025603k

G. R. Cook, P. S. Shanker, and K. , Palladium-Mediated Dynamic Kinetic Resolution: Stereoselective Synthesis of Vicinal Diamines, Angewandte Chemie International Edition, vol.38, issue.1-2, pp.110-112, 1999.
DOI : 10.1002/(SICI)1521-3773(19990115)38:1/2<110::AID-ANIE110>3.0.CO;2-L

M. Trost, R. C. Bunt, R. C. Lemoine, and T. L. Calkins, Dynamic Kinetic Asymmetric Transformation of Diene Monoepoxides:?? A Practical Asymmetric Synthesis of Vinylglycinol, Vigabatrin, and Ethambutol, Journal of the American Chemical Society, vol.122, issue.25, pp.5968-5976, 2000.
DOI : 10.1021/ja000547d

R. Noyori, T. Ohkuma-angew, T. Ohkuma, M. Kitamura, and R. , Noyori Catalytic Asymmetric Synthesis, 2 nd Ed, Chem. Int. Ed. J.P. Genet Acc. Chem. Res, vol.40, issue.36, pp.40-73, 1999.

W. S. Knowles, M. J. Sabacky, B. D. Vineyard, and D. J. Weinkauff, Asymmetric hydrogenation with a complex of rhodium and a chiral bisphosphine, Journal of the American Chemical Society, vol.97, issue.9, pp.2567-2568, 1975.
DOI : 10.1021/ja00842a058

R. Noyori, M. Ohta, Y. Hsiao, M. Kitamura, and H. Takaya, Asymmetric synthesis of isoquinoline alkaloids by homogeneous catalysis, Journal of the American Chemical Society, vol.108, issue.22, pp.7117-7119, 1986.
DOI : 10.1021/ja00282a054

M. Kitamura, M. Tokunaga, and R. Noyori, Practical synthesis of BINAP-ruthenium(II) dicarboxylate complexes, The Journal of Organic Chemistry, vol.57, issue.14, pp.4053-4054, 1992.
DOI : 10.1021/jo00040a068

B. Heiser, E. A. Broger, and Y. Crameri, New efficient methods for the synthesis and in-situ preparation of ruthenium(II) complexes of atropisomeric diphosphines and their application in asymmetric catalytic hydrogenations, Tetrahedron: Asymmetry, vol.2, issue.1, pp.51-62, 1991.
DOI : 10.1016/S0957-4166(00)82157-6

W. Alcok, J. M. Brown, M. Rose, and A. Wienand, A simple general route to chelate diphosphine ruthenium (II) complexes., Tetrahedron: Asymmetry, vol.2, issue.1, pp.47-50, 1991.
DOI : 10.1016/S0957-4166(00)82156-4

J. P. Genet, S. Mallart, C. Pinel, S. Jugé, and J. A. Tetrahedron, General synthesis of novel chiral ruthenium catalysts and their use in asymmetric hydrogenation, Tetrahedron: Asymmetry, vol.2, issue.1, pp.43-46, 1991.
DOI : 10.1016/S0957-4166(00)82155-2

J. P. Genet, C. Pinel, V. Ratovelomanana-vidal, S. Mallart, X. Pfister et al., Novel, general synthesis of the chiral catalysts diphosphine-ruthenium (II) diallyl complexes and a new practical in situ preparation of chiral ruthenium (II) catalysts, Tetrahedron: Asymmetry, vol.5, issue.4, pp.665-674, 1994.
DOI : 10.1016/0957-4166(94)80029-4

X. Madec, P. Pfister, V. Phansavath, J. P. Ratovelomanana-vidal, and . Genet, Asymmetric hydrogenation reactions using a practical in situ generation of chiral ruthenium???diphosphine catalysts from anhydrous RuCl3, Tetrahedron, vol.57, issue.13, pp.2563-2568, 2001.
DOI : 10.1016/S0040-4020(01)00067-9

M. Akotsi, K. Metera, R. D. Reid, R. Mcdonald, and S. H. , Versatile precursor to ruthenium-bis(phosphine) hydrogenation catalysts, Chirality, vol.103, issue.5-6, pp.514-522, 2000.
DOI : 10.1002/(SICI)1520-636X(2000)12:5/6<514::AID-CHIR38>3.0.CO;2-#

M. Bulliard, B. Laboue, J. Lastennet, and S. R. Org, Large-Scale Candoxatril Asymmetric Hydrogenation, Organic Process Research & Development, vol.5, issue.4, pp.438-441, 2001.
DOI : 10.1021/op010005w

