O. P. Grigoryeva, A. M. Fainleib, A. L. Tolstov, O. M. Starostenko, E. Lievana et al., Thermoplastic elastomers based on recycled high-density polyethylene, ethylene-propylene-diene monomer rubber, and ground tire rubber, Journal of Applied Polymer Science, vol.57, issue.3, pp.95-659, 2005.
DOI : 10.1002/app.21177

W. Hutchinson, Structural relaxation in the glass transition region, in The Physics of Glassy Polymers, 1997.

M. Carrega, Les polymères, de la molécule à l'objet, 1999.

M. Gordon and J. S. Taylor, Ideal copolymers and second-order transitions in synthetic rubbers. I. Non-crystalline polymers, Journal of Applied Chemistry, issue.29, pp.493-500, 1952.

P. S. Ravishankar, Treatise on EPDM. Rubber Chemistry and Technology, pp.327-349, 2012.
DOI : 10.5254/rct.12.87993

G. Ver-strate, Ethylene-Propylene Elastomers, in Encyclopedia of Polymer Science and Engineering, p.522, 1986.

M. Van-duin and H. G. Dikland, Effect of third monomer type and content on peroxide crosslinking efficiency of EPDM. Rubber Chemistry and Technology, pp.132-144, 2003.

M. Van-duin and B. Coussens, Re) evaluation of the importance of hydrogen abstraction during radical grafting of polyolefins, 11 th Polymer Processing Society Meeting, 1995.

T. Yamazaki and T. Seguchi, Electron spin resonance study on chemical crosslinking reaction mechanisms of polyethylene using a chemical agent. V. Comparison with polypropylene and ethylene-propylene copolymer, Journal of Polymer Science Part A: Polymer Chemistry, issue.18, pp.38-3383, 2000.

K. Fujimoto and K. Wataya, The study of polymers by high-temperature ATR spectroscopy, Journal of Applied Polymer Science, vol.13, issue.12, pp.2513-2526, 1969.
DOI : 10.1002/app.1969.070131201

F. B. Baldwin, P. Borzel, C. A. Cohen, H. S. Makowski, J. F. Van-de-castle et al., The Influence of Residual Olefin Structure on EPDM Vulcanization, Diene termonomer type and EPDM properties. Rubber Chemistry and Technology, pp.522-548, 1970.
DOI : 10.5254/1.3547272

F. Delor, G. Teissedre, M. Baba, and J. Lacoste, Ageing of EPDM-2. Role of hydroperoxides in photo-and thermo-oxidation. Polymer Degradation and Stability, pp.321-331, 1998.

R. C. Keller, Peroxide curing of ethylene-propylene elastomers. Rubber Chemistry and Technology, pp.238-254, 1988.

F. P. Baldwin, EPDM vulcanization and high temperature compression set. Rubber Chemistry and Technology, pp.1040-1054, 1970.
DOI : 10.5254/1.3547307

M. Qu, F. Deng, S. M. Kalkhoran, A. Gouldstone, A. Robisson et al., Nanoscale visualization and multiscale mechanical implications of bound rubber interphases in rubber???carbon black nanocomposites, Soft Matter, vol.35, issue.3, pp.1066-1077, 2011.
DOI : 10.1080/14786435.2010.495360

S. N. Magonov, V. Elings, and M. H. Whangbo, Phase imaging and stiffness in tappingmode atomic force microscopy, L385-L391. 18. Dupres, S., Dynamique, déformations locales et irréversibilités dans des élastomères renforcés par du noir de carbone Sciences-Physiques Paris XI: Paris. 19. Kraus, G., Reinforcement of elastomers by carbon black. Rubber Chemistry and Technology, pp.51-297, 1978.

H. Nakauchi, K. Naito, T. Utsunomiya, K. Masuda, and S. Inoue, Analysis of crosslinking structure by compressive property of the swollen rubber, Nippon Gomu Kyokaishi, issue.5, pp.60-267, 1987.

N. Dutta, D. Khastgir, and D. K. Tripathy, The effect of carbon black concentration on the dynamic mechanical properties of bromobutyl rubber, Journal of Materials Science, vol.42, issue.1, pp.177-188, 1991.
DOI : 10.1007/BF00576049

G. Heinrich and H. Kluppel, The role of polymer-filler-interphase in reinforcement of elastomers Kautschuk und Gummi Kunststoffe Overview of curing and crosslinking of elastomers, Progress in Rubber & Plastics Technology, pp.452-454, 1988.

J. L. Leblanc, R. A. Orza, P. C. Magusin, V. M. Litviniv, M. Van-dwin et al., Rubber-filler interactions and rheological properties in filled compounds Progress in Polymer Science Network density and diene conversion in peroxide-cured gumstock EPDM Rubbers. A solid-state NMR study, Macromolecular Symposia, pp.627-687, 2002.

