Rh(1)-P(1) 159.76(5) C(13)-Rh(1)-Cl(3) 156 C(17)-Rh(1)-Cl(3) 88.81(5) C(18)-Rh(1)-Cl(3) 90 P(1)-Rh(1)-Cl(3) 90, ) C(1)-P(1)-C(4) 110.15(7) C(1)-P(1)-Rh(1) 115.99(6) C(4)-P(1)-Rh, pp.112-117 ,
N(3)-C(37) 1, ) N(4)-C(37) 1, pp.468-476 ,
C(1)-P(1)-Au(1) 109 C(28)-P(1)-Au(1) 117, ) Au(1)-P(1)-Au(2) 100, pp.4-122 ,
N(1)-C(1)-P(1) 128, pp.126-133 ,
C(38)-N(3)-C(40) 120.1(6) C(37)-N(4)-C(39) 110.5(5) C(37)-N(4)-C(52) 128, ) C(39)-N(4)-C(52) 121.0) C(39)-C(38)-N(3) 107.2(6) C(39)-C(38)-H(38) ,
The Organometallic Chemistry Of The Transition Metals, 2009. ,
Effect of structure on the rate of pyramidal inversion of acyclic phosphines, Journal of the American Chemical Society, vol.92, issue.10, pp.3090-3093, 1970. ,
DOI : 10.1021/ja00713a028
Organic Chemistry : Structure And Function, 2002. ,
Application of photoelectron spectroscopy to molecular properties. Part 34. Phosphaethene. Synthesis by vacuum gas-solid reaction (VGSR) and characterization by photoelectron spectroscopy, Journal of the American Chemical Society, vol.110, issue.21, pp.6964-6967, 1988. ,
DOI : 10.1021/ja00229a005
The Chemistry of Phosphinines: Syntheses, Coordination Chemistry and Catalysis, Current Organic Chemistry, vol.10, issue.1, pp.3-25, 2006. ,
DOI : 10.2174/138527206775193004
Metal complexes of heteroarenes. 5. Bis(.eta.6-phosphorin)metal coordination: is there conformational preference?, Organometallics, vol.12, issue.8, pp.3373-3378, 1993. ,
DOI : 10.1021/om00032a071
Metall-komplexe von heteroarenen, Journal of Organometallic Chemistry, vol.459, issue.1-2, pp.157-167, 1993. ,
DOI : 10.1016/0022-328X(93)86068-S
Pentakis(.eta.1-phosphinine)iron: Synthesis, Structure, and Mode of Formation, Journal of the American Chemical Society, vol.116, issue.14, pp.6217-6219, 1994. ,
DOI : 10.1021/ja00093a022
-pentamethylcyclo- pentadienyl)chlororuthenium(II) Complex, Organometallics, vol.15, issue.15, pp.3267-3274, 1996. ,
DOI : 10.1021/om960063j
URL : https://hal.archives-ouvertes.fr/hal-00506747
A 2,2???-Biphosphinine Dianion: Synthesis and Reactivity, Organometallics, vol.18, issue.17, pp.3348-3352, 1999. ,
DOI : 10.1021/om9902176
Synthesis, Unusual Trigonal Prismatic Geometry, and Theoretical Study of the Homoleptic Tris-(2,2???-biphosphinine) Complexes of Chromium, Molybdenum, and Tungsten, Inorganic Chemistry, vol.37, issue.13, pp.3154-3158, 1998. ,
DOI : 10.1021/ic980042c
Phosphabenzenes as Monodentate ??-Acceptor Ligands for Rhodium-Catalyzed Hydroformylation, Chemistry - A European Journal, vol.8, issue.192, pp.3106-3121, 2001. ,
DOI : 10.1002/1521-3765(20010716)7:14<3106::AID-CHEM3106>3.0.CO;2-Y
Multiple Bonds and Low Coordination in Phosphorus Chemistry ; Thieme, 1990. ,
A comparison of the energies of double bonds of second-row elements with carbon and silicon, Journal of the American Chemical Society, vol.110, issue.7, pp.2105-2109, 1988. ,
DOI : 10.1021/ja00215a016
New functional inorganic polymers containing phosphorus, Macromolecular Symposia, vol.196, issue.1, pp.271-278, 2003. ,
DOI : 10.1002/masy.200390166
??1- and ??2-coordination in phosphaalkeneplatinum(0) complexes. High resolution solid state 31P NMR spectrum of mesityl(diphenylmethylene)phosphinebis(triphenylphosphine)platinum(0), Journal of Organometallic Chemistry, vol.280, issue.2, pp.281-287, 1985. ,
DOI : 10.1016/0022-328X(85)88100-6
Expanding the analogy between phosphorus-carbon and carbon-carbon double bonds, Accounts of Chemical Research, vol.25, issue.2, pp.90-96, 1992. ,
DOI : 10.1021/ar00014a006
Synthesis and structure of pentacarbonyl(mesityldiphenylmethylenephosphine)-chromium(0), Journal of Organometallic Chemistry, vol.210, issue.2, pp.211-221, 1981. ,
DOI : 10.1016/S0022-328X(00)82233-0
Chelating phosphines with low coordinated phosphorus atoms Part I. Phosphaalkenes associated with phosphine moieties???X-ray structure of cis-(CO)4Mo[ortho-Ph2P_C6H4_CH=P(t-Bu3C6H2)]??C7H16, Journal of Organometallic Chemistry, vol.626, issue.1-2, pp.106-112, 2001. ,
DOI : 10.1016/S0022-328X(01)00654-4
Niederkoordinierte phosphorverbindungen, Journal of Organometallic Chemistry, vol.347, issue.3, pp.299-306, 1988. ,
DOI : 10.1016/0022-328X(88)80153-0
Synthesis of a phosphavinyl complex via shift of a pentamethylcyclopentadienyl from phosphorus to iron, Organometallics, vol.5, issue.3, pp.593-595, 1986. ,
