Microphase Separation and Shear Alignment of Gradient Copolymers: Melt Rheology and Small-Angle X-Ray Scattering Analysis, Macromolecules, vol.41, issue.15, pp.5818-5829, 2008. ,
DOI : 10.1021/ma8009454
Structuration et renforcement du polystyrène par des copolymères styrène/butadiène à gradient de composition, 2005. ,
Theory of Microphase Separation in Block Copolymers, Macromolecules, vol.13, issue.6, p.1602, 1980. ,
DOI : 10.1021/ma60078a047
Modelling X-ray or neutron scattering spectra of lyotropic lamellar phases : interplay between form and structure factors, Journal de Physique II, vol.3, issue.4, pp.487-502, 1993. ,
DOI : 10.1051/jp2:1993146
URL : https://hal.archives-ouvertes.fr/jpa-00247849
Small-angle x-ray scattering analyses of lamellar microdomains based on a model of one-dimensional paracrystal with uniaxial orientation, Macromolecules, vol.19, issue.3, pp.740-749, 1986. ,
DOI : 10.1021/ma00157a043
Properties of Polymers, 1997. ,
Solvent Distribution in Weakly-Ordered Block Copolymer Solutions, Macromolecules, vol.30, issue.20, pp.6139-6149, 1997. ,
DOI : 10.1021/ma970720z
Les techniques de l'ingénieur, 1465, 1994. ,
Phase Behavior and Viscoelastic Properties of Thermoplastic Elastomer Gels Based on ABC Triblock Copolymers, Macromolecules, vol.38, issue.18, pp.7798-7806, 2005. ,
DOI : 10.1021/ma050294e
Structuration et rhéologie des solutions de copolymères triblocs SBM : smectiques frustrés d'intérêt industriel, soutenue le 26, 2001. ,
Development of an ultra-small-angle X-ray scattering instrument for probing the microstructure and the dynamics of soft matter, Journal of Applied Crystallography, vol.40, issue.s1, pp.459-462, 2007. ,
DOI : 10.1107/S0021889806045833
Nonergodicity and light scattering from polymer gels, Physical Review A, vol.46, issue.10, pp.6550-6563, 1992. ,
DOI : 10.1103/PhysRevA.46.6550
Dynamic light scattering by nonergodic media: Brownian particles trapped in polyacrylamide gels, Physical Review A, vol.42, issue.4, pp.2161-2175, 1990. ,
DOI : 10.1103/PhysRevA.42.2161
Dynamic light scattering by non-ergodic media, Physica A: Statistical Mechanics and its Applications, vol.157, issue.2, pp.705-741, 1989. ,
DOI : 10.1016/0378-4371(89)90063-0
Asymmetric poly(ethylene-alt-propylene)-poly(ethylene oxide) micelles: A system with starlike morphology and interactions, Physical Review E, vol.76, issue.4, p.41503, 1997. ,
DOI : 10.1103/PhysRevE.76.041503
Form Factors of Block Copolymer Micelles with Excluded-Volume Interactions of the Corona Chains Determined by Monte Carlo Simulations, Macromolecules, vol.35, issue.3, pp.1028-1037, 2002. ,
DOI : 10.1021/ma011046v
Synchrotron Small-Angle X-Ray Scattering, Soft Matter: Scattering, Imaging and Manipulation, 2008. ,
DOI : 10.1007/978-1-4020-4465-6_17
Advances in Colloid and Interface Sciences, pp.171-176, 1997. ,
Modern Aspects of Small Angle Scattering, 1995. ,
DOI : 10.1007/978-94-015-8457-9
Polyelectrolyte Behavior of Diblock Copolymer Micelles Having Phosphonic Diacid Groups at the Corona, Macromolecules, vol.41, issue.6, pp.2195-2202, 2008. ,
DOI : 10.1021/ma702182p
URL : https://hal.archives-ouvertes.fr/hal-00303864
Development of an ultra-small-angle X-ray scattering instrument for probing the microstructure and the dynamics of soft matter, Journal of Applied Crystallography, vol.40, issue.s1, pp.459-462, 2007. ,
DOI : 10.1107/S0021889806045833