A. Y. Coran and A. Gent, in Encyclopedia of Polymer Engineering John Willey&Sons: New York. 27. Martinon, P., Caractéristiques des élastomères Strength of sulfur-linked elastomers, Rubber Chemistry and Technology, vol.69, issue.4, pp.577-590, 1989.

W. Hoffman, Vernetzungsmittel in ethylene-propylene-kautschuk, pp.308-332, 1987.

Y. Tanaka, Recent advances in structural characterization of elastomers. Rubber Chemistry and Technology, pp.325-385, 1991.

P. D. Wu and E. Van-der-giessen, On improved network models for rubber elasticity and their applications to orientation hardening in glassy polymers, Journal of the Mechanics and Physics of Solids, vol.41, issue.3, pp.41-427, 1993.
DOI : 10.1016/0022-5096(93)90043-F

H. Kato and H. Fujita, Development of synergistic curing systems for polychloroprene. Rubber Chemistry and Technology, pp.949-960, 1982.

W. Gronski and H. Hasenhindl, High resolution solid state 13 C NMR studies of the crosslink structure in acclerated sulfur vulcanized natural rubber, Kautschuk und Gummi Kunststoffe, vol.44, issue.2, pp.119-123, 1991.

V. Duch-c-ek, T. B. Bhattacharyya, and A. Kuta, A study of sulfur-free thiuram vulcanization using differential scanning calorimeter, Journal of Polymer Science Part A: Polymer Chemistry, vol.27, issue.3, pp.1089-1095, 1989.
DOI : 10.1002/pola.1989.080270330

T. Yamada, T. Okumoto, H. Ohtani, and S. Tsuge, Structural characterization of ethylenepropylene-diene rubbers by high-resolution pyrolysis gas chromatography. Rubber Chemistry and Technology, pp.191-201, 1990.

D. S. Campbell, Structural characterization of vulcanizates part X. Thiol-disulfide interchange for cleaving disulfide crosslinks in natural rubber vulcanizates, Journal of Applied Polymer Science, vol.13, issue.6, pp.1201-1214, 1969.
DOI : 10.1002/app.1969.070130609

D. S. Campbell, B. M. Saville, L. Van-der-does, J. W. Noordermeer, and M. Van-duin, Current principles and practices in elucidating structure in sulfur-vulcanized elastomers. in 1 st International Rubber Conference Influence of the diene monomer on devulcanization of EPDM rubber, Journal of Applied Polymer Science, vol.109, issue.2, pp.976-986, 1967.

S. Wolff and A. P. Singh, Silanes in tire compounding after 10 years -review Heterogenized vanadyl cations over modified silica surfaces: A comprehensive understanding toward the structural property and catalytic activity difference over mesoporous and amorphous silica supports, 3 rd Annual Meeting and Conference on Tire Science and Technology, pp.52-64, 1984.

A. J. Lapra, Caractérisation moléculaire et propriétés mécaniques des réseaux élastomères SBR renforcés par la silice Comportement mécanique d'élastomères chargés, influence de l'adhésion charge/polymère, influence de la morphologie Kinetic Theory of Liquids, 488. 44. Einstein, A., Zur theorie der brownschen bewegung Annalen der Physik, pp.371-385, 1906.

H. M. Smallwood, Limiting Law of the Reinforcement of Rubber, Journal of Applied Physics, vol.15, issue.11, pp.758-766, 1944.
DOI : 10.1063/1.1707385

E. Guth and O. Gold, On the hydrodynamical theory of the viscosity of suspension Physical Review, p.322, 1938.

E. Guth, Theory of Filler Reinforcement, Journal of Applied Physics, vol.16, issue.1, pp.20-25, 1945.
DOI : 10.1063/1.1707495

J. C. Halpin, Stiffness and expansion estimates for oriented short fiber composites, Journal of Composite Materials, vol.3, issue.4, pp.732-734, 1969.

P. R. Dluzneski, Peroxide Vulcanization of Elastomers, Rubber Chemistry and Technology, vol.74, issue.3, pp.451-492, 2001.
DOI : 10.5254/1.3547647

Y. L. Moisan, Effects of oxygen permeation and stabilizer migration on polymer degradation Polymer Permeability, 1985.

S. Girois, Stabilisation des plastiques-Principes généraux

L. H. Sperling, P. Heuillet, and L. Dugautier, Introduction to Physical Polymer Science Modélisation du comportement hyperélastique des élastomères compacts Reinforcement of natural rubber, Génie Mécanique des Caoutchoucs et des Elastomères Thermoplastiques, pp.85-2301, 1992.

