Peralkylated Polyaminophosphazenes??? Extremely Strong, Neutral Nitrogen Bases, Angewandte Chemie International Edition in English, vol.26, issue.11, pp.1167-1169, 1987. ,
DOI : 10.1002/anie.198711671
Superbases for Organic Synthesis, Chem. Rev, vol.59, issue.35364, pp.515-568, 1959. ,
DOI : 10.1002/9780470740859
??ber neue organische Phosphorverbindungen IV Phosphinimine, Helvetica Chimica Acta, vol.2, issue.1, pp.861-886, 1921. ,
DOI : 10.1002/hlca.19210040192
Proof of N??N??-Elimination from Staudinger Adducts R3P???N?????N?????N?????X by15N-Isotopic Labeling, Angewandte Chemie International Edition in English, vol.7, issue.8, pp.636-636, 1968. ,
DOI : 10.1002/anie.196806361
Staudinger reaction between triarylphosphines and azides. Mechanism, Journal of the American Chemical Society, vol.89, issue.20, pp.5235-5246, 1967. ,
DOI : 10.1021/ja00996a027
???ber die Umsetzung von Tris(dimethylamino)phosphin, Triisopropylphosphin undtButyldifluorphosphin mit terti???ren Alkylaziden: Phosphazidbildung versus Phosphinimidbildung. R???ntgenstrukturen von Triphenylmethylazid und Tris(dimethylamino)-N-triphenylmethylphosphazid, Zeitschrift f???r anorganische und allgemeine Chemie, vol.10, issue.4, pp.707-715, 1994. ,
DOI : 10.1002/zaac.19946200421
New Cage Compounds: Preparation and Characterization of ChiralC3-Symmetric Macrobicyclic Tris(phosphazides), Angewandte Chemie International Edition in English, vol.36, issue.12, pp.67-70, 1997. ,
DOI : 10.1002/anie.199700671
Tripod-Tripod Coupling of Triazides with Triphosphanes. The Synthesis, Characterization, and Stability in Solution of New Cage Compounds: Chiral Macrobicyclic Triphosphazides, Chemistry - A European Journal, vol.4, issue.12, pp.2558-2570, 1998. ,
DOI : 10.1002/(SICI)1521-3765(19981204)4:12<2558::AID-CHEM2558>3.0.CO;2-3
Substituent effects on the phosphorus-31, nitrogen-15, and carbon-13 NMR spectra of N-(arylsulfonyl)-P,P,P-triphenylphospha-.lambda.5-azenes and on the nitrogen-15 and carbon-13 NMR spectra of the corresponding arenesulfonamides, The Journal of Organic Chemistry, vol.52, issue.1, pp.159-163, 1987. ,
DOI : 10.1021/jo00377a031
Cycloruthenated Complexes from Iminophosphoranes: Synthesis, Structure, and Reactivity with Internal Alkynes, Organometallics, vol.30, issue.3, pp.642-648, 2011. ,
DOI : 10.1021/om100997x
Phosphororganische Verbindungen, XVIII Phosphinimino-Verbindungen aus Phosphindihalogeniden und prim??ren Aminen, Justus Liebigs Annalen der Chemie, vol.115, issue.1, pp.142-162, 1959. ,
DOI : 10.1002/jlac.19596270115
Synthesis of Some Triphenylphosphinalkylimines and Mono- and Dialkylaminotriphenylphosphonium Halides, The Journal of Organic Chemistry, vol.28, issue.2, pp.483-486, 1963. ,
DOI : 10.1021/jo01037a052
Synthesis of New Mixed Phosphine???Iminophosphorane Bidentate Ligands and Their Coordination to Group 10 Metal Centers, Organometallics, vol.24, issue.6, pp.1065-1074, 2005. ,
DOI : 10.1021/om0490684
URL : https://hal.archives-ouvertes.fr/hal-00086060
A Mixed Phosphine???Iminophosphorane Tetradentate Ligand: Synthesis, Coordination to Group 10 Metal Centers, and Use as Catalyst in Suzuki???Miyaura Coupling, Organometallics, vol.27, issue.17, pp.4380-4385, 2008. ,
DOI : 10.1021/om8002637
Nouveaux ligands mixtes phosphorés: synthèse, coordination et étude de réactivité, 2010. ,
The aza-Wittig reaction: an efficient tool for the construction of carbon???nitrogen double bonds, Tetrahedron, vol.63, issue.3, pp.523-575, 2007. ,
DOI : 10.1016/j.tet.2006.09.048
A ???Traceless??? Staudinger Ligation for the Chemoselective Synthesis of Amide Bonds, Organic Letters, vol.2, issue.14, pp.2141-2143, 2000. ,
