A. E. Adenekan, T. Patzek, and K. Pruess, Modeling of multiphase transport of multicomponent organic contaminants and heat in the subsurface: Numerical model formulation, Water Resources Research, vol.29, issue.5
DOI : 10.1029/93WR01957

J. Auriault, Nonsaturated deformable porous media : quasistatics. Transp. Porous Media 2, pp.45-64, 1987.

J. Auriault and E. Sanchez-palencia, Etude du comportement macroscopique d'un milieu poreux saturé déformable, J. Méc, vol.16, pp.575-603, 1977.

P. Baggio, C. Bonacina, and B. A. Schrefler, Some considerations on modeling heat and mass transfer in porous media, Transport in Porous Media, pp.233-251, 1997.

J. Barthélémy, Effective Permeability of Media with a Dense Network of Long and Micro Fractures, Transport in Porous Media, vol.452, issue.1950, 2008.
DOI : 10.1007/s11242-008-9241-9

Z. P. Bazant and L. N. Najjar, Nonlinear water diffusion in nonsaturated concrete, Mat??riaux et Constructions, vol.27, issue.No. 2, pp.3-20, 1972.
DOI : 10.1007/BF02479073

E. Bemer, P. Longuemare, and O. Vincké, Poroelastic parameters of Meuse/Haute Marne argillites: effect of loading and saturation states, Applied Clay Science, vol.26, issue.1-4, 2004.
DOI : 10.1016/j.clay.2003.12.012

J. Biarez, J. Fleureau, and S. Taibi, Mechanical constitutive model for unsaturated granular media, Second International Conferences on Micromechanics of Granular Media, pp.51-58, 1993.

M. A. Biot, General Theory of Three???Dimensional Consolidation, Journal of Applied Physics, vol.12, issue.2, pp.155-164, 1941.
DOI : 10.1063/1.1712886

URL : https://hal.archives-ouvertes.fr/hal-01368635

A. W. Bishop, The principle of effective stress, Teknisk Ukeblad, vol.39, pp.859-863, 1959.

A. W. Bishop and G. E. Blight, Some Aspects of Effective Stress in Saturated and Partly Saturated Soils, G??otechnique, vol.13, issue.3, pp.117-197, 1963.
DOI : 10.1680/geot.1963.13.3.177

M. Boutéca, Réflexion sur l'origine de l'´ evolution du coefficient de biot des argilites au cours d'un chargement mécanique, Actes des journées scientifiques de l'Andra, 1999.

G. R. Bright, Effective stress evaluation for unsaturated soils, ASCE J. Soil Mech. Found

J. C. Bénet, ContributionàContribution`Contributionà l'´ etude thermodynamique des milieux poreux non saturés avec changement de phase, sciences et techniques du Languedoc, 1981.

X. Chateau and L. Dormieux, Homogénéisation d'un milieu poreux non saturé : lemme de hill et applications, C.R. Acad. Sci. Paris, t, vol.320, pp.627-634, 1995.

X. Chateau and L. Dormieux, Approche microm??canique du comportement d'un milieu poreux non satur??, Comptes Rendus de l'Acad??mie des Sciences - Series IIB - Mechanics-Physics-Astronomy, vol.326, issue.9, pp.533-538, 1998.
DOI : 10.1016/S1251-8069(98)80017-3

X. Chateau and L. Dormieux, The behaviour of unsaturated porous media in the light of a micromechanical approach, Unsaturated Soils for Asia

X. Chen, Effet du chauffage sur le comportement mécanique et poro-mécanique de matériaux cimentaires -propriétés hydrauliques et changements morphologiques, 2009.