Q. V. Bui and J. P. Ponthot, Estimation of rubber sliding friction from asperity interaction modeling, Wear, vol.252, issue.1-2, pp.150-160, 2002.
DOI : 10.1016/S0043-1648(01)00864-X

J. Marchal, Cristallisation des caoutchoucs chargés et non chargés sous contrainte : effet sur les chaines amorphes, 2006.

S. Etienne, L. David, P. J. Flory, E. M. Arruda, and M. C. Boyce, Introduction à la Physique des Polymères Principles of Polymer Chemistry. Press, Ithaca ed The Physics of Rubber Elasticity A three-dimensional constitutive model for the large stretch behavior of rubber elastic materials, Journal of the Mechanics and Physics of Solids, pp.41-389, 1953.

W. Kuhn and F. Grun, Beziehungen zwischen elastischen konstanten und dehnungsdoppelbrechung hochelastischer stoffe. Kolloid-Zeitschrift, pp.248-271, 1942.
DOI : 10.1007/bf01793684

L. Mullins and N. R. Tobin, Theoretical Model for the Elastic Behavior of Filler-Reinforced Vulcanized Rubbers, Rubber Chemistry and Technology, vol.30, issue.2, pp.555-571, 1957.
DOI : 10.5254/1.3542705

A. F. Blanchard, Breakage of rubber-filler linkages and energy dissipation in stressed rubber, Journal of Polymer Science, vol.14, issue.76, pp.355-374, 1954.
DOI : 10.1002/pol.1954.120147604

F. J. Bueche, Molecular basis for the mullins effect, Journal of Applied Polymer Science, vol.4, issue.10, pp.107-114, 1960.
DOI : 10.1002/app.1960.070041017

E. M. Dannenberg, Molecular slippage mechanism of reinforcement. Transactions of the Institution of the Rubber Industry, pp.26-42, 1966.

A. R. Payne, Dynamic properties of filler-loaded rubbers, pp.69-123, 1965.

A. R. Payne, The dynamic properties of carbon black loaded natural vulcanizates. Part II, Journal of Applied Polymer Science, issue.621, pp.368-372, 1962.

G. Kraus, Mechanical losses in carbon-black-filled rubbers Strain dependent dynamic mechanical properties of black loaded vulcanizates, Journal of Applied Polymer Science : Applied polymer Symposium Kautschuk und Gummi Kunststoffe, vol.39, issue.708, pp.75-92, 1984.

G. M. Bartenev and L. A. Vishnitskaya, Effect of disperse fillers on the relaxation properties of rubbers, 135. 72. Bartenev, G.M., Sbornik Vulkanizatsia Rezin (the vulcanization of Rubber), 1956.

J. G. Goskhimizdat and E. A. Curro, Doklady Akademii nauk SSSR 133: p. 88. 74 Physical and chemical stress relaxation of elastomers Stress relaxation mechanisms in rubbers reinforced with carbon blacks, state Publisher for chemistry) USSR 75. A.V. Tobolsky., Properties and structure of polymers, pp.196-73, 1954.

A. V. Tobolsky, I. B. Prettyman, J. H. Dillon, T. L. Smith, T. L. Smith et al., Stress relaxation of natural and synthetic rubber stocks Rubber Chemistry and Technology Dependence of ultimate properties of a GR-S rubber on strain rate and temperature Ultimate tensile properties of elastomers. I. Characterization by a time and temperature independent failure envelope, Ultimate tensile properties of elastomers. IV. dependence of the failure envelope, maximum extensibility, and equilibrium stress-strain curve on network characteristics, pp.551-575, 1944.

N. Abdelaziz, M. Neviere, R. , C. G. Sell, A. Coupard et al., Rupture et déchirement des élastomères Radiochemical ageing of ethylene-propyleneediene elastomers. 4. Evaluation of some anti-oxidants, Génie mécanique des caoutchoucs, pp.91-136, 1997.

R. S. Rajeev, S. K. De, A. K. Bhowmick, and B. John, Studies on thermal degradation of short melamine fibre reinforced EPDM, maleated EPDM and nitrile rubber composites, Polymer Degradation and Stability, vol.79, issue.3, pp.79-449, 2003.
DOI : 10.1016/S0141-3910(02)00361-0

N. S. Tomer, F. Delor-jestin, R. P. Singh, and J. Lacoste, Cross-linking assessment after accelerated ageing of ethylene propylene diene monomer rubber, Polymer Degradation and Stability, vol.92, issue.3, pp.92-457, 2007.
DOI : 10.1016/j.polymdegradstab.2006.11.013
URL : https://hal.archives-ouvertes.fr/hal-00399015

M. Giurginca, T. Zaharescu, and A. Meghea, Degradation of ethylene-propylene elastomers in the presence of ozone, Polymer Degradation and Stability, vol.50, issue.1, pp.45-48, 1995.
DOI : 10.1016/0141-3910(95)00108-X