DOI : 10.1021/om00134a036
The Benzodiphosphaalkene Ligand and Its PdII and PtII Complexes: Their Synthesis, Structure, and an ESR Study of Their Reduction Products, Journal of the American Chemical Society, vol.117, issue.8, pp.2251-2258, 1995. ,
DOI : 10.1021/ja00113a014
1,3-Diphosphapropenes for novel chemistry of metal complexes, Journal of Organometallic Chemistry, vol.690, issue.10, pp.2531-2535, 2005. ,
DOI : 10.1016/j.jorganchem.2004.09.045
Preparation, properties, and catalytic activity of transition-metal complexes containing a ligated 2-methyl-3,3-diphenyl-1,3-diphosphapropene skeleton, Tetrahedron Letters, vol.44, issue.45, pp.8297-8300, 2003. ,
DOI : 10.1016/j.tetlet.2003.09.073
Synthesis, Structures, and Reactions of Methylplatinum(II) and -palladium(II) Complexes Bearing Diphosphinidenecyclobutene Ligands (DPCB-Y), Organometallics, vol.23, issue.6, pp.1325-1332, 2004. ,
DOI : 10.1021/om030676d
Catalytic C???O Bond Cleavage of Allylic Alcohols Using Diphosphinidenecyclobutene-Coordinated Palladium Complexes. A Mechanistic Study, Organometallics, vol.23, issue.8, pp.1698-1707, 2004. ,
DOI : 10.1021/om030682+
Synthesis and Reactions of Diphosphinidenecyclobutene Ruthenium Complexes Relevant to Catalytic Hydrosilylation of Terminal Alkynes, Organometallics, vol.27, issue.10, pp.2321-2327, 2008. ,
DOI : 10.1021/om800119f
Complex formation between nickel(0) and a phosphaalkene: Influence of the second ligand on the ??1- and ??2-coordination mode, Journal of Organometallic Chemistry, vol.254, issue.3, pp.33-36, 1983. ,
DOI : 10.1016/0022-328X(83)80143-0
Influence of steric factors on the coordination mode (.eta.1 or .eta.2) of phosphaalkenes to zerovalent Pt0L2 centers. X-ray structure of bis(triphenylphosphine)[(2,6-dimethylphenyl)-9-fluorenylidenephosphine]platinum(0)-toluene, Organometallics, vol.5, issue.10, pp.2014-2020, 1986. ,
DOI : 10.1021/om00141a014
Synthesis and structures of platinum diphenylacetylene and dithiolate complexes bearing diphosphinidenecyclobutene ligands (DPCB-Y), New Journal of Chemistry, vol.93, issue.8, pp.1713-1722, 2010. ,
DOI : 10.1039/c0nj00118j
Ligand effect of bulky 2,2-dialkyl-1-phosphaethenes on Au-catalyzed cycloisomerization of 1,6-enynes and lactonization of pent-4-ynoic acids, Journal of Organometallic Chemistry, vol.695, issue.2, pp.291-296, 2010. ,
DOI : 10.1016/j.jorganchem.2009.09.040
Dehydrogenative Silylation of Ketones Catalyzed by Diphosphinidenecyclobutene-Coordinated Platinum(II) Complexes, Chemistry Letters, vol.30, issue.10, pp.972-973, 2001. ,
DOI : 10.1246/cl.2001.972
Preparation and Structure of Dichloropalladium(II) Complexes of Sterically Protected Diphosphinidenecyclobutenes and Their Synthetic Application as Homogeneous Catalyst, Chemistry Letters, vol.24, issue.3, pp.221-222, 1995. ,
DOI : 10.1246/cl.1995.221
Synthesis and Reactions of Palladium and Platinum Complexes Bearing Diphosphinidenecyclobutene Ligands: A Thermally Stable Catalyst for Ethylene Polymerization, Angewandte Chemie International Edition, vol.17, issue.24, pp.4512-4513, 2000. ,
DOI : 10.1002/1521-3773(20001215)39:24<4512::AID-ANIE4512>3.0.CO;2-I
(??3-Allyl)palladium Complexes Bearing Diphosphinidenecyclobutene Ligands: Highly Active Catalysts for the Hydroamination of 1,3-Dienes This work was supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science, Sports and Culture, Japan., Angewandte Chemie International Edition, vol.40, issue.23, pp.4501-4503, 2001. ,
DOI : 10.1002/1521-3773(20011203)40:23<4501::AID-ANIE4501>3.0.CO;2-K
(??-Allyl)palladium Complexes Bearing Diphosphinidenecyclobutene Ligands (DPCB):?? Highly Active Catalysts for Direct Conversion of Allylic Alcohols, Journal of the American Chemical Society, vol.124, issue.37, pp.10968-10969, 2002. ,
DOI : 10.1021/ja0274406
Solvent Free Amination Reactions of Aryl Bromides at Room Temperature Catalyzed by a (??-Allyl)palladium Complex Bearing a Diphosphinidenecyclobutene Ligand, The Journal of Organic Chemistry, vol.69, issue.19, pp.6504-6506, 2004. ,
DOI : 10.1021/jo049087n
Phosphinidine-Palladium Complexes for the Polymerization and Oligomerization of Ethylene, Organometallics, vol.21, issue.26, pp.5935-5943, 2002. ,
DOI : 10.1021/om020631x
Phosphaalkenes palladium(II) complexes in the suzuki and sonogashira cross-coupling reactions, Heteroatom Chemistry, vol.82, issue.4, pp.363-371, 2007. ,