DOI : 10.1021/ol006054v
Staudinger Ligation:??? A Peptide from a Thioester and Azide, Organic Letters, vol.2, issue.13, pp.1939-1941, 2000. ,
DOI : 10.1021/ol0060174
The Staudinger Ligation???A Gift to Chemical Biology, Angewandte Chemie International Edition, vol.43, issue.24, pp.3106-3116, 2004. ,
DOI : 10.1002/anie.200401744
Organotin(IV) Derivatives of Some O,C,O-Chelating Ligands, Organometallics, vol.21, issue.19, pp.3996-4004, 2002. ,
DOI : 10.1021/om020361i
Eds.; Topics in Organometallic Chemistry, 2013. ,
Platinum Group Organometallics Based on ???Pincer??? Complexes: Sensors, Switches, and Catalysts, Angewandte Chemie International Edition, vol.57, issue.302, pp.3750-3781, 2001. ,
DOI : 10.1002/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO;2-6
Cyclometalated Phosphine-Based Pincer Complexes:?? Mechanistic Insight in Catalysis, Coordination, and Bond Activation, Chemical Reviews, vol.103, issue.5, pp.1759-1792, 2003. ,
DOI : 10.1021/cr960118r
Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes, Chemical Reviews, vol.111, issue.3, pp.1761-1779, 2011. ,
DOI : 10.1021/cr1003503
Ruthenium pincer complexes: Ligand design and complex synthesis, Coordination Chemistry Reviews, vol.276, issue.86, pp.112-152, 2014. ,
DOI : 10.1016/j.ccr.2014.06.016
N-Heterocyclic ???Pincer??? Dicarbene Complexes of Cobalt(I), Cobalt(II), and Cobalt(III), Organometallics, vol.23, issue.21, pp.4807-4810, 2004. ,
DOI : 10.1021/om049489l
Chiral and C2-symmetrical bis(oxazolinylpyridine)rhodium(III) complexes: effective catalysts for asymmetric hydrosilylation of ketones, Organometallics, vol.8, issue.3, pp.846-848, 1989. ,
DOI : 10.1021/om00105a047
C2 symmetry and asymmetric induction, Chemical Reviews, vol.89, issue.7, pp.1581-1590, 1989. ,
DOI : 10.1021/cr00097a012
Chiral Bis(oxazoline) Copper(II) Complexes:?? Versatile Catalysts for Enantioselective Cycloaddition, Aldol, Michael, and Carbonyl Ene Reactions, Accounts of Chemical Research, vol.33, issue.6, pp.325-335, 2000. ,
DOI : 10.1021/ar960062n
-Symmetric Copper(II) Complexes as Chiral Lewis Acids. Catalytic Enantioselective Aldol Additions of Silylketene Acetals to (Benzyloxy)acetaldehyde, Journal of the American Chemical Society, vol.118, issue.24, pp.5814-5815, 1996. ,
DOI : 10.1021/ja960712i
URL : https://hal.archives-ouvertes.fr/hal-01158298
-Symmetric Copper(II) Complexes as Chiral Lewis Acids. Scope and Mechanism of Catalytic Enantioselective Aldol Additions of Enolsilanes to (Benzyloxy)acetaldehyde, Journal of the American Chemical Society, vol.121, issue.4, pp.669-685, 1999. ,
DOI : 10.1021/ja9829822
URL : https://hal.archives-ouvertes.fr/hal-01158298
Lanthanide Pybox Complexes as Catalysts for Enantioselective Silylcyanation of Aldehydes, Organometallics, vol.24, issue.14, pp.3458-3467, 2005. ,
DOI : 10.1021/om050197+
Relative stability of half-sandwich ??6-benzene Ru(II) complexes of tridentate (2-pyridyl)alkylamine ligands of varying chelate ring-size: Nucleophilic addition of hydride ion onto the benzene ring, Inorganica Chimica Acta, vol.362, issue.2, pp.483-490, 2009. ,
DOI : 10.1016/j.ica.2008.04.043
)][OTf] (OTf = Trifluoromethane Sulfonate), Organometallics, vol.18, issue.6, pp.1097-1105, 1999. ,
DOI : 10.1021/om980878n
Reactivity of a binuclear Ru(II) N2-bridged complex towards phosphines: facile access to novel mono and binuclear phosphorous derivatives. X-ray structural characterization of two unusual binuclear complexes containing ???pincer??? ligands: [{RuCl2(??3-NN???N)}2(??-??2-P2)] (NN???N=2,6-bis[(dimethylamino)methyl]pyridine; P2=1,3-bis[(diphenylphosphino)methyl]benzene or 1,3-bis(diphenylphosphino)propane), Journal of Organometallic Chemistry, vol.583, issue.1-2, pp.69-79, 1999. ,
