. Proof, By Lemma 6.3.2, the sequence (E(u n )) n?N * is convergent

. Firstly, u), since u is the global minimizer of the functional E. By letting n go to infinity, we obtain E ? E(u

V. Let, M. , and ?. N-*,-u-n-v-?-m, Its existence is ensured by Lemma 6.3.3 M + 2 + u V ) be the closed ball of V centered at 0 of radius M + 2 + u V . Let L be the Lipschitz constant associated with K in (6.9) Using (6.9) and the fact that E ? (u) = 0, we have E ? (u n ) V ? Lu ? u n V and as (u n ) n?N * is bounded in V by Lemma 6.3.3, we deduce that (E ? (u n )) n?N * is also bounded in V . We can then extract a subsequence of (E ? (u n )) n?N * which weakly converges in V towards w ? V, Let us first prove that (E ?

. Then and . Span, is dense in V with assumption (A1), necessarily w = 0. Thus the sequence (E ? (u n )) n?N * weakly converges to 0 in V . As E is convex, we have the following inequality for all n

R. J. Adler, Freefem++ finite element software. http://www.freefem.org/. [2] Scilab software The geometry of random fields, Bibliography, issue.1, 1981.

A. Alvino, G. Trombetti, and P. Lions, On optimization problems with prescribed rearrangements, Nonlinear Analysis: Theory, Methods & Applications, vol.13, issue.2, pp.185-220, 1989.
DOI : 10.1016/0362-546X(89)90043-6

A. Ammar, B. Mokdad, F. Chinesta, and R. Keunings, A new family of solvers for some classes of multidimensional partial differential equations encountered in kinetic theory modeling of complex fluids, Journal of Non-Newtonian Fluid Mechanics, vol.139, issue.3, pp.153-176, 2006.
DOI : 10.1016/j.jnnfm.2006.07.007

URL : https://hal.archives-ouvertes.fr/hal-01004909

A. Anantharaman and E. Cancès, Existence of minimizers for Kohn-Sham models in quantum chemistry Annales de l'Institut Henri Poincaré, Analyse non linéaire, pp.2425-2455, 2009.

D. Arnold, Differential complexes and numerical stability, Proceedings of the ICM 2002, pp.137-157, 2002.

H. Avci and A. T. Gürkanli, Multipliers and tensor products of L(p, q) Lorentz spaces, Acta Mathematica Scientia, vol.27, issue.1, pp.107-116, 2007.
DOI : 10.1016/S0252-9602(07)60009-5

I. Babu?ka and J. Osborn, Eigenvalue problems. Handbook of Numerical Analysis, pp.641-787, 1991.

I. Babu?ka and P. Chatzipantelidis, On solving elliptic stochastic partial differential equations, Computer Methods in Applied Mechanics and Engineering, vol.191, issue.37-38, pp.4093-4122, 2002.
DOI : 10.1016/S0045-7825(02)00354-7

I. Babu?ka, F. Nobile, and R. Tempone, A Stochastic Collocation Method for Elliptic Partial Differential Equations with Random Input Data, SIAM Journal on Numerical Analysis, vol.45, issue.3, pp.1005-1034, 2007.
DOI : 10.1137/050645142

A. R. Barron, A. Cohen, W. Dahmen, and R. Devore, Approximation and learning by greedy algorithms, The Annals of Statistics, vol.36, issue.1, pp.64-94, 2008.
DOI : 10.1214/009053607000000631

A. D. Becke, Density-functional exchange-energy approximation with correct asymptotic behavior, Physical Review A, vol.38, issue.6, pp.3098-3100, 1988.
DOI : 10.1103/PhysRevA.38.3098

R. E. Bellman, Dynamic Programming, 1957.

J. Bergh and J. Löfström, Interpolation spaces, 1976.
DOI : 10.1007/978-3-642-66451-9

G. Beylkin and M. J. Mohlenkamp, Algorithms for Numerical Analysis in High Dimensions, SIAM Journal on Scientific Computing, vol.26, issue.6, p.2133, 2005.
DOI : 10.1137/040604959

P. Binev, A. Cohen, W. Dahmen, R. Devore, G. Petrova et al., Convergence Rates for Greedy Algorithms in Reduced Basis Methods, SIAM Journal on Mathematical Analysis, vol.43, issue.3, pp.1457-1472, 2011.
DOI : 10.1137/100795772

URL : https://hal.archives-ouvertes.fr/hal-00767082

X. Blanc, C. L. Bris, and P. Lions, A Definition of the Ground State Energy for Systems Composed of Infinitely Many Particles, Communications in Partial Differential Equations, vol.35, issue.1-2, pp.439-475, 2003.
DOI : 10.1081/PDE-120019389

F. Bloch, ???ber die Quantenmechanik der Elektronen in Kristallgittern, Zeitschrift f???r Physik, vol.52, issue.7-8, pp.555-560, 1928.
DOI : 10.1007/BF01339455