DOI : 10.1002/hc.20307
URL : https://hal.archives-ouvertes.fr/hal-00168490
Cyclodehydration of cis???2-butene-1,4-diol with active methylene compounds catalyzed by a diphosphinidenecyclobutene-coordinated palladium complex, Journal of Organometallic Chemistry, vol.691, issue.14, pp.3151-3156, 2006. ,
DOI : 10.1016/j.jorganchem.2006.03.011
Synthesis, Structures, and Catalytic Properties of Late-Transition-Metal 2,6-Bis(2-phosphaethenyl)pyridine Complexes, Organometallics, vol.26, issue.21, pp.5246-5249, 2007. ,
DOI : 10.1021/om700488y
P,N-Chelate Complexes of Pd(II) and Pt(II) Based on a Phosphaalkene Motif:?? A Catalyst for the Overman???Claisen Rearrangement, Organometallics, vol.26, issue.25, pp.6481-6486, 2007. ,
DOI : 10.1021/om700784x
Phospha-Organic Chemistry: Panorama and Perspectives, Angewandte Chemie International Edition, vol.42, issue.14, pp.1578-1604, 2003. ,
DOI : 10.1002/anie.200200557
Coordination Behavior of Sterically Protected Phosphaalkenes on the AuCl Moiety Leading to Catalytic 1,6-Enyne Cycloisomerization, Chemistry ??? An Asian Journal, vol.27, issue.5, pp.693-700, 2006. ,
DOI : 10.1002/asia.200600155
Kupferkomplexe von invers polarisierten Phosphaalkenen RP=C(NMe2)2 (R =t-Bu, Ph). Molek???lstruktur von [Cu3Cl3{?-P(t-Bu)C(NMe2)2}3], Zeitschrift f???r anorganische und allgemeine Chemie, vol.29, issue.13-14, pp.2478-2482, 2004. ,
DOI : 10.1002/zaac.200400233
], Organometallics, vol.22, issue.24, pp.5063-5068, 2003. ,
DOI : 10.1021/om030578s
Recent developments in the chemistry of metallophosphaalkenes, Coordination Chemistry Reviews, vol.249, issue.7-8, pp.741-763, 2005. ,
DOI : 10.1016/j.ccr.2004.08.005
Synthesis of mesityldiphenylmethylenephosphine: a stable compound with a localized phosphorus:carbon bond, Journal of the American Chemical Society, vol.100, issue.15, pp.4886-4888, 1978. ,
DOI : 10.1021/ja00483a041
Bildung und Eigenschaften von Acylphosphinen. I. Monosubstitutionsreaktionen an substituierten Disilylphosphinen mit Pivaloylchlorid, Zeitschrift f???r anorganische und allgemeine Chemie, vol.103, issue.3, pp.242-254, 1976. ,
DOI : 10.1002/zaac.19764230309
Phosphaalkynes and phosphaalkenes, Tetrahedron, vol.45, issue.19, pp.6019-6090, 1989. ,
DOI : 10.1016/S0040-4020(01)85121-8
Chlormethylchlorphosphane R(Cl)P???CH2???Cl - synthone f??r den aufbau von phosphaalkenen im metalltemplat, Journal of Organometallic Chemistry, vol.462, issue.1-2, pp.111-123, 1993. ,
DOI : 10.1016/0022-328X(93)83348-Y
Synthesis and structure of aryl-substituted phospha-alkenes, Tetrahedron, vol.40, issue.4, pp.765-776, 1984. ,
DOI : 10.1016/S0040-4020(01)91106-8
Phospha-alkene durch thermische, basen- oder metall-induzierte eliminierung, Tetrahedron Letters, vol.22, issue.49, pp.4957-4960, 1981. ,
DOI : 10.1016/S0040-4039(01)92391-3
Synthesis and investigation of new types of dicoordinated phosphorus compounds, Phosphorus and Sulfur and the Related Elements, vol.52, issue.1-3, pp.31-34, 1983. ,
DOI : 10.1080/03086648308075960
Scope and Limitations of the Base-Catalyzed Phospha-Peterson PC Bond-Forming Reaction, Inorganic Chemistry, vol.45, issue.13, pp.5225-5234, 2006. ,
DOI : 10.1021/ic060236p
Phospha-amidine, Journal of Organometallic Chemistry, vol.160, issue.1, pp.47-57, 1978. ,
DOI : 10.1016/S0022-328X(00)91197-5
Acyl- und Alkylidenphosphane. XII [1]. Synthese und Eigenschaften des 2,2-Dimethylpropionylphosphans und einiger Derivate, Zeitschrift f???r anorganische und allgemeine Chemie, vol.13, issue.1, pp.7-19, 1981. ,
DOI : 10.1002/zaac.19814730202
Easy Synthesis of Phosphaalkenes by a Phosphorus-Analogous Isocyanide Reaction and an Atypical Crystal Structure of a Tetracarbonyl(phosphaalkene)iron Complex, Angewandte Chemie International Edition in English, vol.23, issue.11, p.895, 1984. ,
DOI : 10.1002/anie.198408951
Thermal isomerization of a secondary vinylphosphine into a phosphaalkene, Tetrahedron Letters, vol.30, issue.18, pp.2397-2398, 1989. ,
DOI : 10.1016/S0040-4039(01)80409-3
Prototropy in H???P???C???C triad of alkyl(??-ethoxyethenyl)phosphines, Tetrahedron Letters, vol.36, issue.23, pp.4121-4124, 1995. ,
DOI : 10.1016/0040-4039(95)00674-2
A Convenient Synthesis of New Isolable Phosphaalkenes Using the Base-Induced Rearrangement of Secondary Vinylphosphines, Inorganic Chemistry, vol.43, issue.12, pp.3719-3723, 2004. ,