S. Mitra, A. Ghanbari-siahkali, P. Kingshott, H. K. Rehmeier, H. Abildgaard et al., Chemical degradation of crosslinked ethylene-propylene-diene rubber in an acidic environment. Part I. Effect on accelerated sulphur crosslinks, Polymer Degradation and Stability, vol.91, issue.1, pp.91-69, 2006.
DOI : 10.1016/j.polymdegradstab.2005.04.032

S. Mitra, A. Ghanbari-siahkali, P. Kingshott, H. K. Rehmeier, H. Abildgaard et al., Chemical degradation of crosslinked ethylene-propylene-diene rubber in an acidic environment. Part II. Effect of peroxide crosslinking in the presence of a coagent, Polymer Degradation and Stability, vol.91, issue.1, pp.91-81, 2006.
DOI : 10.1016/j.polymdegradstab.2005.04.031

A. Rivaton, S. Cambon, and J. L. Gardette, Radiochemical ageing of EPDM elastomers., Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, vol.227, issue.3
DOI : 10.1016/j.nimb.2004.09.008

J. Rychly, L. Matisová-rychlá, P. Tiemblo, and J. Gomez-elvira, The effect of physical parameters of isotactic polypropylene on its oxidisability measured by chemiluminescence method. Contribution to the spreading phenomenon, Polymer Degradation and Stability, vol.71, issue.2, pp.71-253, 2001.
DOI : 10.1016/S0141-3910(00)00169-5

T. Nishiyama, T. Sugimoto, N. Miyamoto, M. Uezomo, and Y. Nakajima, Antioxidant activities of phenols having a fused oxygen-containing heterocyclic ring, Polymer Degradation and Stability, vol.70, issue.1, pp.103-109, 2000.
DOI : 10.1016/S0141-3910(00)00096-3

T. Zaharescu, S. Jipa, and I. Mihalcea, Kinetic effects of selenium on degradation of ethylene-propylene copolymer, Journal of Applied Polymer Science, vol.40, issue.177, pp.80-2053, 2001.
DOI : 10.1002/app.1304

T. Zaharescu, S. Jipa, R. Setnescu, J. Brites, M. A. Esteves et al., Synergistic effects on thermal stability of ethylene???propylene elastomers stabilized with hindered phenols and secondary amines, Polymer Testing, vol.21, issue.2, pp.149-153, 2002.
DOI : 10.1016/S0142-9418(01)00062-9

C. Wilhelm and J. L. Gardette, Infrared identification of carboxylic acids formed in polymer photooxidation, Journal of Applied Polymer Science, vol.51, issue.8, pp.51-1411, 1994.
DOI : 10.1002/app.1994.070510808

M. F. Porter and . Eirich, Organic Chemistry of Sulfur, 1987.

M. R. Krejsa and J. L. Koenig, A review of sulfur crosslinking fundamentals for accelerated and unaccelerated vulcanization. Rubber Chemistry and Technology, pp.376-410, 1993.

J. L. Bolland and G. Gee, Kinetic studies in the chemistry of rubber and related materials. II. The kinetics of oxidation of unconjugated olefins. Transactions of the Faraday Society, pp.236-243, 1946.

Y. Kamiya and E. Niki, Aspect of degradation and stabilisation of polymers, 1978.

Y. Kamiya and E. Niki, Oxidative degradation, in Aspects of Degradation and Stabilization of Polymers, 1978.

S. Korcek, J. H. Chenier, J. A. Howard, and K. U. Ingold, Absolute Rate Constants for Hydrocarbon Autoxidation. XXI. Activation Energies for Propagation and the Correlation of Propagation Rate Constants with Carbon???Hydrogen Bond Strengths, Canadian Journal of Chemistry, vol.50, issue.14, pp.50-2285, 1972.
DOI : 10.1139/v72-365

F. Severini, R. Gallo, and S. Ipsale, Environmental degradation of polypropylene, Polymer Degradation and Stability, vol.22, issue.2, pp.185-194, 1988.
DOI : 10.1016/0141-3910(88)90041-9

L. Achimsky, Etude cinétique de la thermo-oxydation du polypropylène, 1996.

G. Teissedre, J. F. Pilichowski, S. Chmela, and J. Lacoste, Ageing of EPDM???I: Photo and thermal stability of EPDM hydroperoxides, Polymer Degradation and Stability, vol.53, issue.2, pp.207-215, 1996.
DOI : 10.1016/0141-3910(96)00082-1

X. Colin, B. Fayolle, L. Audouin, and J. Verdu, About a quasi-universal character of unstabilised polyethylene thermal oxidation kinetics, Polymer Degradation and Stability, vol.80, issue.1, pp.67-74, 2003.
DOI : 10.1016/S0141-3910(02)00384-1
URL : https://hal.archives-ouvertes.fr/hal-00113813