R. Noyori, T. Ikeda, T. Ohkuma, M. Widhalm, M. Kitamura et al., Stereoselective hydrogenation via dynamic kinetic resolution, Journal of the American Chemical Society, vol.111, issue.25, pp.9134-9135, 1989.
DOI : 10.1021/ja00207a038

J. P. Genêt, S. Mallart, and S. , Asymmetric synthesis. Practical production of D and L threonine. Dynamic kinetic resolution in rhodium and ruthenium catalyzed hydrogenation of 2-acylamino-3-oxobutyrates., Tetrahedron: Asymmetry, vol.2, issue.7, pp.555-567, 1989.
DOI : 10.1016/S0957-4166(00)86108-X

J. A. Daley and S. H. Bergens, The First Complete Identification of a Diastereomeric Catalyst???Substrate (Alkoxide) Species in an Enantioselective Ketone Hydrogenation. Mechanistic Investigations, Journal of the American Chemical Society, vol.124, issue.14, pp.3680-3691, 2002.
DOI : 10.1021/ja0102991

N. Makino, O. Okamoto, Y. Hara, and . Hamada, Efficient enantioselective synthesis of (2R,3R)- and (2S,3S)-3-hydroxyleucines and their diastereomers through dynamic kinetic resolution, Tetrahedron: Asymmetry, vol.12, issue.12, pp.1757-1762, 2001.
DOI : 10.1016/S0957-4166(01)00306-8

A. Lei, S. Wu, M. He, and X. Zhang, Highly Enantioselective Asymmetric Hydrogenation of ??-Phthalimide Ketone:?? An Efficient Entry to Enantiomerically Pure Amino Alcohols, Journal of the American Chemical Society, vol.126, issue.6, pp.1626-1627, 2004.
DOI : 10.1021/ja039153n

M. Kitamura, M. Tokunaga, and R. Noyori, Quantitative expression of dynamic kinetic resolution of chirally labile enantiomers: stereoselective hydrogenation of 2-substituted 3-oxo carboxylic esters catalyzed by BINAP-ruthenium(II) complexes, Journal of the American Chemical Society, vol.115, issue.1, pp.144-152, 1993.
DOI : 10.1021/ja00054a020

M. Kitamura, M. Tokunaga, and R. Noyori, Asymmetric Hydrogenation of .beta.-Keto Phosphonates: A Practical Way to Fosfomycin, Journal of the American Chemical Society, vol.117, issue.10, pp.2931-2932, 1995.
DOI : 10.1021/ja00115a030

M. J. Burk, T. G. Harper, and C. S. Kalberg, Highly Enantioselective Hydrogenation of .beta.-Keto Esters under Mild Conditions, Journal of the American Chemical Society, vol.117, issue.15, pp.4423-4424, 1995.
DOI : 10.1021/ja00120a035

S. D. Rychnovsky and R. C. Hoye, Convergent Synthesis of the Polyene Macrolide (-)-Roxaticin, Journal of the American Chemical Society, vol.116, issue.5, pp.1753-1765, 1994.
DOI : 10.1021/ja00084a017

M. Wovkulich, K. Shankaran, J. Kiegel, and M. R. Uskokovic, Total synthesis of 1233A, The Journal of Organic Chemistry, vol.58, issue.4, pp.832-839, 1993.
DOI : 10.1021/jo00056a013

T. Ohkuma, H. Ooka, M. Yamakawa, T. Ikariya, and R. Noyori, Stereoselective Hydrogenation of Simple Ketones Catalyzed by Ruthenium(II) Complexes, The Journal of Organic Chemistry, vol.61, issue.15, pp.4872-4873, 1996.
DOI : 10.1021/jo960997h

T. Ohkuma, H. Ooka, S. Hashiguchi, T. Ikariya, and R. Noyori, Practical Enantioselective Hydrogenation of Aromatic Ketones, Journal of the American Chemical Society, vol.117, issue.9, pp.2675-2676, 1995.
DOI : 10.1021/ja00114a043

T. Matsumoto, T. Murayama, S. Mitsuhashi, and T. Miura, Diastereoselective synthesis of a key intermediate for the preparation of tricyclic ??-lactam antibiotics, Tetrahedron Letters, vol.40, issue.27, pp.5043-5046, 1999.
DOI : 10.1016/S0040-4039(99)00929-6

