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Optimisation et simulation du rotomoulage réactif

Abstract : Reactive rotational molding is a process to manufacture hollow plastic parts where synthesis occurs during the shaping. This method has several advantages compared to traditional rotomolding using thermoplastic powders: shorter cycle time, possible use of high performance materials, and decrease of energy consumption and raw materials costs. However reactive rotational molding is more complex to implement mainly because of the important and quick change of viscosity occurring during polymerization. One of the solutions to optimize this process is to simulate the reactive system flow during processing.In this work we used thermoset polyurethane as reactive system. Thanks to thermal and rheological analysis, gelation and vitrification phenomena were studied and Time-Temperature-Transformation diagram was established. Material chemiorheological behavior was also modeled.The process has been simulated using a solver based on Smoothed Particle Hydrodynamics (SPH) method. This solver was developed in our research team and several improvements have been added during this study. To be able to simulate realistic flows with a high number of particles, the first improvement was to accelerate the resolution of calculations. Then the change of viscosity has been taken into account using a chemiorheological model and a new boundary condition was developed to simulate adhesion of polymer on the mold wall. To be able to simulate 3D flows, the needed modifications have been also added to the SPH solver.
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Submitted on : Wednesday, June 26, 2013 - 11:57:19 AM
Last modification on : Wednesday, September 28, 2022 - 5:53:14 AM
Long-term archiving on: : Friday, September 27, 2013 - 4:06:39 AM


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  • HAL Id : pastel-00838690, version 1


Sylvain Riviere. Optimisation et simulation du rotomoulage réactif. Autre. Ecole nationale supérieure d'arts et métiers - ENSAM, 2012. Français. ⟨NNT : 2012ENAM0044⟩. ⟨pastel-00838690⟩



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