N. Khelidj, X. Colin, L. Audouin, J. Verdu, C. Monchy-leroy et al., Oxidation of polyethylene under irradiation at low temperature and low dose rate. Part I. The case of ???pure??? radiochemical initiation, Polymer Degradation and Stability, vol.91, issue.7, pp.91-1593, 2006.
DOI : 10.1016/j.polymdegradstab.2005.09.011
URL : https://hal.archives-ouvertes.fr/hal-00199223

J. M. Ginhac, J. C. Gardette, R. Arnaud, and J. Lemaire, Influence of hydroperoxides on the photothermal oxidation of polyethylene. Die Makromolekulare Chemie, pp.1017-1025, 1981.

M. Zachary, S. Camara, A. C. Whitwood, B. C. Gilbert, M. Van-duin et al., EPR study of persistent free radicals in cross-linked EPDM rubbers, European Polymer Journal, vol.44, issue.7, pp.44-2099, 2008.
DOI : 10.1016/j.eurpolymj.2008.04.008

J. Y. Buzaré, G. Silly, J. Emery, G. Boccaccio, and E. Rouault, Aging effects on vulcanized natural rubber studied by high resolution solid state 13C-NMR, European Polymer Journal, vol.37, issue.1, pp.85-91, 2001.
DOI : 10.1016/S0014-3057(00)00081-1

I. Kende, T. L. Pickering, and A. V. Tobolsky, The Dissociation Energy of the Tetrasulfide Linkage, Journal of the American Chemical Society, vol.87, issue.24, pp.5582-5586, 1965.
DOI : 10.1021/ja00952a012

N. J. Morrison and M. Porter, Temperature Effects on the Stability of Intermediates and Crosslinks in Sulfur Vulcanization, Rubber Chemistry and Technology, vol.57, issue.1, pp.63-85, 1984.
DOI : 10.5254/1.3536002

S. S. Choi, S. H. Ha, and C. S. Woo, Thermal aging behaviors of rubber vulcanizates cured with single and binary cure systems, Bulletin of the Korean Chemical Society, vol.27, issue.3, pp.429-431, 2006.

S. Yamashita, Reclaimed rubber from rubber scrap (2) International Polymer Science and Technology, pp.77-93, 1981.

W. Wang and B. Qu, Photo-and thermo-oxidative degradation of photocrosslinked ethylene-propylene-diene terpolymer. Polymer Degradation and Stability, pp.81-531, 2003.

A. Kumar, S. Commereuc, and V. Verney, Ageing of elastomers: a molecular approach based on rheological characterization, Polymer Degradation and Stability, vol.85, issue.2, pp.751-757, 2004.
DOI : 10.1016/j.polymdegradstab.2003.11.014

R. V. Gemmer and M. A. Golub, Applications of Polymer Spectroscopy, 1978.

F. Delor-jestin, J. Lacoste, N. Barrois-oudin, C. Cardinet, and J. Lemaire, Photo-, thermal and natural ageing of ethylene???propylene???diene monomer (EPDM) rubber used in automotive applications. Influence of carbon black, crosslinking and stabilizing agents, Polymer Degradation and Stability, vol.67, issue.3, pp.67-469, 2000.
DOI : 10.1016/S0141-3910(99)00147-0

R. Clavreul, Evolution of ethylene propylene copolymers properties during ageing. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, pp.1-4, 1997.

F. Delor, N. Barrois-oudin, X. Duteurtre, C. Cardinet, J. Lemaire et al., Oxidation of rubbers analysed by HATR/IR spectroscopy, Polymer Degradation and Stability, vol.62, issue.2, pp.62-395, 1998.
DOI : 10.1016/S0141-3910(98)00028-7

R. A. Assink, K. T. Gillen, and B. Sanderson, Monitoring the degradation of a thermally aged EPDM terpolymer by 1H NMR relaxation measurements of solvent swelled samples, Polymer, vol.43, issue.4, pp.1349-1355, 2002.
DOI : 10.1016/S0032-3861(01)00661-9

A. V. Tobolsky, Stress relaxation studies of the viscoelastic properties of polymers. Rubber Chemistry and Technology, pp.427-448, 1957.

R. 1. Flory and P. J. , Principles of polymer chemistry, 1953.

N. Khelidj, X. Colin, L. Audouin, J. Verdu, C. Monchy-leroy et al., Oxidation of polyethylene under irradiation at low temperature and low dose rate. Part II. Low temperature thermal oxidation, Polymer Degradation and Stability, vol.91, issue.7, pp.91-1598, 2006.
DOI : 10.1016/j.polymdegradstab.2005.09.012
URL : https://hal.archives-ouvertes.fr/hal-00199223

S. Sarrabi, X. Colin, and A. Tcharkhtchi, Dégradation thermique du polypropylène au cours du rotomoulage. Partie II. Modélisation de la cinétique de thermooxydation, Matériaux & Techniques, pp.96-281, 2008.