A. Chiarelli, Etude expérimentale et modélisation du comportement mécanique de l'argilite de l'est, 2000.

O. Coussy, Mechanics of porous continua, J. Wiley & Sons, 1995.

O. Coussy, R. Eymard, and T. Lassabatère, Constitutive Modeling of Unsaturated Drying Deformable Materials, Journal of Engineering Mechanics, vol.124, issue.6, pp.658-667, 1998.
DOI : 10.1061/(ASCE)0733-9399(1998)124:6(658)

URL : https://hal.archives-ouvertes.fr/hal-00586635

Y. J. Cui and P. Delage, Yielding and plastic behaviour of an unsaturated compacted silt, G??otechnique, vol.46, issue.2
DOI : 10.1680/geot.1996.46.2.291

E. Dana, F. Skoczylas-]-p, L. Dangla, O. Milinsky, and . Coussy, Gas relative permeability and pore structure of sandstones, Numerical models in geomechanics. Balkema, pp.613-625, 1997.
DOI : 10.1016/S0148-9062(99)00037-6

C. Davy, F. Skoczylas, J. Barnichon, and P. Lebon, Permeability of macro-cracked argillite under confinement: Gas and water testing, Physics and Chemistry of the Earth, Parts A/B/C, vol.32, issue.8-14, pp.667-680, 2007.
DOI : 10.1016/j.pce.2006.02.055

URL : https://hal.archives-ouvertes.fr/hal-00155358

C. Davy, F. Skoczylas, P. Lebon, and T. Dubois, Gas migration properties through a bentonite/argillite interface, Applied Clay Science, vol.42, issue.3-4, pp.639-648, 2009.
DOI : 10.1016/j.clay.2008.05.005

URL : https://hal.archives-ouvertes.fr/hal-00342302

J. F. Da¨?anda¨?an, Processus de condensation et de transfert d'eau dans un matériau meso et macroporeux. Etude expérimentale du mortier de ciment, 1986.

A. Degiovanni and C. Moyne, Conductivit?? thermique de mat??riaux poreux humides: ??valuation th??orique et possibilit?? de mesure, International Journal of Heat and Mass Transfer, vol.30, issue.11, pp.2225-2245, 1987.
DOI : 10.1016/0017-9310(87)90217-1

A. Delafargue and F. Ulm, Explicit approximations of the indentation modulus of elastically orthotropic solids for conical indenters, International Journal of Solids and Structures, vol.41, issue.26, pp.7351-7360
DOI : 10.1016/j.ijsolstr.2004.06.019

R. Dingreville, Modeling and characterization of the elastic behavior of interfaces in nanostructured materials : from an atomistic description to a continuum approach, 2007.

L. Dormieux, Equation d'´ etat de la phase argileuse en présence d'effets osmotiques et capillaire

L. Dormieux and E. Bourgeois, IntroductionàIntroduction`Introductionà la micromécanique des milieux poreux, 2002.

L. Dormieux and S. Cariou, Equation d'´ etat de l'argilite avec prise en compte des effets de défauts d'interface

L. Dormieux and D. Kondo, Approche microm??canique du couplage perm??abilit?????endommagement, Comptes Rendus M??canique, vol.332, issue.2, pp.135-140, 2004.
DOI : 10.1016/j.crme.2003.11.003

L. Dormieux, E. Lemarchand, and J. Sanahuja, Comportement macroscopique des mat??riaux poreux ?? microstructure en feuillets, Comptes Rendus M??canique, vol.334, issue.5, pp.304-310, 2006.
DOI : 10.1016/j.crme.2006.03.008

L. Dormieux, J. Sanahuja, and Y. Maalej, R??sistance d'un polycristal avec interfaces intergranulaires imparfaites, Comptes Rendus M??canique, vol.335, issue.1, pp.25-31, 2007.
DOI : 10.1016/j.crme.2006.11.005

H. Ene and E. Sanchez-palencia, Equations et phénomènes de surface pour l'´ ecoulement dans un mdèle de milieu poreux, Journale de Mécanique, vol.14, issue.1, pp.73-108, 1975.

S. Escoffier, Caractérisation expérimentale du comportement hydromécanique des argilites de Meuse/Haute-Marne, 2001.

J. Eshelby, The Determination of the Elastic Field of an Ellipsoidal Inclusion, and Related Problems, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, vol.241, issue.1226, pp.376-396, 1957.
DOI : 10.1098/rspa.1957.0133

]. P. Fillunger, Versuchê uber die zugfestigkeit bei allseitigem wasserdruck, Oesterr. Wochenschrift oeffent. Baudienst, vol.29, pp.443-448, 1915.

