H. Aagard, P. Aagard, and H. C. Helgeson, Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions; I, Theoretical considerations, American Journal of Science, vol.282, issue.3, p.237, 1982.
DOI : 10.2475/ajs.282.3.237

. Abbas, Molecular dynamics study of the structure and dynamic behavior at the surface of a silicate glass, Journal of Non-Crystalline Solids, vol.315, issue.1-2, 2002.
DOI : 10.1016/S0022-3093(02)01432-1
URL : https://hal.archives-ouvertes.fr/hal-00085112

. Aertsens, Modelling of silica diffusion experiments with 32Si in Boom Clay, Journal of Contaminant Hydrology, vol.61, issue.1-4, p.117, 2003.
DOI : 10.1016/S0169-7722(02)00140-7

G. Aertsens, M. Aertsens, and D. Ghaleb, New techniques for modelling glass dissolution, Journal of Nuclear Materials, vol.298, issue.1-2, p.37, 2001.
DOI : 10.1016/S0022-3115(01)00575-X

V. Aertsens, . Iseghem, M. Aertsens, and P. Van-iseghem, Modelling Glass Dissolution with a Monte Carlo Technique, MRS Proceedings, vol.333, 1995.
DOI : 10.1111/j.1151-2916.1991.tb06925.x

. Angeli, Influence of calcium on sodium aluminosilicate glass leaching behaviour, Phys. Chem. Glasses, vol.42, p.279, 2001.

. Angeli, 17O 3Q-MAS NMR characterization of a sodium aluminoborosilicate glass and its alteration gel, Chemical Physics Letters, vol.341, issue.1-2, p.23, 2001.
DOI : 10.1016/S0009-2614(01)00423-7

E. Antoni, Structure et propriétés des verres silicatéssilicatésà haute teneur en alumine, Thèse, 2003.

. Boksay, The kinetics of the formation of leached layers on glass surfaces, Phys. Chem. Glasses, vol.9, p.69, 1968.

. Braver, . White, S. A. Braver, and W. B. White, Raman spectroscopic investigation of the structure of silicate glasses. i. the binary alkali silicates, 1975.

. Brunauer, Adsorption of gases in multimoleculer layers Molecular mechanisms for corrosion of silica and silicate glasses The effect of molecular structure on borosilicate glass leaching The structure of leached sodium borosilicate glass Unified approach for molecular dynamics and density-functional theory, [Car and Parrinello, p.3093002261062471, 1938.

G. Charlot, Les méthodes de la chimie analytique Analyse quantitive minérale, 1966.

F. Delage and . Delage, ´ Etude de la fonction cinétique de dissolution d'un verre nucléaire. Thèse, Université Montpellier II A mechanistic model for understanding nuclear waste glass dissolution, J. Nucl. Mat, vol.191, p.190, 1992.

. Delage, Dissolution of R7T7 Glass in Static and Flowing Conditions: Influence of Si Diffusion Mechanism in the Leached Layer, MRS Proceedings, vol.112, p.171, 1993.
DOI : 10.1557/PROC-294-171

. Delaye, Modeling oxide glasses with born-mayer-huggins potentials : Effet of composition on structural changes Growth and ripening of porous layers in water altered glasses, J. Non-Cryst. Solids J. Non-Cryst. Solids, vol.210, issue.261, p.232237, 1997.

B. Devreux, F. Devreux, and P. Barboux, Numerical modelling of glass dissolution: gel layer morphology, Journal of Nuclear Materials, vol.298, issue.1-2, p.145, 2001.
DOI : 10.1016/S0022-3115(01)00579-7

. Devreux, A simplified model for glass dissolution in water, Journal of Materials Science, vol.36, issue.6, p.1331, 2001.
DOI : 10.1023/A:1017591100985

. Bibliographie and . Dilmore, Corrosion behvior of lithia dislicate glass in aqueous solutions of alumina compounds, Bull. Am. Ceram. Soc, vol.58, p.1111, 1979.