L. K. Nait-ali, X. Colin, and A. Bergeret, Kinetic analysis and modelling of PET macromolecular changes during its mechanical recycling by extrusion, Polymer Degradation and Stability, vol.96, issue.2, pp.236-246, 2011.
DOI : 10.1016/j.polymdegradstab.2010.11.004

C. El-mazry, B. Hassine, M. Correc, O. Colin, and X. , Thermal oxidation kinetics of additive free polyamide 6-6. Polymer Degradation and Stability, pp.22-36, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00984697

P. D. Calvert and N. C. Billingham, Loss of additives from polymers: A theoretical model, Journal of Applied Polymer Science, vol.24, issue.2, pp.357-370, 1979.
DOI : 10.1002/app.1979.070240205

X. Colin, C. Monchy-leroy, L. Audouin, and J. Verdu, Lifetime prediction of polyethylene in nuclear plants. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, pp.251-255, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00213324

T. Seguchi, S. Hashimoto, K. K. Arakawa, N. Hayakawa, W. Kawakami et al., Radiation induced oxidative degradation of polymers???I, Radiation Physics and Chemistry (1977), vol.17, issue.4, pp.195-201, 1981.
DOI : 10.1016/0146-5724(81)90331-9

X. Colin, L. Audouin, and J. Verdu, Thermal oxidation kinetics of unvulcanized unstabilized polyisoprene. Rubber Chemistry and Technology, pp.621-641, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00203570

M. Coquillat, J. Verdu, X. Colin, L. Audouin, and . Nevière, Thermal oxidation of polybutadiene. Part II-Mechanistic and kinetic schemes for additive free uncrosslinked polybutadiene, Polymer Degradation and Stability, issue.7, pp.92-1334, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00199764

H. L. Mcmurry and V. Thornton, Correlation of Infrared Spectra, Analytical Chemistry, vol.24, issue.2, pp.318-334, 1952.
DOI : 10.1021/ac60062a018

X. Colin, L. Audouin, and J. Verdu, Kinetic modelling of the thermal oxidation of polyisoprene elastomers. Part 1: Unvulcanized unstabilized polyisoprene. Polymer Degradation and Stability, pp.92-886, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00199728

N. B. Colthup, Spectra-Structure Correlations in the Infra-Red Region, Journal of the Optical Society of America, vol.40, issue.6, pp.397-400, 1950.
DOI : 10.1364/JOSA.40.000397

C. Jing, Y. Lei, Z. Jieping, L. Sidong, C. Yongjun et al., DRYING KINETICS AND CROSS-LINKING OF SULFUR PREVULCANIZED THICK NATURAL RUBBER LATEX FILM, Rubber Chemistry and Technology, vol.86, issue.1, pp.57-67, 2013.
DOI : 10.5254/rct.13.88908

N. B. Colthup, L. H. Daly, S. E. Wiberley, N. Naskar, R. N. Datta et al., Introduction to Infrared and Raman Spectroscopy. 3 rd ed Reactive blending, reinforcement and curing of NR/BR/EPDM compounds for tire sidewall applications. Rubber Chemistry and Technology, pp.115-138, 1990.

G. Weng, Crack initiation and evolution in vulcanized natural rubber under high temperature fatigue Polymer Degradation and Stability Application of sepiolite to prevent bleeding and blooming for EPDM rubber composition, Applied Clay Science, vol.96, issue.1124, pp.2221-2228, 1996.

S. S. Choi, H. S. Chung, Y. T. Joo, K. M. Yang, and S. H. Lee, Analysis of whitening phenomenon of EPDM article by humid aging, Journal of Applied Polymer Science, vol.99, issue.4, pp.2451-2457, 2012.
DOI : 10.1002/app.34826

X. Colin, L. Audouin, J. Verdu, L. Huy, and M. , Kinetic modelling of the thermal oxidation of polyisoprene elastomers. Part 2: Effect of sulfur vulcanization on mass changes and thickness distribution of oxidation products during thermal oxidation, Polymer Degradation and Stability, vol.92, issue.5, pp.92-898, 2007.
DOI : 10.1016/j.polymdegradstab.2007.01.004
URL : https://hal.archives-ouvertes.fr/hal-00199728

E. Richaud, C. Monchy-leroy, X. Colin, L. Audouin, J. E. Verdu et al., Kinetic modelling of stabilization coupled with stabilizer loss by evaporation. Case of dithioester stabilized polyethylene Polymer Degradation and Stability Polyethylene stabilization against thermal oxidation by a trimethylquinoleine oligomer Stabilization mechanisms of hindered amines, Polymer Degradation and Stability Klemchuk, P.P., Gande, M.E. Polymer Degradation and Stability, vol.94, issue.273, pp.94-410, 1988.