D. Boffi, F. Brezzi, and L. Gastaldi, On the problem of spurious eigenvalues in the approximation of linear elliptic problems in mixed form, Mathematics of Computation, vol.69, issue.229, pp.121-140, 1999.
DOI : 10.1090/S0025-5718-99-01072-8

L. Boulton, Non-variational approximation of discrete eigenvalues of self-adjoint operators, IMA Journal of Numerical Analysis, vol.27, issue.1, pp.102-121, 2007.
DOI : 10.1093/imanum/drl015

L. Boulton and N. Boussaid, Abstract, LMS Journal of Computation and Mathematics, vol.44, pp.10-32, 2010.
DOI : 10.1112/S1461157008000429

L. Boulton, N. Boussaid, and M. Lewin, Generalised Weyl theorems and spectral pollution in the Galerkin method, Journal of Spectral Theory, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00536270

L. Boulton and M. Levitin, On approximation of the eigenvalues of perturbed periodic Schr??dinger operators, Journal of Physics A: Mathematical and Theoretical, vol.40, issue.31, pp.9319-9329, 2007.
DOI : 10.1088/1751-8113/40/31/010

S. Boyaval, C. Le-bris, T. Lelièvre, Y. Maday, N. C. Nguyen et al., Reduced Basis Techniques for Stochastic Problems, Archives of Computational Methods in Engineering, vol.8, issue.1, pp.435-454, 2010.
DOI : 10.1007/s11831-010-9056-z

URL : https://hal.archives-ouvertes.fr/hal-00470522

S. Boyaval, C. Le-bris, Y. Maday, N. C. Nguyen, and A. T. Patera, A reduced basis approach for variational problems with stochastic parameters: Application to heat conduction with variable Robin coefficient, Computer Methods in Applied Mechanics and Engineering, vol.198, issue.41-44, pp.3187-3206, 2009.
DOI : 10.1016/j.cma.2009.05.019

URL : https://hal.archives-ouvertes.fr/inria-00311463

H. Brézis, R. Benguria, and E. H. Lieb, The Thomas-Fermi-von Weiszäcker theory of atoms and molecules, Communications in Mathematical Physics, vol.79, pp.167-180, 1981.

A. Brezzi and M. Fortin, Mixed and Hybrid finite element methods, 1991.
DOI : 10.1007/978-1-4612-3172-1

A. Buffa, Y. Maday, A. T. Patera, C. Prud-'homme, and G. Turinici, convergence of the Greedy algorithm for the parametrized reduced basis method, ESAIM: Mathematical Modelling and Numerical Analysis, vol.46, issue.3, pp.595-603, 2012.
DOI : 10.1051/m2an/2011056

URL : https://hal.archives-ouvertes.fr/hal-00659314

H. Bungartz, An adaptative Poisson solver using hierarchical bases and sparse grids. Iterative Methods in Linear Algebra, pp.293-310, 1992.

H. Bungartz and M. Griebel, Sparse grids, Acta Numerica, vol.13, pp.147-269, 2004.
DOI : 10.1017/S0962492904000182

R. E. Caflisch, Monte Carlo and quasi-Monte Carlo methods, Acta Numerica, vol.73, pp.1-49, 1998.
DOI : 10.1137/S0036142994277468

R. H. Cameron and W. T. Martin, The Orthogonal Development of Non-Linear Functionals in Series of Fourier-Hermite Functionals, The Annals of Mathematics, vol.48, issue.2, pp.385-392, 1947.
DOI : 10.2307/1969178

E. Cancès, R. Chakir, and Y. Maday, Numerical analysis of the planewave discretization of some orbital-free and Kohn-Sham models, ESAIM: Mathematical Modelling and Numerical Analysis, vol.46, issue.2, pp.341-388, 2012.
DOI : 10.1051/m2an/2011038

E. Cancès, A. Deleurence, and M. Lewin, A New Approach to the Modeling of Local Defects in Crystals: The Reduced Hartree-Fock Case, Communications in Mathematical Physics, vol.9, issue.8, pp.129-177, 2008.
DOI : 10.1007/s00220-008-0481-x

E. Cancès, A. Deleurence, and M. Lewin, Non-perturbative embedding of local defects in crystalline materials, Journal of Physics: Condensed Matter, vol.20, issue.29, p.294213, 2008.
DOI : 10.1088/0953-8984/20/29/294213

E. Cancès and V. Ehrlacher, Local defects are always neutral in the Thomas-Fermivon Weiszäcker theory of crystals. Archive for Rational Mechanics and Analysis, pp.933-973, 2011.

E. Cancès, V. Ehrlacher, and T. Lelièvre, CONVERGENCE OF A GREEDY ALGORITHM FOR HIGH-DIMENSIONAL CONVEX NONLINEAR PROBLEMS, Mathematical Models and Methods in Applied Sciences, vol.21, issue.12, pp.2433-2467, 2011.
DOI : 10.1142/S0218202511005799

E. Cancès, V. Ehrlacher, and Y. Maday, Periodic Schrödinger operators with local defects and spectral pollution, 2011.

E. Cancès, V. Ehrlacher, and Y. Maday, Non-consistent approximations of selfadjoint eigenproblems: Application to the supercell method, 2012.

