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. Si, O(1)-C(29) 1.453(3) C(1)-C(5) 1.415(3) C(1)-C(2) 1, pp.420-423

I. Annex, Tm(1)-I(1) 143.5(1) C(4)-Tm(1)-I(1) 92Tm(1)-I(1) 120.3(1) C(3)-Tm(1)-I(1) 92.2(1) C(5)-Tm(1)-I(1) 121) I(2)-Tm(1)-I(1) 132C(1)-Tm(1) 74, ) C(5)-C(1)-Tm(1) 74.6(3) C(6)-C(1)-Tm(1) 126.0(4) C(1)-C(2)-C(3) 108.5(4) C(1)-C(2)-C(7)) C(8)-C(3)-Tm(1) 124.9(3) C(3)-C(4)-C(5) 108.1(3) C(3)-C(4)-C(9) 123.8(4) C(5)-C(4)-C(9) 127.2(4) C(3)-C(4)-Tm) O(2)-C(15)-C(16) 105.9(4) C(17)-C(16)-C(15) 103.9(4) C(18)-C(17)-C, pp.79-530

. Si, Tm(1) 128

. Si, C(4)-C(3)-Tm(1) 74

. Si, Tm(1) 128.5(1) C(4)-C(5)-C(1) 111.0(2) C(4)-C(5)-Tm(1) 75

I. Annex, Tm(1)-C(5) 2.553(5) Tm(1)-C(3) 2, )-C(4) 2.586(5) Tm(1)-C(1) 2.587(5) Tm(1)-C(2) 2.601(5) Tm(1)-I(2) 2

I. Annex, Tm(1)-C(4) 93.2(1) C(22)-Tm(1)-C(4) 92Tm(1)-C(20) 113.2(1) C(22)-Tm(1)-C(20) 50 C(21)-Tm(1)-C(18) 51 C(5)-Tm(1)-C(18) 121.5(1) C(3)-Tm(1)-C(18) 126.3(1) C(4)-Tm(1)-C(18) 109.5(1) C(20)-Tm(1)-C(18) 50.0(1) C(2)-Tm(1)-C(18) 156 N(1)-Tm(1)-C(1) 118.4(1) C(22)-Tm(1)-C(1) 121.1(1) C(21)-Tm(1)-C(1) 109.3(1) C(5)-Tm(1)-C(1) 30.2(1) C(3)-Tm(1)-C(1) 49.8(1) C(4)-Tm(1)-C(1) 50) C(20)-Tm(1)-C(1) 126Tm(1)-C(1) 30.2(1) C(18)-Tm(1)-C(1) 150) C(22)-Tm(1)-C(19) 50.2(1) C(21)-Tm(1)-C(19) 50.9(1) C(5)-Tm(1)-C(19) 142.1(1) C(3)-Tm(1)-C(19) 152.1(1) C(4)-Tm(1)-C(19) 139.3(1) C(20)-Tm(1)-C(19) 30) C(18)-Tm(1)-C(19) 30.0(1) C(1)-Tm(1)-C(19)) N(1)-Tm(1)-I(1) 88.91(8) C(22)-Tm(1)-I(1) 129.49(7) C(21)-Tm(1)-I(1) 104.44(7) C(5)-Tm(1)-I(1) 118 C(3)-Tm(1)-I(1) 110 C(4)-Tm(1)-I(1) 135 C(20)-Tm(1)-I(1) 79 C(2)-Tm(1)-I(1) 84.51(7) C(18)-Tm(1)-I(1) 114 C(1)-Tm(1)-I(1) 89.57(7) C(19)-Tm(1)-I(1) 85, ) C(35)-N(1)-Tm(1) 166.2(3) C(5)-C(1)-C(2) 106.3(3) C(5)-C(1)-C(6) 119.4(3) C(2)-C(1)-C(6) 132.3(3) C(5)-C(1)-Tm(1) 69.9(2) C(2)-C(1)-Tm(1) 73.9(2) C(6)-C(1)-Tm(1) 132.5(2) C(3)-C(2)-C(1) 106.1(3) C(3)-C(2)-C(10) 117.7(3) C(1)-C(2)-C(10)) C(18)-C(19)-C(27) 132.2(3) C(20)-C(19)-Tm(1) 69.6(2) C(18)-C(19)-Tm(1) 73.5(2) C(27)-C(19)-Tm(1) 130.0(2) C(21)-C(20)-C) C(21)-C(20)-Tm) C(19)-C(20)-Tm) C(20)-C(21)-C(22) 105.7(3) C(20)-C(21)-C(31) 124.0(3) C(22)-C(21)-C(31) 127.0(3) C(20)-C(21)-Tm) C(22)-C(21)-Tm(1) 74.2(2) C(31)-C(21)-Tm) C(21)-C(22)-C(18) 110.4(3) C(21)-C(22)-Tm, pp.117-123, 2019.