P. Fokker, General anisotropic effective medium theory for the effective permeability of heterogeneous reservoirs, Transport in Porous Media, vol.44, issue.2, pp.205-218, 2001.
DOI : 10.1023/A:1010770623874

D. G. Fredlung, R. Morgenstern, and A. Widgerr, The shear strength of unsaturated soils

D. Gallipoli, A. Gens, R. Sharma, and J. Vaunat, An elastoplastic model for unsaturated soil incorporating the effects of suction and degree of saturation on mechanical behaviour

D. Gawin and B. A. Schrefler, Thermo???hydro???mechanical analysis of partially saturated porous materials, Engineering Computations, vol.13, issue.7, pp.113-343, 1996.
DOI : 10.1108/02644409610151584

A. Gens, Constitutive modelling : application to compacted soils, Unsaturated Soils : Proceedings of the 1st International Conference on Unsaturated Soils, pp.1179-1200

W. G. Gray and B. A. Schrefler, Thermodynamic approach to effective stress in partially saturated porous media, European Journal of Mechanics - A/Solids, vol.20, issue.4, pp.521-538, 2001.
DOI : 10.1016/S0997-7538(01)01158-5

D. Grgic, R. Giot, F. Homand, and A. Giraud, Effect of suction on the mechanical behaviour of iron ore rock, International Journal for Numerical and Analytical Methods in Geomechanics, vol.28, issue.8, pp.789-827, 2005.
DOI : 10.1002/nag.438

A. Abou-chakra and . Guery, ContributionsàContributions`Contributionsà la modélisation micromécanique du comportement non linéaire de l'argilite du Callovo-Oxfordien, 2007.

A. Abou-chakra-guéry, F. Cormery, J. Shao, and D. Kondo, Application of a micromechanical model to cavity excavation analysis in argillite, International Journal of Rock Mechanics and Mining Sciences, vol.46, issue.5, 2009.
DOI : 10.1016/j.ijrmms.2008.11.005

Z. Hashin, The Spherical Inclusion With Imperfect Interface, Journal of Applied Mechanics, vol.58, issue.2, pp.444-449, 1991.
DOI : 10.1115/1.2897205

Z. Hashin, Thin interphase/imperfect interface in elasticity with application to coated fiber composites Journal of the Mechanics and Physics of Solids [58] A.V Hershey. The elasticity of an isotropic aggregate of anisotropic cubic crystals, J. Appl. Mech, vol.21, pp.226-240, 1954.

E. Hervé and A. Zaoui, n-layered inclusion-based micromechanical modelling, Int. J. Eng

F. Homand, A. Giraud, S. Escoffier, A. Koriche, and D. Hoxha, Permeability determination of a deep argillite in saturated and partially saturated conditions, International Journal of Heat and Mass Transfer, vol.47, issue.14-16, 2004.
DOI : 10.1016/j.ijheatmasstransfer.2004.02.012

M. Francois, J. Uriot, L. J. Michot, A. Masion, I. Bérend et al., Mechanism of adsorption and desorption of water vapour by homoionic montmorillonite 2. the li + , na + , k + etc. exchanged forms, 1995.

N. Ibrahim, Caractérisation des propriétés mécaniques des géomatériaux par technique de micro indentation, 2008.

J. Israelachvili, Intermolecular and Surface Forces, 1992.

T. Jiang, A. Abou-chakra-guéry, D. Kondo, and J. Shao, Multi-scale modeling for inelastic behavior of a cohesive geomaterial, Mechanics Research Communications, vol.36, issue.6, 2009.
DOI : 10.1016/j.mechrescom.2009.03.007

URL : https://hal.archives-ouvertes.fr/hal-00397556

B. Kari, B. Perrin, and J. C. Foures, Mod??lisation macroscopique des transferts de chaleur et d'humidit?? dans des mat??riaux du b??timent. Les donn??es n??cessaires, Materials and Structures, vol.31, issue.11, pp.482-489, 1992.
DOI : 10.1007/BF02472638

D. Karube and S. Kato, An ideal unsaturated soil and the bishops soil, Proc. 13th Int

L. Klinkenberg, The permeability of porous media to liquids and gases. Drilling and Production Practice, pp.200-213, 1941.