R. H. Doremus, Interdiffusion of hydrogen and alkali ions in a glass surface, Journal of Non-Crystalline Solids, vol.19, p.137, 1975.
DOI : 10.1016/0022-3093(75)90079-4

R. H. Doremus, Glass science, 1994.

M. Ebert, W. L. Ebert, and J. J. Mazer, Laboratory Testing of Waste Glass Aqueous Corrosion; Effects of Experimental Parameters, MRS Proceedings, vol.26, p.27, 1994.
DOI : 10.1016/0022-3115(92)90090-8

. El-damrawi, 11 B, 29 Si and 27 Al nuclear magnetic resonance studies of N a 2 O, p.52, 1992.

. Galoisy, Evidence for 6-Coordinated Zirconium in Inactive Nuclear Waste Glasses, Journal of the American Ceramic Society, vol.14, issue.9, p.2219, 1999.
DOI : 10.1111/j.1151-2916.1999.tb02065.x

P. Ganster, Modélisation par dynamique moléculaire des verres de confinement des déchets nucléaires de haute activité, Thèse, 2004.

. Ganster, Structural properties of a calcium aluminosilicate glass from molecular-dynamics simulations: A finite size effects study, The Journal of Chemical Physics, vol.120, issue.21, p.10172, 2004.
DOI : 10.1063/1.1724815

. Gin, French SON 68 nuclear glass alteration mechanisms on contact with clay media, Applied Geochemistry, vol.16, issue.7-8, p.861, 2001.
DOI : 10.1016/S0883-2927(00)00068-8

. Gin, Role and properties of the gel formed during nuclear glass alteration: importance of gel formation conditions, Journal of Nuclear Materials, vol.298, issue.1-2, p.1, 2001.
DOI : 10.1016/S0022-3115(01)00573-6

. Gong, Reaction sintered glass: a durable matrix for spinel-forming nuclear waste compositions, Journal of Nuclear Materials, vol.278, issue.1, 2000.
DOI : 10.1016/S0022-3115(99)00226-3

. Gou, Molecular dynamics simulation of sodium borosilicate glasses, Journal of Non-Crystalline Solids, vol.293, issue.295, p.539, 2001.
DOI : 10.1016/S0022-3093(01)00775-X

. Grambow, . Muller, B. Grambow, and R. Muller, First-order dissolution rate law and the role of surface layers in glass performance assessment, Journal of Nuclear Materials, vol.298, issue.1-2, 2001.
DOI : 10.1016/S0022-3115(01)00619-5
URL : https://hal.archives-ouvertes.fr/in2p3-00021463

B. E. Grambow, A General Rate Equation for Nuclear Waste Glass Corrosion, MRS Proceedings, vol.8, p.15, 1985.
DOI : 10.1016/0016-7037(80)90220-3

P. Hamilton, J. P. Hamilton, and C. G. Pantano, Effects of glass structure on the corrosion behavior of sodium-aluminosilicate glasses, Journal of Non-Crystalline Solids, vol.222, p.167, 1997.
DOI : 10.1016/S0022-3093(97)90110-1

K. Hoschen, J. Hoschen, and R. Kopelman, Percolation and cluster distribution. I. Cluster multiple labeling technique and critical concentration algorithm, Physical Review B, vol.14, issue.8, p.3428, 1976.
DOI : 10.1103/PhysRevB.14.3438

R. Iler, The chemistry of silica, 1979.

W. Janke, Pseudo random numbers : Generation and quality checks, Proc. of the winter school : Quantum Simulations of Complex Many-Body Systems, From Theory to Algorithms, p.447, 2002.

C. Jégou, Mise enévidenceenévidence expérimentale des mécanismes limitant l'altération du verre R7T7 en milieu aqueux. Critique et proposition d'´ evolution du formalisme cinétique, Thèse, 1998.

. Jégou, Alteration kinetics of a simplified nuclear glass in an aqueous medium: effects of solution chemistry and of protective gel properties on diminishing the alteration rate, Journal of Nuclear Materials, vol.280, issue.2, p.216, 2000.
DOI : 10.1016/S0022-3115(00)00039-8

. Jollivet, Estimating the alteration kinetics of the french vitrified high-level waste package in a geologic repository, Nuclear Technology, vol.123, p.67, 1998.

