E. M. Beccalli, C. La-rosa, and A. Marchesini, Oxidation of 4-aryl-substituted isoxazolin-5-ones. A new synthesis of 2,5-diaryl-1,3-oxazin-6-ones, The Journal of Organic Chemistry, vol.49, issue.22, p.4287, 1984.
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. Danheiser, CuI (1 equiv.), no ligand KHMDS (1 equiv

. Evano, atm) 4A molecular sieves, CH 2 Cl 2, rt, X = BF 3 K until here: cross-coupling reactions described at the time our work was developed 192 For leading references, see: (a) Méndez, CuCl 2 .2H 2 O (15 mol%, p.2

. Am, . Chem, . Soc, A. Fürstner, F. Stelzer et al., 901. 193 For leading references, see: (a) Trost, J. Am. Chem. Soc. Organometallics B. M.; Lee. D. C.; Rise, F Tetrahedron Lett, vol.123, issue.123, pp.11863-11878, 1989.

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1. Och-thfring, 62 (d, J = 1072 (s, 3H, OCH 3 ), 3.68 (s, 3H, OCH 3 ), 3.66 (s, 3H, OCH 3, pp.4-41

. Formal, 67 (s, 3H, OCH 3 ), 3.65 (s, 3H, OCH 3, pp.63-65

1. and O. Ring, 68 (d, J = 1072 (s, 3H, OCH 3 ), 3.70 (s, 3H, OCH 3, Minor diasteroisomer: 5.73 (ddd 1H, CH 2 CH=), 2.65 (d, J = 13.8Hz, 1H, CH 2 ), 2.29 (d, J = 13.8Hz, 1H, CH 2 ), 2.24-2.17 (m, 1H, CH-octahydro-benzofuran ring), 2.17 (td, J = 2.0Hz, J = 17.7Hz, 1H, CH 2 CH=), pp.95787666-95787667

3. Formals, 70 (s, 3H, OCH 3 ), 2.64 (d, J = 15.3Hz, 1H, CH 2 ) (q, J = 4.1Hz, 1H, CH), pp.713277-713278

. Major-diasteroisomer, OCH-THF ring), 76.6 (Cq, C-O-THF ring), 52.0 (Cq), 45.5 (CH), pp.172-176

1. Minor-diasteroisomer and O. Ring, 77 (s, 3H, OCH 3 ), 3.74 (s, 3H, OCH 3 ), 3.16 (ddd, J = 1, dd, J = 2.7Hz, J = 19.2Hz, 1H, CH 2 CH=), pp.7-13

1. Och-thfring, 77 (m, 2H, OCH 2 -THFring), 3.74 (s, 3H, OCH 3 ), 3.70 (s, 3H, OCH 3, pp.4-25

2. Ch-ar, 06 (br s, 1H, CH-Ar), 6.99 (t, J = 7.4Hz, 1H, CH- Ar), 4.00 (br s, 2H, 3 ), 3.22 (s, 3H, NCH 3 ), 2.21 (br s, 1H, CH), p.19

2. Ch-ph and 5. Ch-ph, 86 (t, J = 7.3Hz, 1H, CH-Ph), 6.76 (br s, 2H, CH-Ph), 4.83 (d, J = 17, 3Hz, 1H, NCH 2 ), pp.31-38

N. and O. Mf, N-Hex-5-en-2-ynyl-N'-methyl-N'-phenyl-hydrazinecarboxylic acid methyl ester 6

2. Ch-ph and 1. Ch-ph, 71 (br s, 2H, CH- Ph), 5.77 (ddd, J = 5.2Hz, J = 10, 1H, CH=CH 2 ), 4.61 (br d, J = 17.4Hz, 1H, NCH 2 ), 4.09 (d, J = 17.4Hz, 1H, pp.3-692500

N. Mf, -ynyl-[(4-methylphenyl)sulfonyl]hydrazine 6
URL : https://hal.archives-ouvertes.fr/hal-00094165

2. , C. Ts, 2. Ch-ph, 3. Ch-ph, 1. et al., 19 (dd, J = 7, pp.400-407

N. Meo and O. Mf, -Methoxy-phenyl)-N'-phenyl-N-prop-2-ynyl-hydrazinecarboxylic acid methyl ester 6
URL : https://hal.archives-ouvertes.fr/hal-00655798

N. Mf, Methylene-1-pentyl-3,4-dihydro-1H-cinnoline-2-carboxylic acid methyl ester 6