E. Cancès, C. L. Bris, and Y. Maday, Méthodes mathématiques en chimie quantique: une introdution, 2006.

E. Cancès and M. Lewin, The dielectric permittivity of crystals in the reduced Hartree-Fock approximation. Archive for Rational Mechanics and Analysis, pp.139-177, 2010.

E. Cancès and G. Stoltz, A mathematical formulation of the random phase approximation for crystals, 2011.

E. Candès, J. Romberg, and T. Tao, Robust uncertainty principles: exact signal reconstruction from highly incomplete frequency information, IEEE Transactions on Information Theory, vol.52, issue.2, pp.489-509, 2006.
DOI : 10.1109/TIT.2005.862083

E. Candès, J. Romberg, and T. Tao, Stable signal recovery from incomplete and inaccurate measurements, Communications on Pure and Applied Mathematics, vol.7, issue.8, pp.1207-1223, 2006.
DOI : 10.1002/cpa.20124

E. Candès and T. Tao, Decoding by Linear Programming, IEEE Transactions on Information Theory, vol.51, issue.12, pp.4203-4215, 2005.
DOI : 10.1109/TIT.2005.858979

E. J. Candès, The restricted isometry property and its implications for compressed sensing, Comptes Rendus de l'Acdémie des Sciences de Paris, pp.589-592, 2008.
DOI : 10.1016/j.crma.2008.03.014

I. Catto, C. L. Bris, and P. Lions, Limite thermodynamique pour des modèles de type Thomas-Fermi, Notes aux Comptes Rendus de l'Académie des Sciences, pp.357-364, 1996.
DOI : 10.1016/s0764-4442(98)80143-2

I. Catto, C. L. Bris, and P. Lions, Mathematical theory of thermodynamic limits: Thomas-Fermi type models, 1998.
URL : https://hal.archives-ouvertes.fr/hal-00157706

I. Catto, C. L. Bris, and P. Lions, Sur la limite thermodynamique pour des mod??les de type Hartree et Hartree-Fock, Notes aux Comptes Rendus de l'Académie des Sciences, pp.259-266, 1998.
DOI : 10.1016/S0764-4442(98)80143-2

I. Catto, C. L. Bris, and P. Lions, Recent mathematical results on the quantum modeling of crystals, Lecture Notes in Chemistry, vol.74, pp.95-119, 2000.
DOI : 10.1007/978-3-642-57237-1_5

I. Catto, C. L. Bris, and P. Lions, On the thermodynamic limit for Hartree-Fock type models. Annales de l'Institut Henri Poincaré, Analyse non linéaire, pp.687-760, 2001.
URL : https://hal.archives-ouvertes.fr/hal-00157679

I. Catto, C. L. Bris, and P. Lions, On some periodic Hartree-type models for crystals. Annales de l'Institut Henri Poincaré, Analyse non linéaire, vol.19, pp.143-190, 2002.
URL : https://hal.archives-ouvertes.fr/hal-00157675

P. Chaix and D. Iracane, From quantum electrodynamics to mean-field theory. I. The Bogoliubov-Dirac-Fock formalism, Journal of Physics B: Atomic, Molecular and Optical Physics, vol.22, issue.23, pp.3791-3814, 1989.
DOI : 10.1088/0953-4075/22/23/004

F. Chatelin, Spectral Approximation of Linear Operators, 1983.
DOI : 10.1137/1.9781611970678

A. Chkifa, A. Cohen, R. Devore, and C. Schwab, Sparse adaptive Taylor approximation algorithms for parametric and stochastic elliptic PDEs, ESAIM: Mathematical Modelling and Numerical Analysis, vol.47, issue.1, 2011.
DOI : 10.1051/m2an/2012027

A. Cohen, R. Devore, and C. Schwab, Convergence Rates of Best N-term Galerkin Approximations for a Class of Elliptic sPDEs, Foundations of Computational Mathematics, vol.60, issue.6, pp.615-646, 2010.
DOI : 10.1007/s10208-010-9072-2

A. Cohen, R. Devore, and C. Schwab, ANALYTIC REGULARITY AND POLYNOMIAL APPROXIMATION OF PARAMETRIC AND STOCHASTIC ELLIPTIC PDE'S, Analysis and Applications, vol.09, issue.01, pp.11-47, 2011.
DOI : 10.1142/S0219530511001728

M. L. Cohen and T. K. Bergstresser, Band Structures and Pseudopotential Form Factors for Fourteen Semiconductors of the Diamond and Zinc-blende Structures, Physical Review, vol.141, issue.2, pp.789-796, 1966.
DOI : 10.1103/PhysRev.141.789

L. Conlon, Differentiable Manifolds: A First Course, 1993.

C. Cotar, G. Friesecke, and C. Kluppelberg, Density Functional Theory and Optimal Transportation with Coulomb Cost, Communications on Pure and Applied Mathematics, vol.12, issue.3, 2011.
DOI : 10.1002/cpa.21437

W. Dai and O. Milenkovich, Subspace pursuit for compressed sensing: Closing the gap between performance and complexity, IEEE Journal of Selected Topics in Signal Processing, vol.4, pp.310-316, 2010.