. Kinoshita, Percolation Phenomenon for Dissolution of Sodium Borosilicate Glasses in Aqueous Solutions, Journal of the American Ceramic Society, vol.13, issue.3, p.783, 1991.
DOI : 10.1111/j.1151-2916.1991.tb06925.x

D. E. Knuth, The art of computer programming, 1969.

. Lambard, A triple axis double crystal multiple reflection camera for ultra small angle X-ray scattering, Journal de Physique I, vol.2, issue.6, 1992.
DOI : 10.1051/jp1:1992204
URL : https://hal.archives-ouvertes.fr/jpa-00246597

. Ledieu, Leaching of borosilicate glasses. I. Experiments, Journal of Non-Crystalline Solids, vol.343, issue.1-3, p.3, 2004.
DOI : 10.1016/j.jnoncrysol.2004.06.006

S. K. Lee and J. F. Stebbins, Al???O???Al and Si???O???Si sites in framework aluminosilicate glasses with Si/Al=1: quantification of framework disorder, Journal of Non-Crystalline Solids, vol.270, issue.1-3, p.260, 2000.
DOI : 10.1016/S0022-3093(00)00089-2

K. Lemmens, The effect of clay on the dissolution of nuclear waste glass, Journal of Nuclear Materials, vol.298, issue.1-2, p.11, 2001.
DOI : 10.1016/S0022-3115(01)00590-6

. Lobanova, Effect of ZrO 2 on the glass durability, Mat. Res. Soc. Symp. Proc, vol.713, p.571, 2001.

M. Maertens, R. Maertens, and W. Müller-warmuth, Structural groups and their mixing in borosilicate glasses of various compositions ??? an NMR study, Journal of Non-Crystalline Solids, vol.265, issue.1-2, p.167, 2000.
DOI : 10.1016/S0022-3093(99)00693-6

[. Grail, Origins of discrepancies between kinetic rate law theory and experiments in the N a 2 o ? B 2 O 3 ? SiO 2 system Equations of state calculations by fast computing machines, Mat. Res. Soc. Symp. Proc. J. Chem. Phys, vol.713, issue.21, p.1087, 1953.

. Munier, Modelling the alteration gel composition of simplified borosilicate glasses by precipitation of an ideal solid solution in equilibrium with the leachant, Thèse, p.97, 1967.
DOI : 10.1016/j.jnucmat.2003.08.033
URL : https://hal.archives-ouvertes.fr/in2p3-00024104

. Rebiscoul, X-ray reflectometry characterization of SON 68 glass alteration films, Journal of Non-Crystalline Solids, vol.325, issue.1-3, p.113, 2004.
DOI : 10.1016/S0022-3093(03)00321-1
URL : https://hal.archives-ouvertes.fr/hal-00451624

S. Ribet and S. Gin, Role of neoformed phases on the mechanisms controlling the resumption of SON68 glass alteration in alkaline media, Journal of Nuclear Materials, vol.324, issue.2-3, p.152, 2004.
DOI : 10.1016/j.jnucmat.2003.09.010

J. E. Shelby and . Sicard, Study of the kinetics of glass alteration by small angle x-ray scattering, Phys. Chem. Glasses J. Phys. Chem. B, vol.13, issue.108, p.1677702, 1972.

L. Smets, B. M. Smets, and T. P. Lommen, The incorporation of aluminum and boron oxide in sodium silicate glasses, studied by x-ray photoelectron spectroscopy, Phys. Chem. Glasses, vol.22, p.158, 1981.

L. Smets, B. M. Smets, and T. P. Lommen, The leaching of sodium aluminosilicate glasses studied by secondary ion mass spectrometry, Phys. Chem. Glasses, vol.23, p.83, 1981.

. Spalla, Influence of insoluble elements on the nanostructure of water altered glasses, Journal of Non-Crystalline Solids, vol.347, issue.1-3, 2003.
DOI : 10.1016/j.jnoncrysol.2004.08.101

. Spalla, Analysis of the small-angle intensity scattered by a porous and granular medium, Journal of Applied Crystallography, vol.36, issue.2, p.338, 2003.
DOI : 10.1107/S0021889803002279

D. Stauffer, Introduction to percolation theory, 1978.
DOI : 10.4324/9780203211595

R. C. Tausworthe, Random numbers generated by linear recurrence modulo two, Mathematics of Computation, vol.19, issue.90, p.201, 1965.
DOI : 10.1090/S0025-5718-1965-0184406-1

. Trotignon, The compared aqueous corrosion of four simple borosilicate glasses: Influence of Al, Ca and Fe on the formation and nature of secondary phases, Journal of Nuclear Materials, vol.190, p.228, 1992.
DOI : 10.1016/0022-3115(92)90088-3
URL : https://hal.archives-ouvertes.fr/in2p3-00000978

N. Valle, Traçage isotopique ( 29 Si et 18 O) des mécanismes de l'altération du verre de confinement des déchets nucléaires : SON 68, Thèse, 2000.