. Si, C(1)-C(5) 1.412(5) C(1)-C(2) 1, pp.4-5

. Si, C(15)-C(16) 1.430(5) C(15)-C(19) 1.430(5) C(16)-C(17) 1, pp.18-19

. Si, C(43)-C(47) 1.423(5) C(43)-C(44) 1.442(5) C(44)-C(45) 1, pp.46-47

. Si, Dy(1) 127

. Si, C(4)-C(3)-C(2) 111.4(3) C(4)-C(3)-Dy(1) 75, pp.76-76

. Si, Dy(1) 127 C(1)-C(5)-C(4) 111.4(3) C(1)-C(5)-Dy(1) 75

. Si, Dy(2) 131.0(2) C(17)-C(16)-C(15) 106.6(3) C(17)-C(16)-Si(5) 121.2(3) C(15)-C(16)-Si(5) 131, ) C(17)-C(16)-Dy(2) 73.8(2) C(15)-C(16)-Dy

. Si, C(16)-C(17)-C(18) 111.5(3) C(16)-C(17)-Dy(2) 74, ) C(18)-C(17)-Dy

. Si, C(18)-C(19)-C(15) 111.3(3) C(18)-C(19)-Dy(2) 75, ) C(15)-C(19)-Dy, pp.74-75, 2019.

. Si, C(31)-C(30)-C(29) 106.6(3) C(31)-C(30)-Si(8) 121, ) C(29)-C(30)-Si) C(31)-C(30)-Dy(2) 72.1(2) C(29)-C(30)-Dy, p.75

. Si, C(30)-C(31)-C(32) 111.1(3) C(30)-C(31)-Dy(2) 76, ) C(32)-C(31)-Dy, pp.75-78

. Si, C(29)-C(33)-C(32) 111.1(3) C(29)-C(33)-Dy(2) 75, ) C(32)-C(33)-Dy(2) 73.5(2) C(29)-C(33)-H(33)

. Si, C(35)-H(35A) 109

. Si, C(35)-H(35B) 109

. Si, C(37)-H(37A) 109

. Si, C(37)-H(37B) 109

. Si, C(38)-H(38A) 109

. Si, C(38)-H(38B) 109

. Si, C(39)-H(39A) 109

. Si, C(39)-H(39B) 109

. Si, Dy(3) 131 C(45)-C(44)-C(43) 106.8(3) C(45)-C(44)-Si(11) 122, ) C(43)-C(44)-Si) C(45)-C(44)-Dy(3) 73

. Si, C(46)-C(45)-C(44) 110.7(3) C(46)-C(45)-Dy(3) 75

. Si, C(46)-C(47)-C(43) 111.4(3) C(46)-C(47)-Dy(3) 75, pp.74-80

. Si, Dy(3) 122 C(59)-C(58)-C(57) 107.0(3) C(59)-C(58)-Si(14), ) C(57)-C(58)-Si) C(59)-C(58)-Dy(3) 72.2(2) C(57)-C(58)-Dy

. Si, Dy(3) 130 C(60)-C(59)-C(58) 109.6(3) C(60)-C(59)-Dy(3) 74, ) C(58)-C(59)-Dy(3) 76.0(2) C(60)-C(59)-H(59) 125

. Si, C(60)-C(61)-C(57) 111.1(4) C(60)-C(61)-Dy(3) 73, ) C(57)-C(61)-Dy) C(60)-C(61)-H(61)

. Si, (13)-C(62)-H(62A) 109

. Si, (13)-C(62)-H(62B) 109

. Si, (13)-C(62)-H(62C) 109

. Si, (13)-C(63)-H(63A) 109

. Si, (13)-C(63)-H(63B) 109

. Si, (13)-C(63)-H(63C) 109

. Si, (13)-C(64)-H(64A) 109

. Si, (13)-C(64)-H(64B) 109

. Si, (13)-C(64)-H(64C) 109

. Si, (15)-C(68)-H(68A) 109

. Si, (15)-C(68)-H(68B) 109

. Si, (15)-C(68)-H(68C) 109

. Si, (15)-C(69)-H(69A) 109

. Si, (15)-C(69)-H(69B) 109

. Si, (15)-C(69)-H(69C) 109

. Si, (15)-C(70)-H(70A) 109

. Si, (15)-C(70)-H(70B) 109

. Si, (15)-C(70)-H(70C) 109

. Dy, Dy(1)-I(1) 2

. Dy, 745(3) Dy(1)-C(13) 2.746(3) Dy(1)-C(3) 2, p.7958576

. Dy, Dy(1)-I(1) 3, p.1490

. Si, 881(3) C(25)-C(26) 1.419(4) C(26)-C(27) 1, ) C(26)-C(33) 1.509(4) C(27)-C(28) 1.409(4) C(27)-C(32) 1.512(4) C(29)-H(29A) 0, p.9800