M. Dauge and M. Suri, Numerical approximation of the spectra of non-compact operators arising in buckling problems, Journal of Numerical Mathematics, vol.10, issue.3, pp.193-219, 2002.
DOI : 10.1515/JNMA.2002.193

E. Davies and M. Plum, Spectral pollution, IMA Journal of Numerical Analysis, vol.24, issue.3, pp.417-438, 2004.
DOI : 10.1093/imanum/24.3.417

URL : http://imajna.oxfordjournals.org/cgi/content/short/24/3/417

E. B. Davis and M. Plum, Spectral pollution, IMA Journal of Numerical Analysis, vol.24, issue.3, pp.417-438, 2004.
DOI : 10.1093/imanum/24.3.417

L. De-lathauwer, B. De, J. Moor, and . Vandewalle, A Multilinear Singular Value Decomposition, SIAM Journal on Matrix Analysis and Applications, vol.21, issue.4, pp.1253-1278, 2000.
DOI : 10.1137/S0895479896305696

L. De-lathauwer, B. De, J. Moor, and . Vandewalle, ) Approximation of Higher-Order Tensors, SIAM Journal on Matrix Analysis and Applications, vol.21, issue.4, pp.1324-1342, 2000.
DOI : 10.1137/S0895479898346995

V. De-silva and L. H. Lim, Tensor Rank and the Ill-Posedness of the Best Low-Rank Approximation Problem, SIAM Journal on Matrix Analysis and Applications, vol.30, issue.3, pp.1084-1127, 2008.
DOI : 10.1137/06066518X

A. Deleurence, Modélisation mathématique et simulation numérique de la structure électronique de cristaux en présence de défauts ponctuels, 2008.

J. Descloux, Essential Numerical Range of an Operator with Respect to a Coercive form and the Approximation of Its Spectrum by the Galerkin Method, SIAM Journal on Numerical Analysis, vol.18, issue.6, pp.1128-1133, 1981.
DOI : 10.1137/0718077

J. Descloux, N. Nassif, and J. Rappaz, On spectral approximation. Part 1: The problem of convergence. RAIRO Analyse numérique, pp.97-112, 1978.

J. Descloux, N. Nassif, and J. Rappaz, On spectral approximation. Part 2. Error estimates for the Galerkin method, RAIRO. Analyse num??rique, vol.12, issue.2, pp.113-119, 1978.
DOI : 10.1051/m2an/1978120201131

R. Devore, R. Howard, and C. A. Micchelli, Optimal nonlinear approximation, Manuscripta Mathematica, vol.29, issue.4, pp.469-478, 1989.
DOI : 10.1007/BF01171759

R. A. Devore and V. N. Temlyakov, Some remarks on greedy algorithms, Advances in Computational Mathematics, vol.102, issue.1, pp.173-187, 1996.
DOI : 10.1007/BF02124742

D. L. Donoho, Compressed sensing, IEEE Transactions on Information Theory, vol.52, issue.4, pp.5406-5425, 2006.
DOI : 10.1109/TIT.2006.871582

URL : https://hal.archives-ouvertes.fr/inria-00369486

D. L. Donoho, Y. Tsaig, and J. Starck, Sparse solution of undetermined linear equations by stagewise orthogonal matching pursuit, 2006.

A. Doostan, R. Ghanem, and J. Red-horse, Stochastic model reduction for chaos representations, Computer Methods in Applied Mechanics and Engineering, vol.196, issue.37-40, pp.3951-3966, 2007.
DOI : 10.1016/j.cma.2006.10.047

A. Doostan and H. Owhadi, A non-adapted sparse approximation of PDEs with stochastic inputs, Journal of Computational Physics, vol.230, issue.8, pp.3015-3034, 2011.
DOI : 10.1016/j.jcp.2011.01.002

R. M. Dreizler and E. K. Gross, Density Functional Theory, 1990.
DOI : 10.1007/978-3-642-86105-5

W. E. , W. Ren, and E. Van-den-eijnden, A string method for the study of rare events, Physical Review B, vol.66, p.52301, 2002.

L. Eldén and B. Savas, A Newton???Grassmann Method for Computing the Best Multilinear Rank-$(r_1,$ $r_2,$ $r_3)$ Approximation of a Tensor, SIAM Journal on Matrix Analysis and Applications, vol.31, issue.2, pp.248-271, 2009.
DOI : 10.1137/070688316

A. Ern and J. Guermond, Theory and Practice of Finite Elements, Applied Mathematical Series, vol.159, 2004.
DOI : 10.1007/978-1-4757-4355-5

C. Fefferman, The thermodynamic limit for a crystal, Communications in Mathematical Physics, vol.9, issue.3, pp.289-311, 1985.
DOI : 10.1007/BF01205785

E. Fermi, Un Metodo Statistico per la Determinazione di alcune Prioprietà dell'Atomo, Rendiconti Accademia Nazionale Lincei, vol.6, pp.602-607, 1927.