The effect of Brownian motion on the bulk stress in a suspension of spherical particles, Journal of Fluid Mechanics, vol.17, issue.01, p.97, 1977. ,
DOI : 10.1016/0001-8686(72)80001-0
Dynamics of hard spherical colloids from the fluid to the glass, Journal of the Chemical Society, Faraday Transactions, vol.87, issue.3, pp.395-401, 1991. ,
DOI : 10.1039/ft9918700395
Dynamic Structure of Interacting Spherical Polymer Brushes, Langmuir, vol.15, issue.2, pp.358-368, 1999. ,
DOI : 10.1021/la980794j
Kinetic Glass Transition in a Micellar System with Short-Range Attractive Interaction, Physical Review Letters, vol.84, issue.23, pp.5431-5434, 2000. ,
DOI : 10.1103/PhysRevLett.84.5431
Multiple Glassy States in a Simple Model System, Science, vol.296, issue.5565, pp.104-106, 2002. ,
DOI : 10.1126/science.1068238
Re-entrant glass transition and logarithmic decay in a jammed micellar system. Rheology and dynamics investigation, Europhysics Letters (EPL), vol.65, issue.5, pp.712-718, 2004. ,
DOI : 10.1209/epl/i2003-10172-5
URL : https://hal.archives-ouvertes.fr/hal-00015950
Glasses in hard spheres with short-range attraction, Physical Review E, vol.69, issue.1, p.11503, 2004. ,
DOI : 10.1103/PhysRevE.69.011503
Amphiphilic Block Copolymers: Self-Assembly and Applications, Science B. V, 2000. ,
Block Copolymers in Solution: Fundamentals and Applications, 2005. ,
DOI : 10.1002/9780470016985
Block Copolymers : Synhtetic Strategies, Physical Properties, and Applications, 1998. ,
DOI : 10.1002/0471269808
Doctoral Thesis, 2008. ,
Synchrotron Small-Angle X-Ray Scattering, Soft Matter: Scattering, Imaging and Manipulation, 2008. ,
DOI : 10.1007/978-1-4020-4465-6_17
Asymmetric poly(ethylene-alt-propylene)-poly(ethylene oxide) micelles: A system with starlike morphology and interactions, Physical Review E, vol.76, issue.4, p.41503, 2007. ,
DOI : 10.1103/PhysRevE.76.041503
Modern Aspects of Small Angle Scattering; Kluwer Academic; Dordrecht, 1995. ,
Analysis of Classical Statistical Mechanics by Means of Collective Coordinates, Physical Review, vol.110, issue.1, pp.1-13, 1958. ,
DOI : 10.1103/PhysRev.110.1
Development of an ultra-small-angle X-ray scattering instrument for probing the microstructure and the dynamics of soft matter, Journal of Applied Crystallography, vol.40, issue.s1, pp.459-462, 2007. ,
DOI : 10.1107/S0021889806045833
Polymers: Neutron Scattering, 1994. ,
DOI : 10.1016/B0-08-043152-6/01376-0
Structure and properties of tapered block polymers. 4. "Domain-boundary mixing" and "mixing-in-domain" effects on microdomain morphology and linear dynamic mechanical response, Macromolecules, vol.16, issue.4, pp.648-657 ,
DOI : 10.1021/ma00238a031
Microphase Separation and Shear Alignment of Gradient Copolymers: Melt Rheology and Small-Angle X-Ray Scattering Analysis, Macromolecules, vol.41, issue.15, pp.5818-5829, 2008. ,
DOI : 10.1021/ma8009454
Micellization Study on Block and Gradient Copolymer Aqueous Solutions by DLS and SANS, Macromolecules, vol.39, issue.4, pp.1592-1597, 2006. ,
DOI : 10.1021/ma052334k
Concentration dependence of the low-shear viscosity of suspensions of hard-sphere colloids, Physical Review E, vol.55, issue.5, pp.5718-5722, 1997. ,
DOI : 10.1103/PhysRevE.55.5718
Viscosity of Colloidal Suspensions in Aqueous Gelatin, Journal of Colloid and Interface Science, vol.251, issue.1, pp.193-199, 2002. ,
DOI : 10.1006/jcis.2002.8374