DOI : 10.1016/S0022-328X(99)00105-9
Reactions of "mixed" ligands with Group VIB metal carbonyls, Inorganic Chemistry, vol.6, issue.10, pp.1929-1931, 1967. ,
DOI : 10.1021/ic50056a042
Facile Double C???H Activation of Tetrahydrofuran by an Iridium PNP Pincer Complex, Organometallics, vol.28, issue.21, pp.6331-6338, 2009. ,
DOI : 10.1021/om9006906
Ruthenium Complexes with Cooperative PNP Ligands: Bifunctional Catalysts for the Dehydrogenation of Ammonia-Borane, Angewandte Chemie International Edition, vol.68, issue.5, pp.905-907, 2009. ,
DOI : 10.1002/anie.200805108
Iminophosphorane???phosphines: Versatile ligands for homogeneous catalysis, Journal of Organometallic Chemistry, vol.751, pp.792-808, 2014. ,
DOI : 10.1016/j.jorganchem.2013.07.009
Early metal bis(phosphorus-stabilised)carbene chemistry, Chemical Society Reviews, vol.3, issue.618, pp.2164-2176, 2011. ,
DOI : 10.1039/c0cs00135j
Syntheses and Structures of Group 14 1,3-Dimetallacyclobutanes, Organometallics, vol.22, issue.22, pp.4604-4609, 2003. ,
DOI : 10.1021/om0340793
Lithium, Magnesium, and Zinc Iminophosphorano(8-quinolyl)methanide Complexes:?? Syntheses, Characterization, and Activity in ??-Caprolactone Polymerization, Organometallics, vol.26, issue.9, pp.2243-2251, 2007. ,
DOI : 10.1021/om0610400
-Chelate Ligands, Organometallics, vol.27, issue.7, pp.1626-1633, 2008. ,
DOI : 10.1021/om701112m
URL : https://hal.archives-ouvertes.fr/in2p3-00025581
Nickel-Catalyzed Cross-Coupling of Non-Activated or Functionalized Aryl Halides with Aryl Grignard Reagents, Chemistry - A European Journal, vol.109, issue.34, pp.10332-10336, 2010. ,
DOI : 10.1002/chem.201001022
N-Heterocyclic Carbene-Based Nickel Complexes: Synthesis and Catalysis in Cross-Couplings of Aryl Chlorides with ArMX (M = Mg or Zn), Organometallics, vol.28, issue.22, pp.6507-6514, 2009. ,
DOI : 10.1021/om9006399
Reversible Orthopalladation of Phosphinimine???Imine Dichloropalladium(II) Complexes, Organometallics, vol.28, issue.13, pp.3889-3895, 2009. ,
DOI : 10.1021/om900194s
Synthesis and characterization of new Pd(II) non-symmetrical Pincer complexes derived from thioether functionalized iminophosphoranes. Evaluation of their catalytic activity in the Suzuki???Miyaura couplings, Journal of Organometallic Chemistry, vol.749, pp.287-295, 2014. ,
DOI : 10.1016/j.jorganchem.2013.09.038
Synthesis and Reactivity of Dialkyl Lutetium Complexes Supported by a Novel Bis(phosphinimine)carbazole Pincer Ligand, Organometallics, vol.28, issue.21, pp.6352-6361, 2009. ,
DOI : 10.1021/om900731x
A Stable Hydrido Amido Ruthenium Complex Bearing a Tridentate Iminophosphorane???Phosphine???Amine Ligand, Organometallics, vol.25, issue.2, pp.315-317, 2006. ,
DOI : 10.1021/om050738v
URL : https://hal.archives-ouvertes.fr/hal-00090555
Nickel(II) Complexes Chelated by 2-Arylimino-6-benzoxazolylpyridine: Syntheses, Characterization, and Ethylene Oligomerization, Organometallics, vol.27, issue.21, pp.5641-5648, 2008. ,
DOI : 10.1021/om800647w
Reaction chemistry of [Pd2(??-OH)2L4]2+ with aryl amines., Inorganica Chimica Acta, vol.345, pp.8-14, 2003. ,
DOI : 10.1016/S0020-1693(02)01278-1
Rare, Hexatomic, Boat-Shaped, Cross-Linked Bis(iminodiphenylphosphorano)methanediide Pincer Carbon Bridged Photoluminescent Copper Clusters Capped with Methyl or Halide Bridges, Organometallics, vol.29, issue.19, pp.4251-4264, 2010. ,
DOI : 10.1021/om1002478
Unexpected behaviour of copper(I) towards a tridentate Schiff base: synthesis, structure and properties of new Cu(I)???Cu(II) and Cu(II) complexes, Inorganica Chimica Acta, vol.324, issue.1-2, pp.300-308, 2001. ,