L. Figueroa and E. Suli, Greedy Approximation of High-Dimensional Ornstein- Uhlenbeck Operators with Unbounded Drift, 2011.

S. Fliss and P. Joly, Exact boundary conditions for time-harmonic wave propagation in locally perturbed periodic media, Applied Numerical Mathematics, vol.59, issue.9, pp.2155-2178, 2009.
DOI : 10.1016/j.apnum.2008.12.013

URL : https://hal.archives-ouvertes.fr/hal-00873067

S. Fliss and P. Joly, Wave propagation in locally perturbed periodic media (case with absorption): Numerical aspects, Journal of Computational Physics, vol.231, issue.4, pp.1244-1271, 2012.
DOI : 10.1016/j.jcp.2011.10.007

URL : https://hal.archives-ouvertes.fr/hal-00849566

G. Floquet, Sur les équations différentielles linéaires à coefficients périodiques. Annales Scientifiques de l'Ecole Normale Supérieure, pp.47-89, 1883.

M. Fortin and R. Glowinski, Méthodes de Lagrangien augmenté -Application à la résolution numérique de problèmes aux limites. Dunod, 1982.

G. Friesecke, The Multiconfiguration Equations for Atoms and Molecules: Charge Quantization and Existence of Solutions. Archive for Rational Mechanics and Analysis, pp.35-71, 2003.

R. Ghanem and P. Spanos, Stochastic finite elements: a spectral approach, 1991.
DOI : 10.1007/978-1-4612-3094-6

M. Ghimenti and M. Lewin, Properties of periodic Hartree???Fock minimizers, Calculus of Variations and Partial Differential Equations, vol.33, issue.4, pp.39-56, 2009.
DOI : 10.1007/s00526-008-0196-z

R. Glowinski and P. L. Tallec, Augmented Lagrangian and Operator-Splitting Methods in Nonlinear Mechanics, Society for Industrial and Applied Mathematics, 1989.
DOI : 10.1137/1.9781611970838

R. Glowinski, J. Lions, and R. Trémolières, Analyse numérique des inéquations variationnelles -Théorie générale et premières applications, 1976.

L. Grasedyck, Hierarchical Singular Value Decomposition of Tensors, SIAM Journal on Matrix Analysis and Applications, vol.31, issue.4, pp.2029-2054, 2010.
DOI : 10.1137/090764189

M. Griebel and S. Knapek, Optimized Tensor-Product Approximation Spaces, Constructive Approximation, vol.16, issue.4, pp.525-540, 2000.
DOI : 10.1007/s003650010010

M. Griesemer and F. Hantsch, Unique Solutions to Hartree-Fock Equations for Closed Shell Atoms. to appear in Archive for Rational Mechanics and Analysis, 2011.

D. J. Griffiths, Introduction to Quantum Mechanics, 2004.

C. Grossmann, H. Roos, and M. Stynes, Numerical Treatment of Partial Differential Equations, 2007.
DOI : 10.1007/978-3-540-71584-9

D. Guilbarg and N. S. Trudinger, Elliptic partial differential equations of second order, 1983.

W. Hackbusch, Tensor Spaces and Numerical Tensor Calculus, 2012.
DOI : 10.1007/978-3-642-28027-6

W. Hackbusch and S. Kuhn, A New Scheme for the Tensor Representation, Journal of Fourier Analysis and Applications, vol.5, issue.3, pp.706-722, 2009.
DOI : 10.1007/s00041-009-9094-9

C. Hainzl, M. Lewin, and E. Séré, Existence of atoms and molecules in the meanfield approximation of no-photon quantum electrodynamics. Archive for Rational Mechanics and Analysis, pp.453-499, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00096320

C. Hainzl, M. Lewin, E. Séré, and J. P. Solovej, Minimization method for relativistic electrons in a mean-field approximation of quantum electrodynamics, Physical Review A, vol.76, issue.5, p.52104, 2007.
DOI : 10.1103/PhysRevA.76.052104

URL : https://hal.archives-ouvertes.fr/hal-00154152

C. Hainzl, M. Lewin, and J. P. Solovej, The mean-field approximation in quantum electrodynamics: The no-photon case, Communications on Pure and Applied Mathematics, vol.35, issue.4, pp.546-596, 2007.
DOI : 10.1002/cpa.20145

URL : https://hal.archives-ouvertes.fr/hal-00154147

C. Hainzl, M. Lewin, and J. P. Solovej, The thermodynamic limit of quantum Coulomb systems Part I. General theory, Advances in Mathematics, vol.221, issue.2, pp.454-487, 2009.
DOI : 10.1016/j.aim.2008.12.010