J. Alcock, I. Mann, P. Peach, and M. Wills, Dynamic kinetic resolution???asymmetric transfer hydrogenation of 1-aryl-substituted cyclic ketones, Tetrahedron: Asymmetry, vol.13, issue.22, pp.2485-2490, 2002.
DOI : 10.1016/S0957-4166(02)00648-1

F. Eustache, P. I. Dalko, and J. Cossy, Enantioselective monoreduction of 2-alkyl 1,3-diketones using chiral ruthenium catalysts. Synthesis of the C14???C25 fragment of bafilomycin A1, Tetrahedron Letters, vol.44, issue.49, pp.8823-8826, 2003.
DOI : 10.1016/j.tetlet.2003.09.192

S. Y. Yamada, Y. Mori, K. Morimatsu, Y. Ishizu, Y. Ozaki et al., )-??-Amino Acids:?? An Efficient Synthesis of a Key Intermediate of Diltiazem, The Journal of Organic Chemistry, vol.61, issue.24, pp.8586-8590, 1996.
DOI : 10.1021/jo960950w

E. Marchi, M. Trepat, A. Moreno-manias, and E. Vallribera, Ni(II)-catalyzed Michael additions. Part 2: Dynamic kinetic resolution in the reduction of chiral ??-hydrazino-??-ketoacid derivatives, Tetrahedron, vol.58, issue.28, pp.5699-5708, 2002.
DOI : 10.1016/S0040-4020(02)00538-0

T. Noro, . Fujisawa-chem, and . Lett, 1739. c) G. Frater Helv, Chem. Acta, vol.62, p.2825, 1979.

S. Danchet, C. Bigot, D. Buisson, and R. Azerad, Dynamic kinetic resolution in the microbial reduction of ??-monosubstituted ??-oxoesters: the reduction of 2-carbethoxycycloheptanone and 2-carbethoxy-cyclooctanone, Tetrahedron: Asymmetry, vol.8, issue.11, pp.1735-1739, 1997.
DOI : 10.1016/S0957-4166(97)00171-7

O. Cabon, M. Larchevêque, D. Buisson, and R. Azerad, Microbial reduction of 2-chloro-3-aryl-3-oxopropionic acid esters, Tetrahedron Letters, vol.33, issue.48, pp.7337-7340, 1992.
DOI : 10.1016/S0040-4039(00)60181-8

M. Soukup, B. Wipf, E. Hochuli, H. G. Leuenberger, and . Helv, 124-a) S.C. Bergmeier Tetrahedron, Chim. ActaJ. Ager, I. Prakash, D.R. Schaad Chem. Rev, vol.70, issue.96, pp.2561-2576, 1987.

K. Umezawa, K. Nakazawa, Y. Ikeda, H. Naganawa, and S. Kondo, )-3-Hydroxy-3-methylproline, The Journal of Organic Chemistry, vol.64, issue.9, pp.3034-3038, 1999.
DOI : 10.1021/jo981512n

J. C. Panek, C. E. Masse, T. Nagamitsu, T. Sunakuza, H. Tanaka et al., Total Synthesis of (+)-Lactacystin, Angewandte Chemie International Edition, vol.38, issue.8, pp.1093-1095, 1996.
DOI : 10.1002/(SICI)1521-3773(19990419)38:8<1093::AID-ANIE1093>3.0.CO;2-U

J. Clay, T. A. Collom, G. L. Karrick, and J. , Wemple Synthesis, p.290, 1993.

B. L. Cohen, J. F. Banner, G. Blount, M. Weber, G. Tsai et al., Synthesis of novel spiro heterocycles. 2-Amino-7-oxa-3-thia-1-azaspiro[5.5]undec-1-enes, The Journal of Organic Chemistry, vol.39, issue.13, pp.1824-1833, 1974.
DOI : 10.1021/jo00927a008

S. H. Pines, S. Karady, and M. Sletzinger, 3-Aryl-2-methylserines. I. A new synthesis, The Journal of Organic Chemistry, vol.33, issue.5, pp.1758-1761, 1968.
DOI : 10.1021/jo01269a012

M. Ohkuma, K. Koizumi, G. Muniz, C. Hilt, R. Kabuto et al., )(binap)(1,2-diamine):?? A Catalyst for Asymmetric Hydrogenation of Simple Ketones under Base-Free Conditions, Journal of the American Chemical Society, vol.124, issue.23, pp.6508-6509, 2002.
DOI : 10.1021/ja026136+