. Van-iseghem, The role of Al2O3 in the long-term corrosion stability of nuclear waste glasses, Journal of Nuclear Materials, vol.190, p.269, 1992.
DOI : 10.1016/0022-3115(92)90090-8

. Vedishcheva, Thermodynamic modelling of the structure of sodium borosilicate glasses, Phys. Chem. Glasses, vol.44, p.191, 2003.

. Verlet and L. Verlet, Computer "Experiments" on Classical Fluids. I. Thermodynamical Properties of Lennard-Jones Molecules, Physical Review, vol.159, issue.1, p.98, 1967.
DOI : 10.1103/PhysRev.159.98

. Verlet and L. Verlet, Computer "Experiments" on Classical Fluids. II. Equilibrium Correlation Functions, Physical Review, vol.165, issue.1, p.201, 1967.
DOI : 10.1103/PhysRev.165.201

. Vernaz, Present understanding of R7T7 glass alteration kinetics and their impact on long-term behavior modeling, Journal of Nuclear Materials, vol.298, issue.1-2, p.27, 2001.
DOI : 10.1016/S0022-3115(01)00643-2

. West, . Hench, J. K. West, and L. L. Hench, Silica fracture, Journal of Materials Science, vol.74, issue.22, p.5808, 1994.
DOI : 10.1007/BF00366861

X. , L. Xiao, Y. Lasaga, and X. , Ab-initio quantum mechanical studies of the kinetics and mechanisms of silicate dissolution : H + (H 3 O + ) catalysis, Geochim. And Cosmochim. Acta, vol.58, p.5379, 1994.

X. , L. Xiao, Y. Lasaga, and X. , Ab-initio quantum mechanical studies of the kinetics and mechanisms of quartz dissolution : OH ? catalysis, p.2283, 1996.

Y. Bray-]-yun, Y. H. Bray, and P. J. , Nuclear magnetic resonance studies of the glasses in the system Na2O???B2O3???SiO2, Journal of Non-Crystalline Solids, vol.27, issue.3, p.363, 1978.
DOI : 10.1016/0022-3093(78)90020-0

W. H. Zachariasen, THE ATOMIC ARRANGEMENT IN GLASS, Journal of the American Chemical Society, vol.54, issue.10, p.3841, 1932.
DOI : 10.1021/ja01349a006

O. Zarembowitch-deruelle, ´ Etude in situ de la couche d'altération de verres, Thèse, 1997.

J. Zarzicky, Les verres et l'´ etat vitreux, 1982.

. Zemb, Improving sensitivity of a small angle x-ray scattering camera with pinhole collimation using separated optical elements, Review of Scientific Instruments, vol.74, issue.4, p.2456, 2003.
DOI : 10.1063/1.1556954
URL : https://hal.archives-ouvertes.fr/cea-00268837

B. Variation-de-la-fraction, 17 1.8 ´ Energies d'activation de la rupture de la liaison Si?O?Sì a trois pH, acide, neutre et basique, O 3 ] (R) obtenus pour différentes valeurs du rapport [SiO 2 ]/[B 2 O 3 ] (K) (d'après Yunaprès Xiao et Lasaga [Xiao and Lasaga, 1978.

. Delaye, Structure d'un verre borosilicaté prédite par dynamique moléculaire (d'après Delaye, p.20, 1997.

. Sicard, Variation des fractions lixiviées finales dans des verres au zirconium altérés en pH librè a 1 cm ?1 , d'après les travaux de, p.74

L. Variations-de-la-quantité, LF B en fin d'altération en fonction de la proportion de sodium non associéassociéà l'aluminium pour les verresà verresà l'aluminium, p.83

.. ». Altération-par-l-'eau-des-verres-borosilicatés., 8.7 ´ Evolution du front d'altération pour quatre valeurs de la vitesse de saturation du « réservoir, p.144