Y. Kohgo, M. Nakano, and T. Miyazaki, theoretical aspects of constitutive modeling for unsaturated soils. Soils and Foundations, pp.49-63, 1993.

A. Koriche, Caractérisation du comportement couplé des argilites de Meuse/Haute-Marne auxétatsauxétats saturé et partiellement saturé, 2004.

E. Kröner, Kontinuumstheorie der Versetzungen und Eigenspannungen, Ergebnisse der angewandten Mathematik, 1958.
DOI : 10.1007/978-3-642-94719-3

P. V. Lade and R. De-boer, The concept of effective stress for soil, concrete and rock, G??otechnique, vol.47, issue.1
DOI : 10.1680/geot.1997.47.1.61

E. Lemarchand, Contribution de la micromécaniquè a l'´ etude des phénomènes de transport et de couplage poromécanique dans les milieux poreux : Appication aux phénomènes de gonflement des géomatériaux, 2001.

M. Lion, F. Skoczylas, and B. Ledésert, Determination of the main hydraulic and poro-elastic properties of a limestone from Bourgogne, France, International Journal of Rock Mechanics and Mining Sciences, vol.41, issue.6, pp.915-925, 2004.
DOI : 10.1016/j.ijrmms.2004.02.005

URL : https://hal.archives-ouvertes.fr/hal-00069671

B. Loret and N. Khalili, An effective stress elastic???plastic model for unsaturated porous media, Mechanics of Materials, vol.34, issue.2, pp.97-116, 2002.
DOI : 10.1016/S0167-6636(01)00092-8

M. Mainguy, Modèle de diffusion non linéaire en milieux poreux : applicationàapplication`applicationà la dissolution et au séchage des matériaux cimentaires, Thèse de doctorat de 3 eme cycle de l'Ecole Nationale des Ponts et Chaussees, 1999.

N. Malikova, A. Cadène, V. Marry, E. Dubois, P. Turq et al., Diffusion of water in clays ??? microscopic simulation and neutron scattering, Chemical Physics, vol.317, issue.2-3, pp.226-235, 2005.
DOI : 10.1016/j.chemphys.2005.04.035

URL : https://hal.archives-ouvertes.fr/hal-00018896

E. L. Matyas and H. S. Radhakrishna, Volume Change Characteristics of Partially Saturated Soils, G??otechnique, vol.18, issue.4, pp.432-448, 1968.
DOI : 10.1680/geot.1968.18.4.432

C. C. Mei and J. Auriault, Mechanics of Heterogeneous Porous Media With Several Spatial Scales, Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, vol.426, issue.1871, pp.391-423, 1989.
DOI : 10.1098/rspa.1989.0132

J. Mitchell, Fundamentals of soil behavior, 1993.

A. Modaressi and N. Abou-bekr, Constitutive model for unsaturated soils ; validation on a silty material, Proceedings of Numerical Methods in Geomechanics, volume NUMOG V 1. Balkema, 1994.

T. Mori and K. Tanaka, Average stress in matrix and average elastic energy of materials with misfitting inclusions, Acta Metallurgica, vol.21, issue.5, pp.571-574, 1973.
DOI : 10.1016/0001-6160(73)90064-3

C. Moyne, Transferts couplés chaleur-masse lors du séchage : prise en compte du mouvement de la phase gazeuse, 1987.

J. P. Nougier, Méthodes de calcul numérique, 1993.

B. E. Novich and T. A. Ring, Colloid Stability of Clays Using Photon Correlation Spectroscopy, Clays and Clay Minerals, vol.32, issue.5, pp.400-406, 1984.
DOI : 10.1346/CCMN.1984.0320508

P. Pellenard, J. Perrin, and S. Bonnet, Mineralogical variability of callovo-oxfordian clays from the paris basin and the subalpine basin Experimental results concerning combined transport of humidity and chloride in non steady state, Chloride Penetration into Concrete, RILEM International Workshop, L.O. Nilsson and J.P. Ollivier editeurs, pp.854-866, 1995.