DOI : 10.1016/S0020-1693(01)00663-6
Cu(I) and Cu(II) complexes of a pyridine-based pincer ligand, Inorganica Chimica Acta, vol.330, issue.1, pp.103-110, 2002. ,
DOI : 10.1016/S0020-1693(01)00825-8
Some applications of the transition state method to the calculation of reaction velocities, especially in solution, Transactions of the Faraday Society, vol.31, pp.875-894, 1935. ,
DOI : 10.1039/tf9353100875
Semiempirical GGA-type density functional constructed with a long-range dispersion correction, Journal of Computational Chemistry, vol.10, issue.15, pp.1787-1799, 2006. ,
DOI : 10.1002/jcc.20495
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy, Physical Chemistry Chemical Physics, vol.110, issue.16, pp.3297-3305, 2005. ,
DOI : 10.1039/b508541a
A DFT Study of the Full Catalytic Cycle of the Suzuki???Miyaura Cross-Coupling on a Model System, Organometallics, vol.25, issue.15, pp.3647-3658, 2006. ,
DOI : 10.1021/om060380i
Inorganic and Bioinorganic Solvent Exchange Mechanisms, Chemical Reviews, vol.105, issue.6, pp.1923-1960, 2005. ,
DOI : 10.1021/cr030726o
Preparation and crystal structure of the unusual double-helical copper(I) complex bis(2,6-bis(1-methylbenzimidazol-2-yl)pyridine)dicopper(I) naphthalene-1,5-disulfonate, Inorganic Chemistry, vol.28, issue.15, pp.2920-2925, 1989. ,
DOI : 10.1021/ic00314a010
Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis, Chemical Reviews, vol.108, issue.8, pp.3054-3131, 2008. ,
DOI : 10.1021/cr8002505
Stereoselective Cyclopropanation Reactions, Chemical Reviews, vol.103, issue.4, pp.977-1050, 2003. ,
DOI : 10.1021/cr010007e
The growing applications of click chemistry, Chem. Soc. Rev., vol.45, issue.8, pp.1249-1262, 2007. ,
DOI : 10.1039/B613014N
Well-defined copper(i) complexes for Click azide???alkyne cycloaddition reactions: one Click beyond, Catalysis Science & Technology, vol.12, issue.2, pp.166-178, 2011. ,
DOI : 10.1039/c0cy00064g
(Iminophosphorane)copper(I) Complexes as Highly Efficient Catalysts for 1,3-Dipolar Cycloaddition of Azides with Terminal and 1-Iodoalkynes in Water: One-Pot Multi-Component Reaction from Alkynes and in situ Generated Azides, European Journal of Inorganic Chemistry, vol.44, issue.35, pp.5854-5863 ,
DOI : 10.1002/ejic.201200789
] for Azide???Alkyne Cycloaddition Reactions under Strict Click Conditions, The Journal of Organic Chemistry, vol.76, issue.7, pp.2367-2373, 2011. ,
DOI : 10.1021/jo200085j
Use of the Redox-Active Ligand 1,1'-Bis(diphenylphosphino)cobaltocene To Reversibly Alter the Rate of the Rhodium(I)-Catalyzed Reduction and Isomerization of Ketones and Alkenes, Journal of the American Chemical Society, vol.117, issue.12, pp.3617-3618, 1995. ,
DOI : 10.1021/ja00117a033
Sequencing Reactions with Samarium(II) Iodide, Chemical Reviews, vol.96, issue.1, pp.307-338, 1996. ,
DOI : 10.1021/cr950019y
Organic Synthesis using Samarium Diiodide, 2009. ,
/HMPA, Journal of the American Chemical Society, vol.122, issue.9, pp.2118-2119, 2000. ,
DOI : 10.1021/ja992951m
Utility of Neodymium Diiodide as a Reductant in Ketone Coupling Reactions, Organic Letters, vol.5, issue.12, pp.2041-2042, 2003. ,
DOI : 10.1021/ol030033u
Dicyclopentadienyleuropium, Angewandte Chemie International Edition in English, vol.3, issue.2, pp.132-133, 1964. ,
DOI : 10.1002/anie.196401322
Samarium(II) dicyclopentadienide 1-tetrahydrofuranate, Journal of the American Chemical Society, vol.91, issue.3, pp.775-776, 1969. ,
DOI : 10.1021/ja01031a061
Solution synthesis and crystallographic characterization of the divalent organosamarium complexes (C5Me5)2Sm(THF)2 and [(C5Me5)Sm(.mu.-I)(THF)2]2, Journal of the American Chemical Society, vol.107, issue.4, pp.941-946, 1985. ,