URL : https://hal.archives-ouvertes.fr/hal-00334555

C. Hainzl, M. Lewin, and J. P. Solovej, The thermodynamic limit of quantum Coulomb systems, Part II: Applications. Advances in Mathematics, vol.221, pp.488-546, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00334556

A. C. Hansen, On the approximation of spectra of linear operators on Hilbert spaces, Journal of Functional Analysis, vol.254, issue.8, pp.2092-2126, 2008.
DOI : 10.1016/j.jfa.2008.01.006

P. Hohenberg and W. Kohn, Inhomogeneous Electron Gas, Physical Review, vol.136, issue.3B, pp.864-871, 1964.
DOI : 10.1103/PhysRev.136.B864

S. Holtz, T. Rohwedder, and R. Schneider, The Alternating Linear Scheme for Tensor Optimization in the TT format, To appear in SIAM Journal on Scientific Computing, 2011.

S. Holtz, T. Rohwedder, and R. Schneider, On manifolds of tensors of fixed TT-rank, Numerische Mathematik, vol.69, issue.14, 2011.
DOI : 10.1007/s00211-011-0419-7

R. O. Jones and O. Gunnarson, The density functional formalism, its applications and prospects, Reviews of Modern Physics, vol.61, issue.3, pp.689-746, 1989.
DOI : 10.1103/RevModPhys.61.689

K. Karhunen, Zur Spektraltheorie stochasticher Prozesse, Annales Academiae Scientiarum Fennicae, vol.34, 1946.

M. Kleiber and T. D. Hien, The stochastic finite element method. Basic perturbation technique and computer implementation, 1992.

O. Koch and C. Lubich, Dynamical Tensor Approximation, SIAM Journal on Matrix Analysis and Applications, vol.31, issue.5, p.2360, 2010.
DOI : 10.1137/09076578X

URL : http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.158.7563

W. Kohn and L. J. Sham, Self-Consistent Equations Including Exchange and Correlation Effects, Physical Review, vol.140, issue.4A, pp.1133-1138, 1965.
DOI : 10.1103/PhysRev.140.A1133

T. G. Kolda and B. W. Bader, Tensor Decompositions and Applications, SIAM Review, vol.51, issue.3, pp.455-500, 2009.
DOI : 10.1137/07070111X

URL : http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.130.782

E. Korotyaev, Lattice Dislocations in a 1-Dimensional Model, Communications in Mathematical Physics, vol.213, issue.2, pp.471-489, 2000.
DOI : 10.1007/PL00005529

P. Ladevèze, Nonlinear computational structural mechanics: new approaches and non-incremental methods of calculation, 1999.
DOI : 10.1007/978-1-4612-1432-8

S. Lahbabi, in preparation, Thèse de l, 2013.

D. C. Langreth and J. P. Perdew, Theory of nonuniform electronic systems. I. Analysis of the gradient approximation and a generalization that works, Physical Review B, vol.21, issue.12, pp.5469-5493, 1980.
DOI : 10.1103/PhysRevB.21.5469

B. Langwallner, C. Ortner, and E. Suli, EXISTENCE AND CONVERGENCE RESULTS FOR THE GALERKIN APPROXIMATION OF AN ELECTRONIC DENSITY FUNCTIONAL, Mathematical Models and Methods in Applied Sciences, vol.20, issue.12, 2009.
DOI : 10.1142/S021820251000491X

C. and L. Bris, Quelques problèmes mathématiques en chimie quantique moléculaire, Thèse de l'Ecole Polytechnique, 1993.

C. and L. Bris, Some results on the Thomas-Fermi-Dirac-von Weiszäcker model, Differential and Integral Equations, vol.6, pp.337-353, 1993.

C. and L. Bris, A general approach for multiconfiguration methods in quantum molecular chemsitry. Annales de l'Institut Henri Poincaré, pp.441-484, 1994.

C. , L. Bris, T. Lelièvre, and Y. Maday, Results and Questions on a Nonlinear Approximation Approach for Solving High-dimensional Partial Differential Equations, Construsctive Approximation, vol.30, pp.621-651, 2009.
URL : https://hal.archives-ouvertes.fr/inria-00336911

M. Levitin and E. Shargorodsky, Spectral pollution and second-order relative spectra for self-adjoint operators, IMA Journal of Numerical Analysis, vol.24, issue.3, pp.393-416, 2004.
DOI : 10.1093/imanum/24.3.393

A. Levy and J. Rubinstein, Hilbert-space Karhunen???Lo??ve transform with application to image analysis, Journal of the Optical Society of America A, vol.16, issue.1, pp.28-35, 1999.
DOI : 10.1364/JOSAA.16.000028

M. Lewin, Solutions of the multiconfigurational equations in quantum chemistry Archives for Rational Mechanics and Analysis, pp.83-114, 2004.

M. Lewin and E. Séré, Spectral pollution and how to avoid it (with applications to Dirac and periodic Schrödinger operators) Proceedings of the, pp.864-900, 2010.