P. P. Klemchuk, M. E. Gande, E. Cordola, E. Richaud, X. Colin et al., Hindered Amine Mechanisms: Part III???Investigations using isotopic labelling, Polymer Degradation and Stability, vol.27, issue.1, pp.65-74, 1990.
DOI : 10.1016/0141-3910(90)90097-Q

N. Khelidj, X. Colin, L. Audouin, and J. Verdu, Vieillissement d'isolants de câbles en polyéthylène en ambiance nucléaire Ecole Nationale Supérieure d'Arts et Métiers: Paris. p. 264. 31 Kinetic modelling of the thermal oxidation of polyisoprene elastomers. Part 3: Oxidation induced changes of elastic properties, Polymer Degradation and Stability, issue.5, pp.92-906, 2006.

O. Saito, On the Effect of High Energy Radiation to Polymers I. Cross-linking and Degradation, Journal of the Physical Society of Japan, vol.13, issue.2, pp.198-206, 1958.
DOI : 10.1143/JPSJ.13.198

S. R. Acharjee and S. K. Bhattacharjee, Formation and disproportionation of arene sulfenic acids, Journal of Applied Chemistry, vol.3, issue.6, pp.40-45, 2013.

J. R. Shelton, Review of basic oxidation Processes in elastomers. Rubber Chemistry and Technology, pp.359-380, 1972.

S. Gunasekaran, R. K. Natarajan, and A. Kala, FTIR spectra and mechanical strength analysis of some selected rubber derivatives, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol.68, issue.2, pp.323-330, 2007.
DOI : 10.1016/j.saa.2006.11.039

R. 1. Chaboche, J. L. Lemaitre, and J. , Mécanique des matériaux solides, 2001.

M. Mooney, A Theory of Large Elastic Deformation, Journal of Applied Physics, vol.11, issue.9, pp.582-592, 1940.
DOI : 10.1063/1.1712836

R. W. Ogden, Large DeformationI sotropic Elasticity -On the Correlation Theory and Experiment for Incompressible Rubberlike Solids, Proceedings the Royal of society, pp.565-584, 1972.

L. R. Treloar, Stress-strain data for vulcanized rubber under various types of deformation. Transactions of the Faraday Society, pp.40-59, 1944.

R. S. Rivlin, Large elastic deformations of isotropic materials, Philosophical Transactions of the Royal Society, issue.A241, pp.459-525, 1948.

L. R. Treloar, The elasticity of a network of long chain molecules (I and II) Transactions of the Faraday Society, pp.36-64, 1943.

W. Kuhn and F. Grun, Beziehungen zwischen elastischen konstanten und dehnungsdoppelbrechung hochelastischer stoffe. Kolloid-Zeitschrift, pp.248-271, 1942.
DOI : 10.1007/bf01793684

H. M. James and E. Guth, Theory of the Elastic Properties of Rubber, The Journal of Chemical Physics, vol.11, issue.10, pp.455-481, 1943.
DOI : 10.1063/1.1723785

G. Marckmann, E. Verron, L. Gornet, G. Chagnon, P. Charrier et al., A theory of network alteration for the Mullins effect, Journal of the Mechanics and Physics of Solids, vol.50, issue.9, pp.50-2011, 2002.
DOI : 10.1016/S0022-5096(01)00136-3
URL : https://hal.archives-ouvertes.fr/hal-01004954

P. J. Flory, Network Structure and the Elastic Properties of Vulcanized Rubber., Chemical Reviews, vol.35, issue.1, pp.51-75, 1944.
DOI : 10.1021/cr60110a002

E. M. Arruda and M. C. Boyce, A three-dimensional constitutive model for the large stretch behavior of rubber elastic materials, Journal of the Mechanics and Physics of Solids, vol.41, issue.2, pp.41-389, 1993.
DOI : 10.1016/0022-5096(93)90013-6
URL : https://hal.archives-ouvertes.fr/hal-01390807

A. A. Griffith, The Phenomena of Rupture and Flow in Solids, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, vol.221, issue.582-593, pp.163-198, 1920.
DOI : 10.1098/rsta.1921.0006

G. R. Irwin, Relation of stresses near a crack to the crack extension force, 9 th international congress on Applied Mechanics, 1956.