T. Makino, Y. Goto, Y. Hiroli, H. Sato, and A. Nakajima, Stereoselective Synthesis ofanti-??-Hydroxy-??-amino Acids through Dynamic Kinetic Resolution, Angewandte Chemie International Edition, vol.43, issue.7, pp.882-884, 1973.
DOI : 10.1002/anie.200353072

P. B. Schwartz, E. Madan, J. P. Mohacsi, L. J. O-'brien, and D. L. Todaro, Enantioselective synthesis of calcium channel blockers of the diltiazem group, The Journal of Organic Chemistry, vol.57, issue.3, pp.851-856, 1992.
DOI : 10.1021/jo00029a013

A. Gentile, C. Giordano, L. T. Kanerva, and O. Sundholm, The enzymic preparation of (2R,3S)-phenyl glycidic acid esters, The Journal of Organic Chemistry, vol.57, issue.24, pp.6635-6637, 1992.
DOI : 10.1021/jo00050a049

G. Rossey, A. Tixidre, A. Wick, L. S. Yamada, K. Morimatsu et al., Zard Brevet Japonais 4-217969 (Synthelabo), 1992. b), Tetrahedron: Asymmetry, vol.9, pp.1713-1721, 1998.

A. Bousquet, J. R. Dormoy, A. A. Solladié-cavallo, L. Bouérat, L. Jierry-eur et al., Heymes Brevet Européen EP 040912 (Sanofi), 1991. b) A. Solladié-Cavallo, e) T. Furutani, R. Imashiro, M. Hatsuda, M. Seki J. Org. Chem, pp.3531-3534, 2000.

J. M. Chang, E. N. Galvin, and . Jacobsen, Effect of Chiral Quaternary Ammonium Salts on (salen)Mn-Catalyzed Epoxidation of cis-Olefins. A Highly Enantioselective, Catalytic Route to Trans-Epoxides, Journal of the American Chemical Society, vol.116, issue.15, pp.6937-6938, 1994.
DOI : 10.1021/ja00094a059

E. N. Jacobsen, L. Deng, Y. Furukawa, L. E. Martinez-tetrahedron, R. Imashiro et al., 152-(a), J. Org. Chem, vol.50, issue.42, pp.4323-4334, 1994.

M. Takahashi, M. Muraoka, K. Capo, and . Koga, Enantioselective Darzens Reaction: Asymmetric Synthesis of trans-Glycidic Esters Mediated by Chiral Lithium Amides., CHEMICAL & PHARMACEUTICAL BULLETIN, vol.43, issue.10, pp.1821-1823, 1995.
DOI : 10.1248/cpb.43.1821

R. Imashiro, T. Yamanaka, and M. Seki, Catalytic asymmetric synthesis of glycidic amides via chiral sulfur ylides, Tetrahedron: Asymmetry, vol.10, issue.15, pp.2845-2851, 1999.
DOI : 10.1016/S0957-4166(99)00289-X

M. Matsuki, A. Sobukawa, H. Kawai, M. Inoue, and . Takeda, Asymmetric Reduction of Aromatic Ketones. II. An Enantioselective Synthesis of Methyl(2R,3S)-3-(4-Methoxypehnyl)glycidate., CHEMICAL & PHARMACEUTICAL BULLETIN, vol.41, issue.4, pp.643-648, 1993.
DOI : 10.1248/cpb.41.643

M. Choudary, N. S. Choudary, S. Madhi, and M. L. Kantam, A Trifunctional Catalyst for One-Pot Synthesis of Chiral Diols via Heck Coupling???N-Oxidation???Asymmetric Dihydroxylation:?? Application for the Synthesis of Diltiazem and Taxol Side Chain, The Journal of Organic Chemistry, vol.68, issue.5, pp.1736-1746, 2003.
DOI : 10.1021/jo026687i

J. N. Denis, A. Greene, D. Guénard, F. Guéritte-voegelein, L. Mangatal et al., Highly efficient, practical approach to natural taxol, Journal of the American Chemical Society, vol.110, issue.17, pp.5917-5919, 1988.
DOI : 10.1021/ja00225a063

F. Guéritte-voegelein, D. Guénard, F. Lavelle, M. T. Le-goff, L. Mangatal et al., Relationships between the structure of taxol analogs and their antimitotic activity, Journal of Medicinal Chemistry, vol.34, issue.3, pp.992-998, 1991.
DOI : 10.1021/jm00107a017