I. Annex, Dy(1)-I(1) 128 C(3)-Dy(1)-I(1) 114.00(5) C(16)-Dy(1)-I(1) 92Dy(1)-I(1) 137 C(14)-Dy(1)-I(1) 99.04(6) C(15)-Dy(1)-I(1) 81.15(6) P(1)-Dy(1)-I(1) 86Dy(1)-I(1) 129 C(4)-Dy(1)-I(1)#2 121 C(1)-Dy(1)-I(1)#2 87 C(3)-Dy(1)-I(1)#2 137) C(16)-Dy(1)-I(1)#2 127, ) C(13)-Dy(1)-I(1)#2 91) C(2)-Dy(1)-I(1)#2) P(2)-Dy(1)-I(1)#2 128) I(1)-Dy(1)-I(1)#2 77)-I(1)-Dy(1)#2 102, pp.2-80

. Si, C(13)-C(14)-C(21) 125.0(3) C(15)-C(14)-Dy(1) 75 C(13)-C(14)-Dy(1) 73, ) C(21)-C(14)-Dy(1) 125) C(16)-C(15)-Dy

. Si, C(19)-H(19A) 109

. Si, C(19)-H(19B) 109

. Si, C(19)-H(19C) 109

I. Annex, C(47)-Si(7)-C(37) 110, ) C(47)-Si(7)-C(46) 107.7(1) C(48)-Si(7)-C(46) 109) C(42)-Si(8)-C(43) 107.7(2) C(42)-Si(8)-C(41) 108.0(2) C(43)-Si) C(43)-Si) C(41)-Si) C(26)-C(25)-Dy) P(3)-C(25)-Dy, pp.113-115

. Si, C(33)-C(26)-Dy(2) 125) C(28)-C(27)-Dy(2) 74, ) C(27)-C(26)-Dy(2) 76.5(2) C(25)-C(26)-Dy(2) 73) C(28)-C(27)-C(32) 123.7(3) C(26)-C(27)-Dy) C(32)-C(27)-Dy(2) 126.2(2) C(27)-C(28)-P(3)) C(27)-C(28)-Dy) P(3)-C(28)-Dy, pp.110-112

. Si, C(30)-H(30A) 109

. Si, C(30)-H(30B) 109

. Si, C(31)-H(31A) 109

. Si, C(31)-H(31B) 109

. Si, C(35)-H(35A) 109

. Si, C(35)-H(35B) 109

. Si, C(37)-C(38)-Dy(2) 74.1(1) C(39)-C(38)-Dy(2) 75.3(1) C(45)-C(38)-Dy(2) 126 C(40)-C(39)-C(38) 113, ) C(38)-C(39)-C(44) 121.3(2) C(40)-C(39)-Dy) C(38)-C(39)-Dy) C(44)-C(39)-Dy) C(39)-C(40)-P(4)) C(39)-C(40)-Dy(2) 77.0(2) P(4)-C(40)-Dy, pp.110-113