G. P. Cherepanov, Cracks in solids, International Journal of Solids and Structures, vol.4, issue.8, pp.811-831, 1968.
DOI : 10.1016/0020-7683(68)90059-0

J. R. Rice, A Path Independent Integral and the Approximate Analysis of Strain Concentration by Notches and Cracks, Journal of Applied Mechanics, vol.35, issue.2, pp.379-386, 1968.
DOI : 10.1115/1.3601206

R. S. Rivlin and A. G. Thomas, Rupture of rubber. I. Characteristic energy for tearing, Journal of Polymer Science, vol.10, issue.3, pp.291-318, 1953.
DOI : 10.1002/pol.1953.120100303

H. W. Greensmith, Rupture of rubber. X. The change in stored energy on making a small cut in a test piece held in simple extension, Journal of Applied Polymer Science, vol.7, issue.3, pp.993-1002, 1963.
DOI : 10.1002/app.1963.070070316

P. B. Lindley, Energy for crack growth in model rubber components. The Journal of Strain Analysis for Engineering Design, pp.132-140, 1972.

G. J. Lake, Application of fracture mechanics to failure in rubber articles, with particular reference to groove cracking in tyres, in Yield, Deformation and Fracture of Polymers, 1970.

L. R. Treloar, T. Ha-anh, and T. Vu-khanh, Viscoelastic properties of polymers. Ferry. pp. xxi + 671, 1970. London: John Wiley. 285s, British Polymer Journal, vol.3, issue.1, pp.50-74, 1971.
DOI : 10.1002/pi.4980030117

C. S. Woo and H. S. Park, Useful lifetime prediction of rubber component, Engineering Failure Analysis, vol.18, issue.7, pp.1645-1651, 2011.
DOI : 10.1016/j.engfailanal.2011.01.003

K. T. Gillen, R. Bernstein, R. L. Clough, and M. Celina, Lifetime predictions for semicrystalline cable insulation materials: I. Mechanical properties and oxygen consumption measurements on EPR materials, Polymer Degradation and Stability, issue.9, pp.91-2146, 2006.

M. L. Williams, R. F. Landel, and J. D. Ferry, The Temperature Dependence of Relaxation Mechanisms in Amorphous Polymers and Other Glass-forming Liquids, Journal of the American Chemical Society, vol.77, issue.14, pp.77-3701, 1955.
DOI : 10.1021/ja01619a008

J. D. Ferry, Viscoelastic Properties of Polymers, British Polymer Journal, 1970.

B. Nair, A. Kurian, P. Joseph, and R. , Effect of aluminium hydroxide, chlorinated polyethylene, decabromo biphenyl oxide and expanded graphite on thermal, mechanical and sorption properties of oil-extended ethylene-propylene-diene terpolymer rubber, Materials & Design, issue.0, pp.40-80, 2012.

C. Menguy, Mesure des caractéristiques des matériaux isolants solides, in Technique de l'ingénieur. 1997, Editions T.I. 30, Defect Accumulation in Rubber. Rubber Chemistry and Technology, vol.58, issue.4, pp.806-814, 1985.

F. Bueche, The tensile strength of elastomers according to current theories. Rubber Chemistry and Technology, pp.1269-1285, 1959.

I. S. Choi and C. M. Roland, Intrinsic defects and the failure properties of cis-1,4-polyisoprenes. Rubber Chemistry and Technology, pp.591-599, 1996.

M. Nait-abdelaziz, F. Zairi, Z. Qu, A. Hamdi, and N. Nait-hocine, J integral as a fracture criterion of rubber-like materials using the intrinsic defect concept, Mechanics of Materials, vol.53, issue.0, pp.2012-53
DOI : 10.1016/j.mechmat.2012.05.001

P. J. Flory, W. J. Hung, and M. F. Tse, Principles of Polymer Chemistry. Press, Ithaca ed Swelling of constrained rubber layers: effect on free energy of detachment, Rubber Chemistry and Technology, issue.1, pp.74-89, 1953.

G. 'sell, C. Hiver, J. M. Dahoun, and A. , Experimental characterization of deformation damage in solid polymers under tension, and its interrelation with necking, International Journal of Solids and Structures, vol.39, issue.13-14, pp.3857-3872, 2002.
DOI : 10.1016/S0020-7683(02)00184-1

L. Mullins, Effect of stretching on the properties of rubber. Rubber Chemistry Technology, pp.281-300, 1948.

L. Mullins, Softening of rubber by deformation. Rubber Chemistry Technology, pp.339-362, 1969.

L. Mullins, Theoretical model for elastic behaviour of filler-reinforced vulcanized rubbers. Rubber Chemistry Technology, pp.555-571, 1957.

A. V. Tobolsky, I. B. Prettyman, and J. H. Dillon, Stress relaxation of natural and synthetic rubber stocks. Rubber Chemistry and Technology, pp.551-575, 1944.

A. V. Tobolsky, Stress relaxation studies of the viscoelastic properties of polymers. Rubber Chemistry and Technology, pp.427-448, 1957.