I. Ringel, S. B. Horwitz, and J. Natl, Cancer Inst, P. Potier Cancer Res, vol.83, issue.51, pp.288-291, 1991.

C. Wani, H. L. Taylor, M. E. Wall, P. Coggon, and A. T. Mcphail, Plant antitumor agents. VI. Isolation and structure of taxol, a novel antileukemic and antitumor agent from Taxus brevifolia, Journal of the American Chemical Society, vol.93, issue.9, pp.2325-2327, 1971.
DOI : 10.1021/ja00738a045

I. Ojima, I. Habus, M. Zhao, M. Zucco, Y. H. Park et al., New and efficient approaches to the semisynthesis of taxol and its C-13 side chain analogs by means of ??-lactam synthon method, Tetrahedron, vol.48, issue.34, pp.6985-7012, 1992.
DOI : 10.1016/S0040-4020(01)91210-4

M. Gennari, M. Carcano, N. Donghi, E. Mongelli, A. Vanotti et al., Taxol Semisynthesis:?? A Highly Enantio- and Diastereoselective Synthesis of the Side Chain and a New Method for Ester Formation at C-13 Using Thioesters, The Journal of Organic Chemistry, vol.62, issue.14, pp.4746-4755, 1997.
DOI : 10.1021/jo9703212

P. Merino, E. Castillo, S. Franco, F. L. Merchan, and T. , Nucleophilic additions of Grignard reagents to N-benzyl-2,3-O-isopropylidene-D-glyceraldehyde nitrone (BIGN). Synthesis of (2S,3R) and (2S,3S)-3-phenylisoserine, Tetrahedron, vol.54, issue.40, pp.12301-12322, 1998.
DOI : 10.1016/S0040-4020(98)00741-8

I. Kudyba, J. Raczko, and J. Jurczak, )-8-Phenylmenthyl Glyoxylate, The Journal of Organic Chemistry, vol.69, issue.8, pp.2844-2850, 2004.
DOI : 10.1021/jo0358269

M. Pasto, A. Moyano, A. Pericas, and A. , Riera Tetrahedron: Asymmetry, pp.243-262, 1994.

O. Cabon, D. Buisson, M. Larcheveque, and R. Azerad, Stereospecific preparation of glycidic esters from 2-chloro-3-hydroxyesters. Application to the synthesis of (2R,3S)-3-phenylisoserine, Tetrahedron: Asymmetry, vol.6, issue.9, pp.2211-2218, 1995.
DOI : 10.1016/0957-4166(95)00295-Z

P. O-'brien and . Angew, Sharpless Asymmetric Aminohydroxylation: Scope, Limitations, and Use in Synthesis, Angewandte Chemie International Edition, vol.38, issue.3, pp.326-329, 1998.
DOI : 10.1002/(SICI)1521-3773(19990201)38:3<326::AID-ANIE326>3.0.CO;2-T

K. L. Reddy and K. B. Sharpless, From Styrenes to Enantiopure ??-Arylglycines in Two Steps, Journal of the American Chemical Society, vol.120, issue.6, pp.1207-1217, 1998.
DOI : 10.1021/ja9728177

J. N. Denis, A. E. Greene, D. Guénard, F. Guéritte-voegelein, L. Mangatal et al., Highly efficient, practical approach to natural taxol, Journal of the American Chemical Society, vol.110, issue.17, pp.5917-5919, 1988.
DOI : 10.1021/ja00225a063

S. Jeulin, V. Duprat-de-paule, J. P. Ratovelomanana-vidal, N. Genet, and P. Champion, Difluorphos, an Electron-Poor Diphosphane: A Good Match Between Electronic and Steric Features, Angewandte Chemie International Edition, vol.43, issue.3, pp.320-325, 2004.
DOI : 10.1002/anie.200352453

J. N. Denis, A. Correa, and A. E. Grenne, An improved synthesis of the taxol side chain and of RP 56976, The Journal of Organic Chemistry, vol.55, issue.6, pp.1957-1959, 1990.
DOI : 10.1021/jo00293a052

G. R. Pettit, Y. Kamano, C. L. Herald, A. A. Tuinman, F. E. Boettner et al., The isolation and structure of a remarkable marine animal antineoplastic constituent: dolastatin 10, Journal of the American Chemical Society, vol.109, issue.22, pp.6883-6885, 1987.
DOI : 10.1021/ja00256a070

H. Luesch, R. E. Moore, V. J. Paul, S. L. Mooberry, and T. H. Corbett, Species VP642 and Total Stereochemistry and Biological Evaluation of Its Analogue Symplostatin 1, b) L.M. Nogle, W.H, pp.907-910, 2001.
DOI : 10.1021/np010049y