. Si, C(43)-H(43A) 109

. Si, C(43)-H(43B) 109

. Si, C(43)-H(43C) 109

I. Annex, B(1)-Dy(1)-H(1BA) 26.0(1) Cl(1)-Dy(1)-H(1BA) 92(1) Cl(2)-Dy(1)-H(1BA) 128Dy(1)-H(1BA) 114.1(6) C(3)-Dy(1)-H(1BA) 84.2(7) B(1)-Dy(1)-H(1BB) 26.1(1) Cl(1)-Dy(1)-H(1BB) 129 Cl(1)-Dy(1)-H(1BD) Cl(4A)-Dy(2)-C(30) 137 Cl(4B)-Dy(2)-C(30) 111 Cl(3)-Dy(2)-C(33) 131 Cl(4A)-Dy(2)-C(33) 88 Cl(4B)-Dy(2)-C(33) 83.9(8) C(30)-Dy(2)-C(33) 50 Cl(4A)-Dy Cl(4B)-Dy, Dy(1)-H(1BB) 113.5(5) C(4)-Dy(1)-H(1BB) 73(1) C(5)-Dy(1)-H(1BB) 82.6(5) C(2)-Dy(1)-H(1BB) 124(1) C(3)-Dy(1)-H(1BB) 98(1) H(1BA)-Dy(1)-H(1BB) 45.3(5) B(1)-Dy(1)-H(1BD)1BD) 85.9(8) C(1)-Dy(1)-H(1BD) 156.7(8) C(4)-Dy(1)-H(1BD) 114.5(4) C(5)-Dy(1)-H(1BD) 126.5(7) C(2)-Dy(1)-H(1BD) 158.1(6) C(3)-Dy(1)-H(1BD) 127.7(5) H(1BA)-Dy(1)-H(1BD) 44.0(4) H(1BB)-Dy(1)-H(1BD) 44.4(5) B(2)-Dy(2)-Cl(3) 100.3(3) B(2)-Dy(2)-Cl(4A) 103.2(3) Cl(3)-Dy(2)-Cl(4A) 98.9(3) B(2)-Dy(2)-Cl(4B) 70.2(8) Cl(3)-Dy(2)-Cl(4B) 132.6(8) Cl(4A)-Dy(2)-Cl(4B) 44.3(8) B(2)-Dy(2)-C(30) 94.0(3) Cl(3)-Dy) C(30)-Dy) C(33)-Dy) Cl(4A)-Dy) Cl(4B)-Dy) C(30)-Dy) C(33)-Dy) C(34)-Dy) Cl(4A)-Dy(2)-C(31) 132.0(3) Cl(4B)-Dy(2)-C(31) 133.0(8) C(30)-Dy(2)-C(31) 31.2(2) C(33)-Dy(2)-C(31) 51.3(2) C(34)-Dy(2)-C(31) 51.9(2) C(32)-Dy(2)-C(31) 31.2(2) B(2)-Dy(2)-H(2BA) 26.0(2) Cl(3)-Dy(2)-H(2BA) 80.0(7) Cl(4A)-Dy(2)-H(2BA) 91(1) Cl(4B)-Dy(2)-H(2BA) 73(1) C(30)-Dy(2)-H(2BA) 117.5(6) C(33)-Dy(2)-H(2BA) 147.9(6) C(34)-Dy) H(2BA)-Dy(2)-H(2BB) 45.0(5) B(2)-Dy(2)-H(2BD) 26.0(2) Cl(3)-Dy(2)-H(2BD) 123.9(6) Cl(4A)-Dy(2)-H(2BD)) Cl(4B)-Dy(2)-H(2BD) 47(1) C(30)-Dy(2)-H(2BD) 92(1) C(33)-Dy(2)-H(2BD) 103.7(7) C(34)-Dy(2)-H(2BD) 81(1) C(32)-Dy(2)-H(2BD) 132.4(8) C(31)-Dy(2)-H(2BD)) H(2BA)-Dy(2)-H(2BD) 44.1(5) H(2BB)-Dy(2)-H(2BD) 45.0(5) Dy(1)-B(1)-H(1BA)) H(1BA)-B(1)-H(1BB) 109.5(2) Dy(1)-B(1)-H(1BC) 176(2) H(1BA)-B(1)-H(1BC) 109.5(2) H(1BB)-B(1)-H(1BC) 109.5(2) Dy(1)-B(1)-H(1BD) 74(2) H(1BA)-B(1)-H(1BD) 109.5(2) H(1BB)-B(1)-H(1BD) 109.5(2) H(1BC)-B(1)-H(1BD) 109.5(2) Dy(2)-B(2)-H(2BA) 72(2) Dy(2)-B(2)-H(2BB)) H(2BA)-B(2)-H(2BB)) H(2BA)-B(2)-H(2BC) 109.5(2) H(2BB)-B(2)-H(2BC) 109.5(2) Dy(2)-B(2)-H(2BD) 72(2) H(2BA)-B(2)-H(2BD) 109.5(2) H(2BB)-B(2)-H(2BD) 109.5(2) H(2BC)-B(2)-H(2BD)) O(1)-K(1)-O(2) 59