Structure and rheology of hyperbranched and dendritic polymers. I. Modification and characterization of poly(propyleneimine) dendrimers with acetyl groups, Journal of Polymer Science Part B: Polymer Physics, vol.38, issue.6, p.857, 2000. ,
DOI : 10.1002/(SICI)1099-0488(20000315)38:6<857::AID-POLB6>3.0.CO;2-4
Rheology of nanosized hairy grain suspensions, The European Physical Journal B, vol.10, issue.1, pp.61-70, 1998. ,
DOI : 10.1007/s100510050830
Concentration dependence of the low-shear viscosity of polyelectrolyte micro-networks: From hard spheres to soft microgels, Europhysics Letters (EPL), vol.47, issue.6, pp.729-735, 1999. ,
DOI : 10.1209/epl/i1999-00451-1
Scaling of the Dynamic Scattering Function of Concentrated Colloidal Suspensions, Physical Review Letters, vol.77, issue.4, pp.771-774, 1996. ,
DOI : 10.1103/PhysRevLett.77.771
Spherical polymeric brushes viewed as soft colloidal particles: zero-shear viscosity, Physica B: Condensed Matter, vol.296, issue.1-3, pp.184-189, 2001. ,
DOI : 10.1016/S0921-4526(00)00798-5
Properties of Polymers, 1997. ,
Polymer Sci, pp.1061-1080, 1993. ,
Elastic properties of soft particle pastes, Journal of Rheology, vol.50, issue.3, pp.353-377, 2006. ,
DOI : 10.1122/1.2186982
URL : https://hal.archives-ouvertes.fr/hal-00069693
Edge fracture in cone-plate and parallel plate flows, Rheologica Acta, vol.38, issue.4, pp.321-348, 1999. ,
DOI : 10.1007/s003970050184
Shear???Thickening (???Dilatancy???) in Suspensions of Nonaggregating Solid Particles Dispersed in Newtonian Liquids, Journal of Rheology, vol.33, issue.2, pp.329-366, 1989. ,
DOI : 10.1122/1.550017
Rheological Properties and Small-Angle Neutron Scattering of a Shear Thickening, Nanoparticle Dispersion at High Shear Rates, Industrial & Engineering Chemistry Research, vol.45, issue.21, pp.7015-7024, 2006. ,
DOI : 10.1021/ie0512690
Influence of medium viscosity and adsorbed polymer on the reversible shear thickening transition in concentrated colloidal dispersions, Rheologica Acta, vol.8, issue.6, pp.360-371, 2005. ,
DOI : 10.1007/s00397-004-0418-z
Shear induced gelation of colloidal dispersions, Journal of Rheology, vol.41, issue.3, p.531, 1997. ,
DOI : 10.1122/1.550874
Reversible shear gelation of polymer???clay dispersions, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.240, issue.1-3, pp.187-198, 2004. ,
DOI : 10.1016/j.colsurfa.2004.04.040
small-angle neutron scattering and rheological measurements of shear-induced gelation, The Journal of Chemical Physics, vol.127, issue.14, p.144507, 2007. ,
DOI : 10.1063/1.2790900
Viscoplastic flow and shear thickening in concentrated diblock copolymer solutions, Colloid & Polymer Science, vol.36, issue.5, pp.480-489, 1995. ,
DOI : 10.1007/BF00656893
Highly anisotropic vorticity aligned structures in a shear thickening attractive colloidal system, Soft Matter, vol.92, issue.5, pp.1388-1392, 2008. ,
DOI : 10.1039/b716324j
Shear thickening and scaling of the elastic modulus in a fractal colloidal system with attractive interactions, Physical Review E, vol.77, issue.6, p.60402, 2008. ,
DOI : 10.1103/PhysRevE.77.060402
Effect of attractions on shear thickening in dense suspensions, Journal of Rheology, vol.48, issue.6, p.1321, 2004. ,
DOI : 10.1122/1.1784785
Nous avons tracé dans la figure 5, l'évolution de la déformation seuil pour une solution de PLMA-PS-PLMA de concentration 0.25 g/g dans l'huile (étudiée à une fréquence de 0, J. Colloid Interface Sci, vol.185, issue.57, 1997. ,