DOI : 10.1021/ja00290a032
Electron-transfer reactions of divalent ytterbium metallocenes. Synthesis of the series [(Me5C5)2Yb]2[.mu.-E] (E = oxygen, sulfur, selenium, or tellurium) and crystal structure of [(Me5C5)2Yb]2[.mu.-Se], Organometallics, vol.8, issue.8, pp.1865-1870, 1989. ,
DOI : 10.1021/om00110a006
Advances in f element reductive reactivity as a paradigm for expanding lanthanide and actinide science and technology, Journal of Alloys and Compounds, vol.488, issue.2, pp.493-510, 2009. ,
DOI : 10.1016/j.jallcom.2009.02.018
Insertion of two carbon monoxide moieties into an alkene double bond to form a RCH:C(O)C(O):CHR2- unit via organosamarium activation, Journal of the American Chemical Society, vol.110, issue.9, pp.2772-2774, 1988. ,
DOI : 10.1021/ja00217a013
Reduction System, Journal of the American Chemical Society, vol.126, issue.2, pp.454-455, 2004. ,
DOI : 10.1021/ja036923m
Coordination of 2,2???-Bipyridyl and 1,10-Phenanthroline to Substituted Ytterbocenes:?? An Experimental Investigation of Spin Coupling in Lanthanide Complexes, Organometallics, vol.21, issue.3, pp.460-472, 2002. ,
DOI : 10.1021/om010661k
Yb with Heterocyclic Nitrogen Bases:?? Examples of Antiferromagnetic Exchange Coupling across Bridging Ligands, Organometallics, vol.21, issue.22, pp.4622-4631, 2002. ,
DOI : 10.1021/om020477e
Synthesis and x-ray crystal structure of the first tris(pentamethylcyclopentadienyl)metal complex: (.eta.5-C5Me5)3Sm, Journal of the American Chemical Society, vol.113, issue.19, pp.7423-7424, 1991. ,
DOI : 10.1021/ja00019a050
The expansion of divalent organolanthanide reduction chemistry via new molecular divalent complexes and sterically induced reduction reactivity of trivalent complexes, Journal of Organometallic Chemistry, vol.647, issue.1-2, pp.2-11, 2002. ,
DOI : 10.1016/S0022-328X(01)01462-0
Crystal structure of bis(pentamethylcyclopentadienyl)bis(pyridine)ytterbium(II), Inorganic Chemistry, vol.21, issue.7, pp.2647-2649, 1982. ,
DOI : 10.1021/ic00137a023
Influence of Crystal Packing on Molecular Geometry:?? A Crystallographic and Theoretical Investigation of Selected Diorganotin Systems, The Journal of Physical Chemistry A, vol.102, issue.14, pp.2472-2482, 1998. ,
DOI : 10.1021/jp9728722
Crystal packing, hydrogen bonding, and the effect of crystal forces on molecular conformation, Accounts of Chemical Research, vol.13, issue.4, pp.105-112, 1980. ,
DOI : 10.1021/ar50148a002
Complexes of groups 3, 4, the lanthanides and the actinides containing neutral phosphorus donor ligands, Coordination Chemistry Reviews, vol.99, pp.137-212, 1990. ,
DOI : 10.1016/0010-8545(90)80063-Y
Phosphinomethanid-komplexe der lanthanoide, Journal of Organometallic Chemistry, vol.482, issue.1-2, pp.151-167, 1994. ,
DOI : 10.1016/0022-328X(94)88197-9
Synthesis and Structural Characterization of the First Lanthanide(II) Cuboidal Cluster. Unexpected C???O Activation by an Unchanged Ytterbium(II) Center, Organometallics, vol.19, issue.11, pp.2090-2096, 2000. ,
DOI : 10.1021/om000057u
Synthesis and Molecular Structure of Bis(pentamethylcyclopentadienyl) Phospholyl- and Arsolylsamarium(III) Complexes: Influence of Steric and Electronic Factors, Organometallics, vol.20, issue.18, pp.3884-3890, 2001. ,
DOI : 10.1021/om010317n
]: Aspecific and Syndiospecific Styrene Polymerization, Chemistry - A European Journal, vol.41, issue.4, pp.846-850, 2009. ,
DOI : 10.1002/chem.200802220
Single and Double Alkyl Abstraction from a Bis(anilido)xanthene Thorium(IV) Dibenzyl Complex: Isolation of an Organothorium Cation and a Thorium Dication, Organometallics, vol.27, issue.1, pp.15-17, 2008. ,