I. Annex, Dy(1) 125, ) C(6)-C(7)-H(7A)

I. Annex, C(21)-Nd(1)-C(18) 49.2(1) C(20)-Nd(1)-C(18) 48.5(1) C(3)-Nd(1)-C(18) 98.6(1) C(22)-Nd(1)-C(18) 29 C(19)-Nd(1)-C(18) 29 C(4)-Nd(1)-C(1) 49.1(1) C(21)-Nd(1)-C(1) 128.4(1) C(20)-Nd(1)-C(1) 151 C(3)-Nd(1)-C(1) 48.4(1) C(22)-Nd(1)-C(1) 126.0(1) C(5)-Nd(1)-C(1) 29.31(8) H(3B1)-Nd(1)-C(1) 69.5(6) C(19)-Nd(1)-C(1) 173) C(18)-Nd(1)-C(1) 144) B(1)-Nd(1)-H(2B1) 24.0(6) C(4)-Nd(1)-H(2B1) 102.2(8) C(21)-Nd(1)-H(2B1), ) C(20)-Nd(1)-H(2B1) 79.5(8) C(3)-Nd(1)-H(2B1) 131.9(8) C(22)-Nd(1)-H(2B1) 124.8(8) C(5)-Nd(1)-H(2B1) 90.0(8) H(3B1)-Nd(1)-H(2B1) 40.1(8) C(19)-Nd(1)-H(2B1) 77.5(8) C(2)-Nd(1)-H(2B1) 136.7(8) C(18)-Nd(1)-H(2B1) 104.4(7) C(1)-Nd(1)-H(2B1) 108.4(8) B(1)-Nd(1)-H(4B1))-H(4B1) 93.5(8) H(3B1)-Nd(1)-H(4B1) 39.2(8) C(19)-Nd(1)-H(4B1) 95.7(8) C(2)-Nd(1)-H(4B1) 114.6(8) C(18)-Nd(1)-H(4B1) 123.3(8) C(1)-Nd(1)-H(4B1) 89.8(8) H(2B1)-Nd(1)-H(4B1)) C(10)-C(2)-Nd(1) 131.2(2) C(4)-C(3)-C(2) 110.4(3) C(4)-C(3)-Nd) C(2)-C(3)-Nd, pp.46-54

I. Annex, C(49)-O(1)-Na(1) 123Sm(1) 105 C(21)-C(20)-C(25) 119 C(25)-C(20)-P(2) 121 C(22)-C(21)-C(20) 120.6(3) C(23)-C(22)-C(21) 120.4(3) C(24)-C(23)-C(22) 120.2(3) C(23)-C(24)-C(25) 120.4(3) C(20)-C(25)-C(24) 119.5(3) C(30)-C(26)-C(27) 107 C(30)-C(26)-Sm(1) 73.9(1) C(27)-C(26)-Sm(1) 75) C(31)-C(26)-Sm(1) 126, ) C(9)-C(8)-P(1) 122.6(2) C(10)-C(9)-C(8) 120.4(2) C(11)-C(10)-C(9) 120.5(2) C(10)-C(11)-C(12) 119.8(2) C(11)-C(12)-C(13) 119.7(2) C(12)-C(13)-C(8) 121.0(2) C(15)-C(14)-C(19) 118.8(2) C(15)-C(14)-P(2) 122.0(2) C(19)-C(14)-P(2) 119.1(2) C(16)-C(15)-C(14)) C(15)-C(16)-C(17) 120.2(2) C(18)-C(17)-C(16)) C(27)-C(28)-C(33) 125.9(2) C(29)-C(28)-C(33) 125.8(2) C(27)-C(28)-Sm(1) 74.8(1) C(29)-C(28)-Sm(1) 74.6(1) C(33)-C(28)-Sm(1) 122.4(2) C(30)-C(29)-C(28) 107.2(2) C(30)-C(29)-C(34) 126.1(2) C(28)-C(29)-C(34) 126.1(2) C(30)-C(29)-Sm(1) 73.4(1) C(28)-C(29)-Sm(1) 76.0(1) C(34)-C(29)-Sm(1) 123.4(2) C(26)-C(30)-C(29)) C(38)-C(37)-Sm(1) 77.9(1) C(36)-C(37)-Sm) C(42)-C(37)-Sm(1) 122) C(39)-C(38)-C(37)) C(37)-C(38)-C(43)) C(39)-C(38)-Sm(1) 73) C(37)-C(38)-Sm(1) 73.3(1) C(43)-C(38)-Sm) C(49)-C(48)-C(47A) 99.7(4) C(47)-C(48)-C(47A) 45) C(53)-C(52)-C(51) 105) O(2)-C(53)-C(52) 105) O(3)-C(54)-C(55) 105.5(4) C(56)-C(55)-C(54) 106.8(4) C(56)-C(55)-C(56A) 31.3(5) C(54)-C(55)-C(56A) 111.6(8) C(55)-C(56)-C(57) 107.3(5) C(55)-C(56A)-C(57) 91(1) O(3)-C(57)-C(56) 106.2(4) O(3)-C(57)-C(56A) 105.9(7) C(56)-C(57)-C(56A), pp.131-140, 2019.