E. H. Lieb, Thomas-fermi and related theories of atoms and molecules, Reviews of Modern Physics, vol.53, issue.4, pp.603-641, 1981.
DOI : 10.1103/RevModPhys.53.603

E. H. Lieb, Variational Principle for Many-Fermion Systems, Physical Review Letters, vol.46, issue.7, pp.457-459, 1981.
DOI : 10.1103/PhysRevLett.46.457

E. H. Lieb, Density Functional for Coulomb systems, International Journal of Quantum Chemistry, vol.24, pp.143-277, 1983.

E. H. Lieb and B. Simon, The Hartree-Fock theory for Coulomb systems, Communications in Mathematical Physics, vol.22, issue.3, pp.185-194, 1977.
DOI : 10.1007/BF01609845

E. H. Lieb and B. Simon, The Thomas-Fermi theory of atoms, molecules and solids, Advances in Mathematics, vol.23, issue.1, pp.22-116, 1977.
DOI : 10.1016/0001-8708(77)90108-6

P. Lions, The concentration-compactness principle in the calculus of variations. The locally compact case, part 1 and 2. Annales de l'Institut Henri Poincaré, pp.109-145, 1984.

P. Lions, Solutions of Hartree-Fock equations for Coulomb systems, Communications in Mathematical Physics, vol.22, issue.1, pp.33-97, 1987.
DOI : 10.1007/BF01205672

M. Loève, Fonctions aléatoires du second ordre. Comptes Rendus de l'Académie des Sciences de Paris, 1945.

C. Lubich, From Quantum to Classical Molecular Dynamics: Reduced Methods and Numerical Analysis. Zurich Lectures in advanced mathematics, EMS, 2008.

Y. Maday, N. C. Nguyen, A. T. Patera, and G. S. Pau, A general multipurpose interpolation procedure: the magic points, Communications on Pure and Applied Analysis, vol.8, issue.1, pp.383-404, 2009.
DOI : 10.3934/cpaa.2009.8.383

URL : https://hal.archives-ouvertes.fr/hal-00174797

G. D. Mahan, Many Particle Physics (Physics of Solids and Liquids), 2000.

M. Mantoiu and R. Purice, A priori decay for eigenfunctions of perturbed periodic Schrödinger operators, Annales de l'Institut Henri Poincaré, pp.525-521, 2001.

M. D. Mckay, R. J. Beckman, and W. J. Conover, A Comparison of Three Methods for Selecting Values of Input Variables in the Analysis of Output from a Computer Code, Technometrics, vol.21, pp.239-245, 1979.

W. H. Mills, Optimal Error Estimates for the Finite Element Spectral Approximation of Noncompact Operators, SIAM Journal on Numerical Analysis, vol.16, issue.4, pp.704-718, 1979.
DOI : 10.1137/0716053

W. H. Mills, The Resolvent Stability Condition for Spectra Convergence with Application to the Finite Element Approximation of Noncompact Operators, SIAM Journal on Numerical Analysis, vol.16, issue.4, pp.695-703, 1979.
DOI : 10.1137/0716052

D. Needell and J. A. Tropp, CoSaMP, Communications of the ACM, vol.53, issue.12, pp.301-321, 2009.
DOI : 10.1145/1859204.1859229

D. Needell and R. Vershynin, Signal Recovery From Incomplete and Inaccurate Measurements Via Regularized Orthogonal Matching Pursuit, IEEE Journal of Selected Topics in Signal Processing, vol.4, issue.2, 2007.
DOI : 10.1109/JSTSP.2010.2042412

R. B. Nelsen, An Introduction to Copulas, 1999.
DOI : 10.1007/978-1-4757-3076-0

A. Nouy, Recent Developments in Spectral Stochastic Methods for??the??Numerical Solution of Stochastic Partial Differential Equations, Archives of Computational Methods in Engineering, vol.24, issue.2, pp.251-285, 2009.
DOI : 10.1007/s11831-009-9034-5

URL : https://hal.archives-ouvertes.fr/hal-00366636

A. Nouy, A priori tensor approximations for the numerical solution of high dimensional problems: alternative definitions, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00664061

A. Nouy and A. Falco, Proper Generalized Decomposition for Nonlinear Convex Problems in Tensor Banach Spaces, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00609108

A. Nouy and O. L. Maitre, Generalized spectral decomposition for stochastic nonlinear problems, Journal of Computational Physics, vol.228, issue.1, pp.202-235, 2009.
DOI : 10.1016/j.jcp.2008.09.010

I. V. Oseledets, Tensor-Train Decomposition, SIAM Journal on Scientific Computing, vol.33, issue.5, pp.2295-2317, 2011.
DOI : 10.1137/090752286

J. P. Perdew, K. Burke, and M. Ernzerhof, Generalized Gradient Approximation Made Simple, Physical Review Letters, vol.77, issue.18, pp.3865-3868, 1996.
DOI : 10.1103/PhysRevLett.77.3865