DOI : 10.1021/om7011503
Ligand Exchange and Alkyl Abstraction Involving (Perfluoroaryl)boranes and -alanes with Aluminum and Gallium Alkyls, Organometallics, vol.19, issue.23, pp.4684-4686, 2000. ,
DOI : 10.1021/om000573k
Generation of Cationic[Zr-{tert-Butyl Enolate}] Reactive Species: Methyl Abstraction versus Hydride Abstraction, Chemistry - A European Journal, vol.10, issue.17, pp.4301-4307, 2004. ,
DOI : 10.1002/chem.200400473
Phosphinimido Complexes of Silicon, Tin, and Germanium, Organometallics, vol.22, issue.4, pp.818-825, 2003. ,
DOI : 10.1021/om020666x
N), Organometallics, vol.16, issue.18, pp.3941-3949, 1997. ,
DOI : 10.1021/om970207+
URL : https://hal.archives-ouvertes.fr/hal-01511248
Synthesis and Coordination Chemistry of a Novel Phosphinimine Phosphine, Organometallics, vol.14, issue.4, pp.1983-1991, 1995. ,
DOI : 10.1021/om00004a060
Synthesis of Cyclic Diamino-Substituted Metal Carbene Complexes, Organometallics, vol.15, issue.3, pp.1055-1061, 1996. ,
DOI : 10.1021/om950735q
Cycloruthenated Complexes from Iminophosphoranes: Synthesis, Structure, and Reactivity with Internal Alkynes, Organometallics, vol.30, issue.3, pp.642-648, 2011. ,
DOI : 10.1021/om100997x
Synthèse et chimie de coordination de ligands mixtes iminophosphorane-phosphine (30), Chapitre Réau, R. New J. Chem, vol.4, issue.5, pp.26-630, 2002. ,
Contributions to Organo-Nickel Chemistry, Angewandte Chemie International Edition in English, vol.27, issue.1, pp.185-206, 1988. ,
DOI : 10.1002/anie.198801851
Isolation of a Chromium Hydride Single-Component Ethylene Polymerization Catalyst, Organometallics, vol.27, issue.22, pp.5943-5947, 2008. ,
DOI : 10.1021/om800773k
Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis, Chemical Reviews, vol.108, issue.8, pp.3054-3131, 2008. ,
DOI : 10.1021/cr8002505
A Meta-Selective Copper-Catalyzed C-H Bond Arylation, Science, vol.323, issue.5921, pp.1593-1597, 2009. ,
DOI : 10.1126/science.1169975
Synthesis, Structure, and Bonding of Stable Complexes of Pentavalent Uranyl, Journal of the American Chemical Society, vol.132, issue.2, pp.495-508, 2010. ,
DOI : 10.1021/ja9037164
URL : https://hal.archives-ouvertes.fr/hal-00523038
Actinide-based single-molecule magnets, Dalton Trans., vol.28, issue.6, pp.2517-2528 ,
DOI : 10.1039/C4DT02391A
Uranyl-Lanthanide Heterometallic Complexes with Cucurbit[6]uril and Perrhenate Ligands, Inorganic Chemistry, vol.48, issue.3, pp.825-827, 2009. ,
DOI : 10.1021/ic802270n
Single-Electron Uranyl Reduction by a Rare-Earth Cation, Angewandte Chemie International Edition, vol.131, issue.4, pp.887-890, 2011. ,
DOI : 10.1002/anie.201005511
Helicene-like chiral auxiliaries in asymmetric catalysis, Dalton Trans., vol.353, issue.41, pp.15263-15278 ,
DOI : 10.1002/chem.201402822
URL : https://hal.archives-ouvertes.fr/hal-01077165
6 (s, N=P), ?3.4 (s, PEt 3, ?144.8 (h, 1 J PF = 710 Hz ,
Calcd for C 49 H 52 CuF 6 N 3 P 4 : C, 59.79; H, 5.32; N, 4.27. Found: C, 59.65; H, 5.32, ? Compound [L Ph CuBr 2 ] Formula: C 43 H 37 Br 2 CuN 3 P 2 Molecular weight, pp.881-889 ,
6 (d, 1 J PC = 61 ,
5 mg, 86 µmol) and YbI 2 (86 µmol, 18.3 mg) were stirred in THF (2 mL) for 15 minutes, then Et 2 O (5 mL) was added to enhance the precipitation. The mixture was then centrifuged. The supernatant was removed and Et 2 O (5 mL) was added, the mixture was stirred for 5 minutes and centrifuged again, the supernatant was removed and the solid was dried under vacuum overnight to yield [L Me 2 Yb]I 2 (46.2 mg, 94 %) as a green powder, pp.31-32 ,
Calcd for C 26 H 50 I 2 N 6 P 4 Yb: C, 31.31; H, 5.05; N, 8.43. Found: C, 31.41; H, 5.18, ? Compound [L Me 2 Sm]I 2 ,