G. R. Pettit, S. B. Singh, F. Hogan, P. Lloyd-williams, C. L. Herald et al., Antineoplastic agents. Part 189. The absolute configuration and synthesis of natural (-)-dolastatin 10, Journal of the American Chemical Society, vol.111, issue.14, pp.5463-5465, 1989.
DOI : 10.1021/ja00196a061

Y. Hamada, K. Hayashi, and T. Shioiri, Efficient stereoselective synthesis of dolastatin 10, an antineoplastic peptide from a sea hare, Tetrahedron Letters, vol.32, issue.7, pp.931-934, 1991.
DOI : 10.1016/S0040-4039(00)92123-3

T. Shioiri, K. Hayashi, and Y. , Stereoselective synthesis of dolastatin 10 and its congeners, Tetrahedron, vol.49, issue.9, pp.1913-1924, 1993.
DOI : 10.1016/S0040-4020(01)80547-0

F. Roux, I. Maugras, J. Poncet, G. Niel, and P. , Synth??se de la dolastatine 10 et de la [R-doe]-dolastatine 10, Tetrahedron, vol.50, issue.18, pp.5345-5360, 1994.
DOI : 10.1016/S0040-4020(01)80692-X

N. Irako, Y. Hamada, and T. Shioiri, A new efficient synthesis of (S)-dolaphenine ((S)-2-phenyl-1-(2-thiazolyl)ethylamine), the C-terminal unit of dolastatin 10, Tetrahedron, vol.48, issue.35, pp.7251-7264, 1992.
DOI : 10.1016/S0040-4020(01)88264-8

G. R. Pettit, S. B. Singh, D. L. Herald, P. Lloyd-williams, D. Kantoci et al., The Dolastatins. 17. Synthesis of Dolaproine and Related Diastereoisomers, The Journal of Organic Chemistry, vol.59, issue.21, pp.6287-6295, 1994.
DOI : 10.1021/jo00100a034

G. R. Pettit, D. D. Burkett, J. Barkoczy, G. L. Breneman, and W. , Pettit Synthesis, pp.719-725, 1996.

M. Miyazaki, T. Kobayashi, M. Natsume, T. Gondo, K. Mikami et al., Synthesis and Antitumor Activity of Novel Dolastatin 10 Analogs., CHEMICAL & PHARMACEUTICAL BULLETIN, vol.43, issue.10, pp.1706-1718, 1995.
DOI : 10.1248/cpb.43.1706

A. M. Burja, B. Banaigs, E. Abou-mansour, J. G. Burgess, and P. C. Wright, Marine cyanobacteria???a prolific source of natural products, Tetrahedron, vol.57, issue.46, pp.9347-9377, 2001.
DOI : 10.1016/S0040-4020(01)00931-0

R. Pettit, S. B. Singh, J. K. Srirangam, F. Hogan-pierson, and M. D. Williams, The Dolastatins. 19. Synthesis of Dolaisoleuine, The Journal of Organic Chemistry, vol.59, issue.7, pp.1796-1800, 1994.
DOI : 10.1021/jo00086a034

S. Masamune, W. Choy, J. S. Petersen, and L. R. Sita, Double Asymmetric Synthesis and a New Strategy for Stereochemical Control in Organic Synthesis, Angewandte Chemie International Edition in English, vol.25, issue.1, pp.1-30, 1985.
DOI : 10.1002/anie.198500013

J. D. Armstrong, I. , J. L. Keller, J. Lynch, T. Liu et al., An efficient asymmetric synthesis of the mercaptopyrrolidine side chain of an important ??-methyl carbapenem antibiotic, Tetrahedron Letters, vol.38, issue.18, pp.3203-3206, 1997.
DOI : 10.1016/S0040-4039(97)00613-8

H. Ohtake, S. Jona, O. Okada, Y. Okamoto, R. Imai et al., Diastereoselective synthesis of the key intermediate of the BO-2727 side chain, Tetrahedron: Asymmetry, vol.8, issue.17, pp.2939-2947, 1997.
DOI : 10.1016/S0957-4166(97)00315-7

J. Matsubara, K. Nakao, Y. Hamada, and T. Shioiri, A synthesis of the tetraene fragment of calyculins as its antipodal form, Tetrahedron Letters, vol.33, issue.29, pp.4187-4190, 1992.
DOI : 10.1016/S0040-4039(00)74685-5

D. Perrin and W. L. , Armarego Purification of laboratory chemicals 3 rd Ed, 1988.