B. Perrin, V. Bouny, and L. Chemloul, Methods of determination of the hydric diffusivity of hardened cement pastes, Materials and Structures, vol.30, issue.200, pp.235-241, 1998.
DOI : 10.1007/BF02480421

P. Perré and A. Degiovanni, Simulation par volumes finis des transferts coupl??s en milieux poreux anisotropes: s??chage du bois ?? basse et ?? haute temp??rature, International Journal of Heat and Mass Transfer, vol.33, issue.11, pp.2463-2478, 1990.
DOI : 10.1016/0017-9310(90)90004-E

L. and L. Pluart, Nanocomposites : Epoxyde/amine/montmorillonite : Rôle des interactions sur la formation, la morphologie aux différents niveaux d'´ echelle et les propriétés mécaniques des réseaux, 2002.

B. Rotenberg, V. Marry, J. Dufrêche, N. Malikova, E. Giffaut et al., Modelling water and ion diffusion in clays: A multiscale approach, Comptes Rendus Chimie, vol.10, issue.10-11, pp.1108-1116, 2007.
DOI : 10.1016/j.crci.2007.02.009

B. Rotenberg, J. Morel, V. Marry, P. Turq, and N. Morel-desrosiers, On the driving force of cation exchange in clays: Insights from combined microcalorimetry experiments and molecular simulation, Geochimica et Cosmochimica Acta, vol.73, issue.14, pp.4034-4044, 2009.
DOI : 10.1016/j.gca.2009.04.012

URL : https://hal.archives-ouvertes.fr/hal-00391354

F. Salles, Hydratation des argiles gonflantes : Séquence d'hydratation multi-´ echelle ; Détermination desénergiesdesénergies macroscopiquesàmacroscopiques`macroscopiquesà partir des propriétés microscopiques, 1996.

J. Sanahuja, Impact de la morphologie structurale sur les performances mécaniques des matériaux de construction : application au plâtre etàet`età la pâte de ciment, 2008.

J. Sanahuja, L. Dormieux, and G. Chanvillard, Modelling elasticity of a hydrating cement paste, Cement and Concrete Research, vol.37, issue.10, pp.1427-1439, 2007.
DOI : 10.1016/j.cemconres.2007.07.003

J. Sanahuja, L. Dormieux, and G. Chanvillard, A reply to the discussion " does c-s-h particle shape matter ? " f.-j. ulm and h. jennings of the paper " modelling elasticity of a hydrating cemen paste, Cement and Concrete Research, pp.1130-1134, 2007.

J. Sarout, Propriétés physiques et anisotropie des roches argileuses : modélisation micromécanique et expériences triaxiales, 2006.

B. A. Schrefler and D. Gawin, THE EFFECTIVE STRESS PRINCIPLE: INCREMENTAL OR FINITE FORM?, International Journal for Numerical and Analytical Methods in Geomechanics, vol.14, issue.11
DOI : 10.1002/(SICI)1096-9853(199611)20:11<785::AID-NAG848>3.0.CO;2-6

B. A. Schrefler, H. W. Zhang, M. Pastor, and O. Zienkiewicz, Strain localisation modelling and pore pressure in saturated sand samples, Computational Mechanics, vol.22, issue.3, pp.266-280, 1998.
DOI : 10.1007/s004660050359

A. W. Skempton, Effective Stress in Soils, Concrete and Rocks, Proc. Conf. on Pore Pressure and Suction in Soils, pp.4-16, 1960.
DOI : 10.1680/sposm.02050.0014

B. E. Sleep and J. F. Sykes, Compositional simulation of groundwater contamination by organic compounds: 1. Model development and verification, Water Resources Research, vol.29, issue.3, pp.1697-1708, 1993.
DOI : 10.1029/93WR00283

G. Sposito, The Diffuse-Ion Swarm Near Smectite Particles Suspended in 1:1 Electrolyte Solutions, Clays and Clay Minerals, Special Lecture, vol.4, 1989.
DOI : 10.1346/CMS-WLS-4.2

P. Suquet, Continuum micromechanics, chapter Effective behavior of non linear composites . CISM Courses and Lectures n, 1997.