DOI : 10.1021/ic049796j
The "phospha-Wittig" reaction: a new method for building phosphorus-carbon double and single bonds from carbonyl compounds, Organometallics, vol.9, issue.3, pp.793-798, 1990. ,
DOI : 10.1021/om00117a040
Phospha-Wittig reaction in the synthesis of 1-phosphadienes and (.eta.4-1-phosphadiene)tricarbonyliron complexes from .alpha.,.beta.-unsaturated aldehydes, Organometallics, vol.9, issue.3, pp.788-793, 1990. ,
DOI : 10.1021/om00117a039
Synthesis of 1-phosphacycloalkene phosphorus-metal(CO)5 complexes (M = Cr, W) by intramolecular phospha-Wittig reactions, Organometallics, vol.10, issue.4, pp.1190-1195, 1991. ,
DOI : 10.1021/om00050a061
Synthesis, structure, and reactivity of (phosphoranylidenephosphine)pentacarbonyltungsten complexes. Another access to the phosphorus-carbon double bond, Journal of the American Chemical Society, vol.112, issue.6, pp.2407-2410, 1990. ,
DOI : 10.1021/ja00162a051
Phosphinidene Transfer Reactions of the Terminal Phosphinidene Complex Cp2Zr(:PC6H2-2,4,6-t-Bu3)(PMe3), Journal of the American Chemical Society, vol.117, issue.48, pp.11914-11921, 1995. ,
DOI : 10.1021/ja00153a013
Synthesis and structural investigation of [mesityl(diphenylmethylene)phosphine]bis(triphenylphosphine)platinum(0), Journal of the American Chemical Society, vol.104, issue.6, pp.1756-1757, 1982. ,
DOI : 10.1021/ja00370a060
The Chemistry of Pincer Compounds, 2007. ,
Metal Insertion into C???C Bonds in Solution, Angewandte Chemie International Edition, vol.38, issue.7, pp.870-883, 1999. ,
DOI : 10.1002/(SICI)1521-3773(19990401)38:7<870::AID-ANIE870>3.0.CO;2-3
Highly Active Pd(II) PCP-Type Catalysts for the Heck Reaction, Journal of the American Chemical Society, vol.119, issue.48, pp.11687-11688, 1997. ,
DOI : 10.1021/ja9729692
Palladacycles in catalysis ??? a critical survey, Journal of Organometallic Chemistry, vol.689, issue.24, pp.4055-4082, 2004. ,
DOI : 10.1016/j.jorganchem.2004.07.054
Catalysis by Palladium Pincer Complexes, Chemical Reviews, vol.111, issue.3, pp.2048-2076, 2011. ,
DOI : 10.1021/cr1002112
URL : http://doi.org/10.1021/cr1002112
Palladium bis(phosphinite) ???PCP???-pincer complexes and their application as catalysts in the Suzuki reaction, New Journal of Chemistry, vol.24, issue.10, pp.745-747, 2000. ,
DOI : 10.1039/b004793g
The 1,3-Diaminobenzene-Derived Aminophosphine Palladium Pincer Complex {C6H3[NHP(piperidinyl)2]2Pd(Cl)} - A Highly Active Suzuki-Miyaura Catalyst with Excellent Functional Group Tolerance, Advanced Synthesis & Catalysis, vol.24, issue.6, pp.1075-1080, 2010. ,
DOI : 10.1002/adsc.200900848
Pincer Thioamide and Pincer Thioimide Palladium Complexes Catalyze Highly Efficient Negishi Coupling of Primary and Secondary Alkyl Zinc Reagents at Room Temperature, Chemistry - A European Journal, vol.12, issue.6, pp.1499-1507, 2009. ,
DOI : 10.1002/chem.200801860
Identification of a Highly Efficient Alkylated Pincer Thioimido-Palladium(II) Complex as the Active Catalyst in Negishi Coupling, Chemistry - A European Journal, vol.13, issue.17, pp.4437-4445, 2009. ,
DOI : 10.1002/chem.200802238
A Nonsymmetric Pincer-Type Palladium Catalyst In Suzuki, Sonogashira, and Hiyama Couplings in Neat Water, Organometallics, vol.27, issue.12, pp.2833-2839, 2008. ,
DOI : 10.1021/om800175a
)-1,3-Bis[1-(diphenylphosphino)ethyl]benzene. Use in the Asymmetric Aldol Reaction of Methyl Isocyanoacetate and Aldehydes, Organometallics, vol.17, issue.20, pp.4374-4379, 1998. ,
DOI : 10.1021/om980461h
Palladium Pincer Complex-Catalyzed Condensation of Sulfonimines and Isocyanoacetate to Imidazoline Derivatives. Dependence of the Stereoselectivity on the Ligand Effects, Advanced Synthesis & Catalysis, vol.11, issue.17-18, pp.2585-2594, 2007. ,
DOI : 10.1002/adsc.200700242
NCN Pincer Palladium Complexes:?? Their Preparation via a Ligand Introduction Route and Their Catalytic Properties, Journal of the American Chemical Society, vol.127, issue.35, pp.12273-12281, 2005. ,
DOI : 10.1021/ja052780n
Palladium-Catalyzed Asymmetric Addition of Diarylphosphines to Enones toward the Synthesis of Chiral Phosphines, Journal of the American Chemical Society, vol.132, issue.16, pp.5562-5563, 2010. ,
DOI : 10.1021/ja100606v
The uses of pincer complexes in organic synthesis, Tetrahedron, vol.59, issue.11, pp.1837-1857, 2003. ,