J. P. Perdew and Y. Wang, Accurate and simple density functional for the electronic exchange energy: Generalized gradient approximation, Physical Review B, vol.33, issue.12, pp.8800-8802, 1986.
DOI : 10.1103/PhysRevB.33.8800

C. Pisani, Quantum-mechanical treatment of the energetics of local defects in crystals: A few answers and many open questions, Phase Transitions, vol.2, issue.2-3, pp.123-136, 1994.
DOI : 10.1063/1.463922

J. Rappaz, J. Sanchez-hubert, J. Sanchez-palencia, and D. Vasiliev, On spectral pollution in the finite element approximation of thin elastic "membrane" shells, Numerische Mathematik, vol.75, issue.4, pp.473-500, 1997.
DOI : 10.1007/s002110050249

M. Reed and B. Simon, Methods of Modern Mathematical Physics IV: Analysis of Operators, 1978.

R. Schneider, T. Rohwedder, and O. Legeza, Tensor methods in quantum chemistry, 2012.

V. Shabaev, I. I. Tupitsyn, V. A. Yerokhin, G. Plunien, and G. Soff, Dual Kinetic Balance Approach to Basis-Set Expansions for the Dirac Equation, Physical Review Letters, vol.93, issue.13, p.130405, 2004.
DOI : 10.1103/PhysRevLett.93.130405

E. Shargorodsky, Geometry of higher order relative spectra and projection methods, Journal of Operator Theory, vol.44, pp.43-62, 2000.

B. Simon, Schrödinger semigroups. Bulletin of the, pp.447-526, 1982.

S. Smolyak, Quadrature and interpolation formulas for tensor products of certain classes of functions, Soviet Mathematics Doklady, vol.3, pp.240-243, 1963.

J. P. Solovej, Universality in the Thomas-Fermi-von Weizs??cker model of atoms and molecules, Communications in Mathematical Physics, vol.5, issue.3, pp.561-598, 1990.
DOI : 10.1007/BF02097106

J. P. Solovej, Proof of the ionization conjecture in a reduced Hartree-Fock model, Inventiones mathematicae, vol.79, issue.1, pp.291-311, 1991.
DOI : 10.1007/BF01245077

S. Soussi, Convergence of the Supercell Method for Defect Modes Calculations in Photonic Crystals, SIAM Journal on Numerical Analysis, vol.43, issue.3, pp.1175-1201, 2005.
DOI : 10.1137/040616875

V. N. Temlyakov, Greedy Approximation, Acta Numerica, vol.17, pp.235-409, 2008.
DOI : 10.1017/cbo9780511762291

L. H. Thomas, The calculation of atomic fields, Mathematical Proceedings of the Cambridge Philosophical Society, vol.23, issue.05, pp.542-548, 1927.
DOI : 10.1017/S0305004100011683

J. Tropp and A. Gilbert, Signal Recovery From Random Measurements Via Orthogonal Matching Pursuit, IEEE Transactions on Information Theory, vol.53, issue.12, pp.4655-4666, 2007.
DOI : 10.1109/TIT.2007.909108

URL : http://authors.library.caltech.edu/9490/1/TROieeetit07.pdf

N. S. Trudinger, Linear elliptic operators with measurable coefficients, pp.265-308, 1973.

J. Tryoen, Adaptive stochastic Galerkin methods for parametric uncertainty propagation in hyperbolic systems, Thèse de l, 2012.
URL : https://hal.archives-ouvertes.fr/pastel-00795322

T. Petersdorff and C. Schwab, Numerical solution of parabolic equations in high dimensions, ESAIM: Mathematical Modelling and Numerical Analysis, vol.38, issue.1, pp.93-127, 2004.
DOI : 10.1051/m2an:2004005

C. G. Webster, F. Nobile, and R. Tempone, A sparse grid collocation method for partial differential equations with random input data, SIAM Journal on Numerical Analysis, vol.46, pp.2309-2345, 2007.

C. F. Weiszäcker, Zur Theorie der Kernmassen, Zeitschrif für Physik, pp.431-458, 1935.

N. Wiener, The Homogeneous Chaos, American Journal of Mathematics, vol.60, issue.4, pp.897-936, 1938.
DOI : 10.2307/2371268

D. B. Xiu and G. E. Karniadakis, The Wiener--Askey Polynomial Chaos for Stochastic Differential Equations, SIAM Journal on Scientific Computing, vol.24, issue.2, pp.619-644, 2002.
DOI : 10.1137/S1064827501387826

C. Zenger, Sparse grids. Parallel Algorithms for Partial Differential Equations, Hackbusch, Vieweg, pp.241-251

V. Zheludev, The spectrum of Schrödinger operator, with a periodic potential, defined on the half-axis, pp.18-37, 1969.

A. Zhou, Finite dimensional approximations for the electronic ground state solution of a molecular system, Mathematical Methods in the Applied Sciences, vol.26, issue.4, pp.429-447, 1990.
DOI : 10.1002/mma.793