K. Terzaghi, Principles of soil mechanics, a summary of experimental results of clay and sand, Engineering News Record, pp.3-98, 1925.

K. Terzaghi, The shearing resistance of saturated soils and the angle between the planes of shear, First Int. Conf. on Soil Mech. and Found. Engr, pp.54-56, 1936.

B. Viani, P. Low, and C. Roth, Direct measurement of the relation between interlayer force and interlayer distance in the swelling of montmorillonite, Journal of Colloid and Interface Science, vol.96, issue.1, 1983.
DOI : 10.1016/0021-9797(83)90025-5

O. Vincké, M. Boutéca, and P. Longuemarre, Investigation of the Poromechanical Behavior of Shales in the Elastic Domain, SPE/ISRM Rock Mechanics in Petroleum Engineering, pp.515-520, 1998.
DOI : 10.2118/47589-MS

J. J. Vlassak and W. D. Nix, Indentation modulus of elastically anisotropic half spaces, Philosophical Magazine A, vol.8, issue.5
DOI : 10.1016/0022-5096(66)90036-6

D. A. De, A. J. Vries, and . Kruger, On the value of the diffusion coefficient of water vapor in air, Phenomenes de transport avec changement de phase dans les milieux poreux ou colloidaux, Proceedings of CNRS Symposium 160, pp.61-72, 1967.

C. Y. Wang and P. Cheng, A multiphase mixture model for multiphase, multicomponent transport in capillary porous media???I. Model development, International Journal of Heat and Mass Transfer, vol.39, issue.17, pp.393607-3618, 1996.
DOI : 10.1016/0017-9310(96)00036-1

C. C. Wei and K. K. Muraleetharan, A continuum theory of porous media saturated by multiple immiscible fluids: I. Linear poroelasticity, International Journal of Engineering Science, vol.40, issue.16, pp.1807-1833, 2002.
DOI : 10.1016/S0020-7225(02)00068-X

S. J. Wheeler, An elasto-plastic critical state framework for unsaturated soil, G??otechnique, vol.45, issue.1, pp.35-53, 1995.
DOI : 10.1680/geot.1995.45.1.35

Y. Xi, Z. P. Bazant, and H. M. Jennings, Moisture diffusion in cementitious materials Adsorption isotherms, Advanced Cement Based Materials, vol.1, issue.6, pp.248-257, 1994.
DOI : 10.1016/1065-7355(94)90033-7

Y. Xi, Z. P. Bazant, L. Molina, and H. M. Jennings, Moisture diffusion in cementitious materials Moisture capacity and diffusivity, Advanced Cement Based Materials, vol.1, issue.6, pp.258-266, 1994.
DOI : 10.1016/1065-7355(94)90034-5

D. Xin, D. G. Zollinger, and G. D. Allent, An approach to determine diffusivity in hardening concrete based on measured humidity profiles, Advanced Cement Based Materials, pp.138-144, 1995.
DOI : 10.1016/1065-7355(95)90014-4

Z. Zhong and S. A. Meguid, On the elastic field of a spherical inhomogeneity with an imperfectly bonded interface, Journal of Elasticity, vol.46, issue.2, pp.91-113, 1997.
DOI : 10.1023/A:1007342605107

Y. Module-de, coefficient de Poisson (haut, droite), module de compression (milieu, gauche), module de cisaillement (milieu, droite), coefficient de Biot (bas, gauche) et coefficient ? (bas, droite) de la matrice argileuse en fonction du rapport d'aspect des particules, lorsque les pores sont représentés par une morphologie sphérique, p.83

?. Tracé-de-la-courbe-s, eq (s ) ? P eq o , o` u P eq o correspondàcorrespond`correspondà l'´ etat sec des micropores, p.88