DOI : 10.1016/S0040-4020(02)01511-9
Platinum Group Organometallics Based on ???Pincer??? Complexes: Sensors, Switches, and Catalysts, Angewandte Chemie International Edition, vol.57, issue.302, pp.3750-3781, 2001. ,
DOI : 10.1002/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO;2-6
Cyclometalated Phosphine-Based Pincer Complexes:?? Mechanistic Insight in Catalysis, Coordination, and Bond Activation, Chemical Reviews, vol.103, issue.5, pp.1759-1792, 2003. ,
DOI : 10.1021/cr960118r
Bis(imino)pyridines:?? Surprisingly Reactive Ligands and a Gateway to New Families of Catalysts, Chemical Reviews, vol.107, issue.5, pp.1745-1776, 2007. ,
DOI : 10.1021/cr068437y
Iron and Cobalt Ethylene Polymerization Catalysts:?? Variations on the Central Donor, Inorganic Chemistry, vol.42, issue.11, pp.3454-3465, 2003. ,
DOI : 10.1021/ic034040q
Iron-Based Catalysts with Exceptionally High Activities and Selectivities for Oligomerization of Ethylene to Linear ??-Olefins, Journal of the American Chemical Society, vol.120, issue.28, pp.7143-7144, 1998. ,
DOI : 10.1021/ja981317q
Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes, Chemical Reviews, vol.111, issue.3, pp.1761-1779, 2011. ,
DOI : 10.1021/cr1003503
Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2, Science, vol.317, issue.5839, pp.790-792, 2007. ,
DOI : 10.1126/science.1145295
Synthesis of new chelating agents: Association of a phosphaalkene moiety with a pyridine., Tetrahedron Letters, vol.33, issue.35, pp.5071-5074, 1992. ,
DOI : 10.1016/S0040-4039(00)61192-9
Synthesis, structure and ??-delocalization of a phosphaalkenyl based neutral PNP-pincer, Inorganica Chimica Acta, vol.374, issue.1, pp.211-215, 2011. ,
DOI : 10.1016/j.ica.2011.02.078
Electronic Structure of Four-Coordinate Iron(I) Complex Supported by a Bis(phosphaethenyl)pyridine Ligand, Journal of the American Chemical Society, vol.132, issue.29, pp.9934-9936, 2010. ,
DOI : 10.1021/ja102009n
Reagents for Transition Metal Complex and Organometallic Syntheses, 1990. ,
Thermal reactions of (2,4,6-tri-butylphenyl)phosphonous dichloride and its derivatives; formation of 2,3-dihydro-1h-phosphinodes, Tetrahedron Letters, vol.24, issue.9, pp.933-936, 1983. ,
DOI : 10.1016/S0040-4039(00)81569-5
Generation and reactivity of a 3H-phosphaindene: the first 3H-phosphole, Tetrahedron Letters, vol.40, issue.28, pp.5271-5274, 1999. ,
DOI : 10.1016/S0040-4039(99)00999-5
Flash vacuum pyrolysis of dichlorophosphines over magnesium: Generation and reactivity of simple phosphinidenes, Tetrahedron Letters, vol.38, issue.48, pp.8417-8420, 1997. ,
DOI : 10.1016/S0040-4039(97)10236-2
Dehydrocoupling of Phosphanes Catalyzed by a Rhodium(I) Complex, Angewandte Chemie International Edition, vol.47, issue.24, pp.4694-4696, 2001. ,
DOI : 10.1002/1521-3773(20011217)40:24<4694::AID-ANIE4694>3.0.CO;2-7
Catalytic P???H Activation by Ti and Zr Catalysts, Chemistry - A European Journal, vol.4, issue.34, pp.8696-8707, 2006. ,
DOI : 10.1002/chem.200600429
-Cymene Ligand as Reactivity Switch, Organometallics, vol.26, issue.20, pp.5091-5101, 2007. ,
DOI : 10.1021/om7004854
URL : https://hal.archives-ouvertes.fr/tel-00391857
Synthesis and Decarbonylation Reactions of Diiron Cyclopentadienyl Complexes with Bent-Phosphinidene Bridges, Organometallics, vol.30, issue.5, pp.1102-1115, 2011. ,
DOI : 10.1021/om101125g
A Lanthanide Phosphinidene Complex:?? Synthesis, Structure, and Phospha-Wittig Reactivity, Journal of the American Chemical Society, vol.130, issue.8, pp.2408-2409, 2008. ,
DOI : 10.1021/ja7105306
Synthesis and structure of bis(2,4,6-tri-tert-butylphenyl)diphosphene: isolation of a true phosphobenzene, Journal of the American Chemical Society, vol.103, issue.15, pp.4587-4589, 1981. ,
DOI : 10.1021/ja00405a054
Systematic Studies on Homo- and Heteronuclear Doubly Bonded Compounds of Heavier Group 15 Elements, Phosphorus, Sulfur, and Silicon and the Related Elements, vol.177, issue.6-7, pp.1473-1476, 2002. ,
DOI : 10.1002/1521-3773(20020104)41:1<139::AID-ANIE139>3.0.CO;2-3
Photochemical Reactions of Diphosphenes Carrying 2,4,6-Tris(trifluoromethyl)phenyl Group, Bulletin of the Chemical Society of Japan, vol.66, issue.5, pp.1572-1575, 1993. ,
DOI : 10.1246/bcsj.66.1572