59 µmol) yielding [L Me 2 Sm]I 2 as a yellowish powder (53.1 mg, 92 %) ,
5 mg, 0.18 mmol) and [UI 3 (THF) 4 ] (162 mg, 0.18 mmol) were stirred in THF (10 mL) for 5 hours. The solvent was then removed under vacuum Then toluene (2 mL) and pentane (5 mL) were added to form a deep blue precipitate. The mixture was filtered and washed pentane (2x3 mL) and toluene (1 mL). The solid was dried under vacuum for 3 hours to yield [L Ph UI 3 ] (96.0 mg, 74 %) as a blue powder, pp.31-32 ,
8 mg, 80 µmol) and [UI 3 (THF) 4 ] (73 mg, 80 µmol) were stirred in a mixture of Et 2 O and THF (5 mL/1 mL) overnight, resulting in the formation of a blue precipitate. The solid was filtered, washed with Et 2 O (2x3 mL) and finally dried under vacuum for 3 hours to yield ,
Calcd for C 43 H 75 I 3 N 3 P 2 U: C, 39.34; H, 5.61; N, 3.20, pp.812-97 ,
127 mg, 0.18 mmol) and [Yb(tmp) 2 (THF)] (96 mg, 0.18 mmol) were stirred in Et 2 O (2 mL) for 3 h leading to the formation of a green precipitate, pentane (10 mL) was added to enhance the precipitation and the mixture was centrifuged and stored at -40°C overnight. The liquid was removed and the operation repeated another time with 10 mL of pentane. Finally the dark green solid was dried under high vacuum for 2 h to yield ,
5 (s, C 8 ) ,
Calcd for C 59 H 97 N 3 P 4 Yb: C, 61.87; H, 8.54; N, 3.67. Found: C, 61.63; H, 8.62, ? Compound [L Me 2 Yb](tmp ,
1 mg, 0.20 mmol) and [Yb(tmp) 2 (THF)] (51.6 mg, 0.10 mmol) were stirred in toluene (2 mL) for 1 hour, then Et 2 O (2 mL) was added and the mixture was triturated with a spatula to form a green precipitate. The mixture was then centrifuged. The supernatant was removed and a mixture of Et 2 O and pentane (2 mL/2 mL) was added, the mixture was stirred for 5 minutes and centrifuged again, the supernatant was removed and the solid was dried under vacuum overnight to yield) as a green powder, pp.31-32 ,
mg, 1.99 mmol) was dissolved in diethyl ether (15 mL) PPh 3 (522 mg, 1.99 mmol) was added as a solid After few seconds, a nitrogen evolution was potent, the mixture was stirred for 5 h at room temperature. The solvent was evaporated under reduced pressure; the resulting yellow oil was washed with petroleum ether to yield 3 as a yellow viscous oil ,
The red mixture of the anion was stirred for 5 min at -78°C and then at 0°C for 15 min Both Schlenk flasks were cooled to 0°C and the mixture of the anion was added via cannula to the other flask in about 20 min (ca. 1 drop/second). The mixture was then stirred at 0°C for 1h. Solvents were then evaporated to give an off-white solid which was then suspended in pentane ,
After filtration and washing with pentane (5 mL), an off-white solid was obtained (1.03 g, 90 %) ,
12; N, 6.34. Found: C, 65.33; H, 10.22; N, 5.25. filtered and Et 2 O (20 mL) was added leading to the precipitation of a yellowish solid. The precipitate was filtered and washed with Et 2 O (10 mL) After drying under vacuum, Pd(py)](BF 4 ) 2 (72.1 mg, 60%) was isolated ,
6 (d, 1 J PC = 42 (s, C ? ), pp.122-127 ,
85 (s, C 6 ) ,
25 (d, 3 J HH = 6.6 Hz, 1H ,
30 mg, 44 µmol) and B(C 6 F 5 ) 3 (22.4 mg, 44 µmol) were suspended in toluene (3 mL) After 3 hours of stirring the mixture turned clear and was checked in 31 P{ 1 H} probing the disappearance of the starting material and the formation of a new product characterized by a doublet of doublet at 47.1 ppm (J = 23.0, 7.5 Hz) and a doublet at 31.1 ppm (J = 7.5 Hz). The mixture was then transferred to a Schlenk flask and the volatiles were removed under vacuum. The solid was then suspended in pentane (3 mL, filtered, then the solid was washed with Et 2 O (1 mL) and pentane (2x3 mL) to give an off-white solid which was dried under high vacuum to furnish [L 1B PdMe] (39 ,