nous nous concentrerons sur le domaine des hautes températures dans lequel nous savons par ailleurs qu'il n'y a pas de rhéo-épaississement ,
au cours du temps la contrainte relaxe par rapport à sa réponse élastique instantanée (?(t?0)) Si nous analysons la courbe obtenue pour un temps d'attente de 10 s, nous observons que la contrainte diminue d'abord rapidement, puis cette diminution ralentit nettement et l'évolution ,
allure des courbes évolue aussi avec le temps d'attente. Ainsi, pour un temps d'attente Références du chapitre 6 ,
Can the gel point of a cross-linking polymer be detected by theG? -G? crossover?, Polymer Engineering and Science, vol.32, issue.22, p.1698, 1987. ,
DOI : 10.1002/pen.760272209
The yield stress???a review or ????????????? ????????????everything flows?, Journal of Non-Newtonian Fluid Mechanics, vol.81, issue.1-2, p.133, 1999. ,
DOI : 10.1016/S0377-0257(98)00094-9
Yielding and Flow of Monodisperse Emulsions, Journal of Colloid and Interface Science, vol.179, issue.2, p.439, 1996. ,
DOI : 10.1006/jcis.1996.0235
The rheology of a concentrated colloidal suspension of hard spheres, Journal of Colloid and Interface Science, vol.147, issue.2, p.479, 1991. ,
DOI : 10.1016/0021-9797(91)90182-8
Glassy Dynamics and Flow Properties of Soft Colloidal Pastes, Physical Review Letters, vol.90, issue.6, p.68303, 2003. ,
DOI : 10.1103/PhysRevLett.90.068303
Structural Similarity and Transition from Newtonian to Non-Newtonian Behavior for Clay-Water Suspensions, Physical Review Letters, vol.74, issue.20, p.3971, 1995. ,
DOI : 10.1103/PhysRevLett.74.3971
Suspensions de microgels polyélectrolytes : propriétés physico-chimiques, rhéologie, écoulement », soutenue le 30, 2000. ,
The mechanical enhancement of physical aging, Polymer, vol.21, issue.8, pp.962-967, 1980. ,
DOI : 10.1016/0032-3861(80)90255-4
Rejuvenation and Overaging in a Colloidal Glass under Shear, Physical Review Letters, vol.89, issue.6, p.65701, 2002. ,
DOI : 10.1103/PhysRevLett.89.065701
URL : https://hal.archives-ouvertes.fr/hal-00020298
Aging and nonlinear rheology in suspensions of polyethylene oxide???protected silica particles, Physical Review E, vol.67, issue.6, p.61403, 2003. ,
DOI : 10.1103/PhysRevE.67.061403
Evolution of Particle-Scale Dynamics in an Aging Clay Suspension, Physical Review Letters, vol.93, issue.22, p.228302, 2004. ,
DOI : 10.1103/PhysRevLett.93.228302
Ultraslow Dynamics and Stress Relaxation in the Aging of a Soft Glassy System, Physical Review Letters, vol.87, issue.24, p.245503, 2001. ,
DOI : 10.1103/PhysRevLett.87.245503
URL : https://hal.archives-ouvertes.fr/hal-00122195
Intrinsic Aging and Effective Viscosity in the Slow Dynamics of a Soft Glass with Tunable Elasticity, Physical Review Letters, vol.94, issue.15, p.158301, 2005. ,
DOI : 10.1103/PhysRevLett.94.158301
URL : https://hal.archives-ouvertes.fr/hal-00003209
Shear thickening and scaling of the elastic modulus in a fractal colloidal system with attractive interactions, Physical Review E, vol.77, issue.6, p.60402 ,
DOI : 10.1103/PhysRevE.77.060402
Scattering Curves of Ordered Mesoscopic Materials, The Journal of Physical Chemistry B, vol.109, issue.4, pp.1347-1360, 2005. ,
DOI : 10.1021/jp0467494
Phase Behavior and Viscoelastic Properties of Thermoplastic Elastomer Gels Based on ABC Triblock Copolymers, Macromolecules, vol.38, issue.18, pp.7798-7806, 2005. ,
DOI : 10.1021/ma050294e