Electrophilic additions to diphosphenes (RP:PR), Journal of the American Chemical Society, vol.105, issue.14, pp.4845-4846, 1983. ,
DOI : 10.1021/ja00352a059
Sulfur cleavage of a phosphorus-phosphorus double bond, Tetrahedron Letters, vol.25, issue.20, pp.2125-2126, 1984. ,
DOI : 10.1016/S0040-4039(01)81178-3
Photochemistry of functionalized diphosphiranes, The Journal of Organic Chemistry, vol.55, issue.22, pp.5750-5756, 1990. ,
DOI : 10.1021/jo00309a019
Cationic ring opening of functionalized diphosphiranes, Tetrahedron Letters, vol.30, issue.52, pp.7411-7414, 1989. ,
DOI : 10.1016/S0040-4039(00)70711-8
New approaches to the generation of phosphinidenes, Journal of the American Chemical Society, vol.114, issue.8, pp.3142-3144, 1992. ,
DOI : 10.1021/ja00034a073
Etude de la reactivite du tris(tertiobutyl)phenyldithiophosphorane, Tetrahedron Letters, vol.26, issue.2, pp.207-210, 1985. ,
DOI : 10.1016/S0040-4039(00)61881-6
:?? Mechanistic Studies of a Catalytic Intramolecular C???H Bond Activation Reaction, Organometallics, vol.21, issue.6, pp.1008-1010, 2002. ,
DOI : 10.1021/om010952t
Destiny of Transient Phosphenium Ions Generated from the Addition of Electrophiles to Phosphaalkenes:?? Intramolecular C???H Activation, Donor???Acceptor Formation, and Linear Oligomerization, Organometallics, vol.23, issue.25, pp.5913-5923, 2004. ,
DOI : 10.1021/om0495022
Platinum(0)-Catalyzed Intramolecular Addition of a C???H Bond onto the P???C Bond of a Phosphaalkene, Organometallics, vol.28, issue.20, pp.5952-5959, 2009. ,
DOI : 10.1021/om9006664
Handbook of Chemistry and Physics, 2005. ,
Acyl- und Alkylidenphosphane. XVI. (Dimethylaminomethyliden)- und (Diphenylmethyliden)phosphane, Zeitschrift f???r anorganische und allgemeine Chemie, vol.13, issue.1, pp.41-56, 1981. ,
DOI : 10.1002/zaac.19814790805
Phosphatriafulvenes - phosphaalkenes with inverse electron density, Tetrahedron Letters, vol.30, issue.38, pp.5111-5114, 1989. ,
DOI : 10.1016/S0040-4039(01)93461-6
Organophosphorverbindungen, 511) Phosphatriafulvene ??? Phosphaalkene mit inverser Elektronendichte2), Chemische Berichte, vol.103, issue.12, pp.2843-2855, 1991. ,
DOI : 10.1002/cber.19911241228
Synthese von aryl-dialkylaminoalkylidenphosphinen - ein neuer zugang zu derivaten des zweifach-koordinierten dreibindigen phosphors, Tetrahedron Letters, vol.21, issue.12, pp.1141-1144, 1981. ,
DOI : 10.1016/S0040-4039(01)83934-4
Aryl-bis(dimethylamino)methylidenphosphine, Zeitschrift f??r Chemie, vol.24, issue.11, pp.407-408, 1981. ,
DOI : 10.1002/zfch.19810211110
PH-funktionelle Dialkylaminoalkylidenphosphine, Zeitschrift f??r Chemie, vol.3, issue.3, pp.99-100, 1983. ,
DOI : 10.1002/zfch.19830230308
A Carbene???Phosphinidene Adduct: ???Phosphaalkene???, Chemistry Letters, vol.26, issue.2, pp.143-144, 1997. ,
DOI : 10.1246/cl.1997.143
Carbene???Pnictinidene Adducts, Inorganic Chemistry, vol.36, issue.10, pp.2151-2158, 1997. ,
DOI : 10.1021/ic970174q
P???NMR Chemical Shifts of Carbene-Phosphinidene Adducts as an Indicator of the ??-Accepting Properties of Carbenes, Angewandte Chemie International Edition, vol.127, issue.10, pp.2939-2943, 2013. ,
DOI : 10.1002/anie.201209109
Reaktive E???C (p???p) ??-Systeme, XIV. Synthese und Struktur von Phosphaalkenen des Typs F3CP???C(F)NR2, Chemische Berichte, vol.98, issue.4, pp.655-664, 1988. ,
DOI : 10.1002/cber.19881210411
Transition-Metal-Substituted Acylphosphanes and Phosphaalkenes, 35 Unprecedented Coupling of a Transition-Metal Carbyne and a Methylene Phosphane Moiety ??? Structure of [Tp'(CO)2W=CP=C(NEt2)2] [Tp = HB (3,5-Me2HC3N2)3], Chemische Berichte, vol.1988, issue.9, pp.1305-1308, 1997. ,
DOI : 10.1002/cber.19971300920
Synthesis of the first stable metadithiophosphonate, Tetrahedron Letters, vol.24, issue.52, pp.5885-5886, 1983. ,
DOI : 10.1016/S0040-4039(00)94227-8
Platinum-vinylsiloxanes, 1973. ,
Why Does the Rhodium-Catalyzed Hydrosilylation of Alkenes Take Place through a Modified Chalk???Harrod Mechanism? A Theoretical Study, Organometallics, vol.21, issue.18, pp.3788-3802, 2002. ,
DOI : 10.1021/om020239j
Stable Carbenes, Chemical Reviews, vol.100, issue.1, pp.39-91, 2000. ,
DOI : 10.1021/cr940472u
URL : https://hal.archives-ouvertes.fr/hal-00947100
Stable Noncyclic Singlet Carbenes, Chemical Reviews, vol.109, issue.8, pp.3333-3384, 2009. ,
DOI : 10.1021/cr800549j
URL : https://hal.archives-ouvertes.fr/hal-00947100