1 (dd, J = 22 ,
73 (d, 3 J HH = 7.3 Hz, 1H, pp.29-35 ,
Tol-d 8 ) ? 54.0-52.8 (m, N=PCy 3 and PPh 2 ) ,
34 (m Even at low temperature, signals remained very broaden and do not allow the accurate determination of the coupling constants, pp.35-35 ,
KHMDS (8 mg, 40 µmol) and [L 1 RuCl 2 (PPh 3 )] (20 mg, 40 µmol) were mixed in THFd 8 (0.75 mL) and stirred for 5 minutes. The solution was filtered and transferred to a J-Young NMR tube for spectroscopic analysis ,
23 (d, 3 J HH = 6.4 Hz, 1H, ABX system (3.95 J HH = 14.9 Hz, 3 J PH = -5.9 Hz, 1H, pp.70-71 ,
40 (bd, 3 J HH = 7.6 Hz, p.35 ,
12 (d, 3 J HH = 7.2 Hz, 1H ,
69 (ABX system, dd, 2 J HH = 15.3 Hz, 3 J PH = 11.6 Hz, 1H, H 6b )), AMX system2, p.69 ,
At least 20 others signals in the aromatic region can be detected but not assigned, J PC ca, vol.127, issue.478 6, pp.1403-97 ,
8 mg, 78.5 µmol) and KHMDS (31.4 mg, 157 µmol) were stirred in benzene (3 mL) for 20 minutes resulting in a brown solution. A suspension of [UI 4 (dioxane) 2 ] (72.4 mg, 78.5 µmol) in benzene (5 mL) was added resulting in a color change to brown. The mixture was stirred for 2 hours at room temperature. The mixture was filtered over a pad of celite which was washed with toluene (3 mL). The volatiles were evaporated and the resulting yellow powder was suspended in pentane (5 mL) After filtration, the powder was washed with pentane, mL) and dried under vacuum for 2 hours to yield [L Salen UI 2 ] (103 mg, 93 %) ,
1 mg, 0.025 mmol) and KHMDS (102 mg, 0.51 mmol) were stirred in THF (12 mL) for 2 hours resulting in a brown solution. A suspension of [UO 2 Cl 2 (THF) 2 ] (123.7 mg, 0.25 mmol) in THF (4 mL) was added resulting in a color change to red. The mixture was stirred for 2 hours at room temperature. The mixture was filtered over a pad of celite and dried under vacuum. The red/orange powder was suspended in pentane (15 mL) After filtration, the solid was washed with pentane (10 mL) and finally extracted with DCM (10 mL) ,
0 (s, 1 J PC = 126.6 Hz, pp.31-39 ,
Found: C, 60.41; H, 5.71; N, 3.41, Inorganic Syntheses, pp.108-111, 1992. ,
Ionization of YCl3 in Tetrahydrofuran. Crystal Structures of the [trans-YCl2(THF)5][trans-YCl4(THF)2] Salt and Polymeric [YCl3.cntdot.2THF].infin. Compounds, Inorganic Chemistry, vol.33, issue.23, pp.5203-5206, 1994. ,
DOI : 10.1021/ic00101a011
In Inorganic Syntheses, pp.90-92, 1990. ,
Organometallic Syntheses, 2013. ,
Formation of aryl???nitrogen bonds using a soluble copper(I) catalyst, Tetrahedron Letters, vol.42, issue.29, pp.4791-4793, 2001. ,
DOI : 10.1016/S0040-4039(01)00888-7
In Inorganic Syntheses, pp.237-240, 1970. ,
:?? A Simple Preparation of an Anhydrous Uranyl Reagent, Inorganic Chemistry, vol.38, issue.18, pp.4156-4158, 1999. ,
DOI : 10.1021/ic990159g
97: a new tool for crystal structure determination and refinement, Journal of Applied Crystallography, vol.32, issue.1, pp.115-119, 1999. ,
DOI : 10.1107/S0021889898007717
??? a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions, Journal of Applied Crystallography, vol.40, issue.4, pp.786-790, 2007. ,
DOI : 10.1107/S0021889807029238
-III with a Graphical User Interface (GUI), Journal of Applied Crystallography, vol.30, issue.5, pp.565-565, 1997. ,
DOI : 10.1107/S0021889897003117
URL : https://hal.archives-ouvertes.fr/hal-00655769
Gaussian 09, 2009. ,
A DFT Study of the Full Catalytic Cycle of the Suzuki???Miyaura Cross-Coupling on a Model System, Organometallics, vol.25, issue.15, pp.3647-3658, 2006. ,
DOI : 10.1021/om060380i