Nucleophilic Phosphinidene Complexes: Access and Applicability, Angewandte Chemie International Edition, vol.48, issue.618, pp.2102-2113, 2010. ,
DOI : 10.1002/anie.200905689
Electrophilic Terminal-Phosphinidene Complexes: Versatile Phosphorus Analogues of Singlet Carbenes, Helvetica Chimica Acta, vol.84, issue.10, pp.2938-2957, 2001. ,
DOI : 10.1002/1522-2675(20011017)84:10<2938::AID-HLCA2938>3.0.CO;2-P
Phosphinidenes, Top. Curr. Chem, vol.229, pp.95-119, 2003. ,
DOI : 10.1007/b11152
Formation and reactivity of the early metal phosphides and phosphinidenes Cp*2Zr:PR, Cp*2Zr(PR)2, and Cp*2Zr(PR)3, Organometallics, vol.12, issue.8, pp.3158-3167, 1993. ,
DOI : 10.1021/om00032a044
Arsinidene, Phosphinidene, and Imide Formation via 1,2-H2-Elimination from (silox)3HTaEHPh (E = N, P, As): Structures of (silox)3Ta:EPh (E = P, As), Journal of the American Chemical Society, vol.116, issue.24, pp.11159-11160, 1994. ,
DOI : 10.1021/ja00103a042
Reactions of chloro((tri-2,4,6-tert-butylphenyl)imino)phosphane with anionic transition-metal complexes: stable metalloiminophosphanes and evidence for terminal aminophosphinidene complexes, Organometallics, vol.8, issue.9, pp.2290-2291, 1989. ,
DOI : 10.1021/om00111a039
Four-Coordinate Phosphinidene Complexes of Titanium Prepared by ??-H-Migration:?? Phospha-Staudinger and Phosphaalkene-Insertion Reactions, Journal of the American Chemical Society, vol.125, issue.34, pp.10170-10171, 2003. ,
DOI : 10.1021/ja036559r
P???H-Functionalized Phosphenium Complexes[C5R5(OC)2 W???P(H)R???](R???=tBu, sMes): Synthesis, Isomerization, and Transformation into Hydrido Complexes Containing atBuP(H)OH Ligand, Angewandte Chemie International Edition in English, vol.34, issue.22, pp.2500-2502, 1995. ,
DOI : 10.1002/anie.199525001
Monomeric Phosphido and Phosphinidene Complexes of Nickel, Journal of the American Chemical Society, vol.124, issue.15, pp.3846-3847, 2002. ,
DOI : 10.1021/ja017787t
Cleavage of a phosphorus-carbon double bond and formation of a linear terminal phosphinidene complex, Journal of the American Chemical Society, vol.112, issue.18, pp.6734-6735, 1990. ,
DOI : 10.1021/ja00174a056
Synthesis of Novel Terminal Iridium Phosphinidene Complexes, Organometallics, vol.21, issue.15, pp.3196-3202, 2002. ,
DOI : 10.1021/om020062t
Reactive Intermediates: A Transient Electrophilic Phosphinidene Caught in the Act, Chemistry - A European Journal, vol.11, issue.5, pp.1454-1458, 2010. ,
DOI : 10.1002/chem.200902715
-Phosphirene, Journal of the American Chemical Society, vol.125, issue.9, pp.2404-2405, 2003. ,
DOI : 10.1021/ja028303b
Synthesis and Structural Characterization of the First Thermally Stable, Neutral, and Electrophilic Phosphinidene Complexes of Vanadium, Organometallics, vol.30, issue.6, pp.1382-1388, 2011. ,
DOI : 10.1021/om100915v
Generation and trapping of terminal phosphinidene complexes. Synthesis and x-ray crystal structure of stable phosphirene complexes, Journal of the American Chemical Society, vol.104, issue.16, pp.4484-4485, 1982. ,
DOI : 10.1021/ja00380a029
Terminal aminophosphinidene complexes. A new approach, Journal of the American Chemical Society, vol.111, issue.25, pp.9098-9100, 1989. ,
DOI : 10.1021/ja00207a016
Olefin Cycloadditions of the Electrophilic Phosphinidene Complex [iPr2N???P=Fe(CO)4], Angewandte Chemie International Edition, vol.38, issue.17, pp.2596-2599, 1999. ,
DOI : 10.1002/(SICI)1521-3773(19990903)38:17<2596::AID-ANIE2596>3.0.CO;2-I
N-Heterocyclic Carbene-Functionalized Ruthenium Phosphinidenes: What a Difference a Twist Makes, Journal of the American Chemical Society, vol.131, issue.19, pp.6666-6667, 2009. ,
DOI : 10.1021/ja901540h
Reaction of bulky monosubstituted phosphorus(III) halides with disodium tetracarbonylferrate. Steric and electronic factors in the synthesis of Fe(CO)4 complexes of diphosphene and phosphinidene ligands, Journal of the American Chemical Society, vol.109, issue.19, pp.5699-5703, 1987. ,
DOI : 10.1021/ja00253a022
Synthesis and Reactions of Terminal Osmium and Ruthenium Complexed Phosphinidenes [(6-Ar)(L)M???PMes*], Chemistry - A European Journal, vol.9, issue.10, pp.2200-2208, 2003. ,
DOI : 10.1002/chem.200204582
Zirconium - Phosphorus Chemistry: Strategies in Syntheses, Reactivity, Catalysis, and Utility, Angewandte Chemie International Edition, vol.39, issue.2, pp.314-329, 2000. ,
DOI : 10.1002/(SICI)1521-3773(20000117)39:2<314::AID-ANIE314>3.0.CO;2-D
Iridium Phosphinidene Complexes: A Comparison with Iridium Imido Complexes in Their Reaction with Isocyanides, Journal of the American Chemical Society, vol.131, issue.37, pp.13531-13537, 2009. ,
DOI : 10.1021/ja9048509
Synthesis and Reactivity of Phosphametallacyclobutenes:?? Sterically Induced [4 + 2] Retrocycloadditions, Journal of the American Chemical Society, vol.118, issue.17, pp.4204-4205, 1996. ,
DOI : 10.1021/ja953470f
Group Transfer from Nickel Imido, Phosphinidene, and Carbene Complexes to Ethylene with Formation of Aziridine, Phosphirane, and Cyclopropane Products, Journal of the American Chemical Society, vol.125, issue.44, pp.13350-13351, 2003. ,
DOI : 10.1021/ja0381914
The carbene-like behavior of terminal phosphinidene complexes toward olefins. A new access to the phosphirane ring, Organometallics, vol.3, issue.3, pp.456-461, 1984. ,
DOI : 10.1021/om00081a021
Addition of a Phosphinidene Complex to C=N Bonds: P-Ylides, Azaphosphiridines, and 1,3-Dipolar Cycloadditions, Chemistry - A European Journal, vol.7, issue.16, pp.3551-3557, 2001. ,
DOI : 10.1002/1521-3765(20010817)7:16<3551::AID-CHEM3551>3.0.CO;2-M
Unexpected Intramolecular Reactions of Intermediate Phosphacarbonyl Ylide Tungsten Complexes, Angewandte Chemie International Edition in English, vol.36, issue.4, pp.378-381, 1997. ,
DOI : 10.1002/anie.199703781
THE REACTION OF TERMINAL PHOSPHINIDENE COMPLEXES WITH ELECTRON-RICH ALKYNES: A NEW APPROACH TO THE PHOSPHOLE RING, Phosphorus, Sulfur, and Silicon and the Related Elements, vol.668, issue.3-4, pp.477-481, 1990. ,
DOI : 10.1016/S0040-4039(00)96685-1
Addition of a Phenyl Phosphinidene Complex to Conjugated Diynes, Organometallics, vol.18, issue.4, pp.796-799, 1999. ,
DOI : 10.1021/om9806040
Reaction of a terminal phosphinidene complex with a carbene complex. Synthesis of a phosphorus carbon double bond through phosphinidene carbene coupling, Organometallics, vol.6, issue.1, pp.207-208, 1987. ,
DOI : 10.1021/om00144a046
Stabilization of R-P(H)A species (A = OH, OR, S, NH2, NHR, NR2, Cl, Br, I) by complexation with chromium and tungsten pentacarbonyls, Organometallics, vol.1, issue.11, pp.1488-1492, 1982. ,
DOI : 10.1021/om00071a017
Preparation of 1,3-disubstituted imidazolium salts, 1973. ,
Imidazolylidenes, imidazolinylidenes and imidazolidines, Tetrahedron, vol.55, issue.51, pp.14523-14534, 1999. ,
DOI : 10.1016/S0040-4020(99)00927-8
Carbene-Stabilized Diphosphorus, Journal of the American Chemical Society, vol.130, issue.45, pp.14970-14971, 2008. ,
DOI : 10.1021/ja807828t
Carbene Activation of P4 and Subsequent Derivatization, Angewandte Chemie International Edition, vol.29, issue.37, pp.7052-7055, 2007. ,
DOI : 10.1002/anie.200703055
Cluster, Journal of the American Chemical Society, vol.129, issue.46, pp.14180-14181, 2007. ,
DOI : 10.1021/ja077296u
Phosphinidene Complex with an Unprecedented H-Shaped Planar Metal Core, Inorganic Chemistry, vol.47, issue.18, pp.7963-7965, 2008. ,
DOI : 10.1021/ic8011487
Electronic stabilization of nucleophilic carbenes, Journal of the American Chemical Society, vol.114, issue.14, pp.5530-5534, 1992. ,
DOI : 10.1021/ja00040a007
Cationic rhodium(I) diolefin complexes, Transition Metal Chemistry, vol.167, issue.1, pp.65-73, 1980. ,
DOI : 10.1007/BF01396872
(L)MPAr of the Group 9 Transition Metals Cobalt, Rhodium, and Iridium. Synthesis, Structures, and Properties, Organometallics, vol.22, issue.9, pp.1827-1834, 2003. ,
DOI : 10.1021/om0208624
N-Heterocyclic Carbene Functionalized Group 7???9 Transition Metal Phosphinidene Complexes, Organometallics, vol.28, issue.17, pp.5166-5172, 2009. ,
DOI : 10.1021/om900496y
Reaction of zirconocene dichloride with alkyllithiums or alkyl grignard reagents as a convenient method for generating a ???zirconocene??? equivalant and its use in zirconium-promoted cyclization of alkenes, alkynes, dienes, enynes, and diynes, Tetrahedron Letters, vol.27, issue.25, pp.2829-2832, 1986. ,
DOI : 10.1016/S0040-4039(00)84653-5
Synthetic Methods of Organometallic and Inorganic Chemistry, 1996. ,
Preparation of 1,3-Disubstituted Imidazolium Salts, 1990. ,
Gaussian 03, Revision E.01, 2004. ,
Gaussian 03, Revision E.01, 2004. ,
Gaussian 09, Revision B.01, 2010. ,