E. A. Tomic, Thermal stability of coordination polymers, Journal of Applied Polymer Science, vol.9, issue.11, pp.3745-3752, 1965.
DOI : 10.1002/app.1965.070091121

O. M. Yaghi, G. Li, and H. Li, Selective binding and removal of guests in a microporous metal???organic framework, Nature, vol.113, issue.6558, pp.378-703, 1995.
DOI : 10.1038/378703a0

H. Li, M. Eddaoudi, M. O-'keeffe, and O. M. Yaghi, Design and synthesis of an exceptionally stable and highly porous metal-organic framework, Nature, pp.402-276, 1999.

M. Cavellec, D. Riou, J. Grenè-che, and G. Fé-rey, Hydrothermal Synthesis, Structure, and Magnetic Properties of a Novel Monodimensional Iron Phosphate: [FeF(HPO 4 ) 2, Inorg. Chem, issue.2, pp.20-34, 1997.

G. Fé-rey, Hybrid porous solids: past, present, future, Chem. Soc. Rev., vol.294, issue.123, pp.191-214, 2008.
DOI : 10.1126/science.1062126

C. Serre, F. Taulelle, and G. , Fé rey, Rational design of porous titanophosphates, Chem. Commun, pp.2755-2765, 2003.

M. I. Khan, L. M. Meyer, R. C. Haushalter, A. L. Schweitzer, J. Zubieta et al., O, Chemistry of Materials, vol.8, issue.1, pp.43-53, 1996.
DOI : 10.1021/cm950249t

URL : https://hal.archives-ouvertes.fr/in2p3-01342270

J. Chen, S. Natarajan, J. M. Thomas, R. H. Jones, and M. B. Hursthouse, A Novel Open-Framework Cobalt Phosphate Containing a Tetrahedrally Coordinated Cobalt(II) Center: CoPO4?? 0.5 C2H10N2, Angewandte Chemie International Edition in English, vol.33, issue.6, pp.33-639, 1994.
DOI : 10.1002/anie.199406391

S. Kitagawa, R. Kitaura, and S. , Noro, Functional Porous Coordination Polymers
DOI : 10.1002/chin.200429230

G. Fé-rey, Microporous Solids:?? From Organically Templated Inorganic Skeletons to Hybrid Frameworks...Ecumenism in Chemistry, Ecumenism in Chemistry, pp.3084-3098, 2001.
DOI : 10.1021/cm011070n

A. R. Millward and O. M. Yaghi, Metal???Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature, Journal of the American Chemical Society, vol.127, issue.51, pp.17998-17999, 2005.
DOI : 10.1021/ja0570032

C. N. Rao, S. Natarajan, and R. Vaidhyanathan, Metal Carboxylates with Open Architectures, Angewandte Chemie International Edition, vol.43, issue.12, pp.1466-1496, 2004.
DOI : 10.1002/anie.200300588

G. Fé-rey, Building Units Design and Scale Chemistry, Journal of Solid State Chemistry, vol.152, issue.1, pp.37-48, 2000.
DOI : 10.1006/jssc.2000.8667

N. Stock and S. Biswas, Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites, Chemical Reviews, vol.112, issue.2, pp.933-969, 2012.
DOI : 10.1021/cr200304e

C. Gerardin, M. In, L. Allouche, M. Haouas, and F. Taulelle, In Situ pH Probing of Hydrothermal Solutions by NMR, Situ pH Probing of Hydrothermal Solutions by NMR, pp.1285-1292, 1999.
DOI : 10.1021/cm980766m

D. Riou and G. , Fé rey, Hybrid open frameworks (MIL-n) Part 3 Crystal structures of the HT and LT forms of MIL-7: a new vanadium propylenediphosphonate with an open-framework. Influence of the synthesis temperature on the oxidation state of vanadium within the same structural type, J

C. Livage, C. Egger, M. Nogues, and G. , Fé rey, Hybrid open frameworks (MIL-n) Part 5

S. Bauer, T. Bein, and N. Stock, High-Throughput Investigation and Characterization of Cobalt Carboxy Phosphonates, Inorganic Chemistry, vol.44, issue.16, pp.5882-5889, 2005.
DOI : 10.1021/ic0505089

S. Surblé, C. Serre, C. Mellot-draznieks, F. Millange, and G. , Fé rey, A new isoreticular class of metal-organic-frameworks with the MIL-88 topology, Chem. Commun, pp.284-286, 2006.

C. Serre, F. Millange, S. Surblé, and G. , Fé rey, A Route to the Synthesis of Trivalent Transition-Metal Porous Carboxylates with Trimeric Secondary Building Units, Angew. Chem. Int

E. Biemmi, T. Bein, and N. Stock, Synthesis and characterization of a new metal organic framework structure with a 2D porous system: (H2NEt2)2[Zn3(BDC)4]???3DEF, Solid State Sciences, vol.8, issue.3-4, pp.363-370, 2006.
DOI : 10.1016/j.solidstatesciences.2006.02.025

U. Mueller, M. Schubert, F. Teich, H. Puetter, K. Schierle-arndt et al., Metal-organic frameworks-prospective industrial applications, J. Mater. Chem, pp.16-626, 2006.
DOI : 10.1002/chin.200623294

S. Park, Microwave Fabrication of MFI Zeolite Crystals with a Fibrous Morphology and Their Applications, Angew. Chem. Int. Ed, vol.44, pp.556-560, 2005.

S. H. Jhung, T. Jin, Y. K. Hwang, and J. Chang, Microwave Effect in the Fast Synthesis of Microporous Materials: Which Stage Between Nucleation and Crystal Growth is Accelerated by Microwave Irradiation?, Chemistry - A European Journal, vol.16, issue.16, pp.13-4410, 2007.
DOI : 10.1023/B:CATS.0000026990.25778.a8

A. Demessence, P. Horcajada, C. Serre, C. Boissiè-re, D. Grosso et al., Fé rey, Elaboration and properties of hierarchically structured optical thin films of MIL-101(Cr), Chem. Commun, pp.7149-7151, 2009.

P. M. Forster, N. Stock, and A. K. Cheetham, A High-Throughput Investigation of the Role of pH, Temperature, Concentration, and Time on the Synthesis of Hybrid Inorganic-Organic Materials, Angewandte Chemie International Edition, vol.443, issue.46, pp.44-7608, 2005.
DOI : 10.1002/anie.200501766

S. Bauer and N. Stock, Implementation of a Temperature-Gradient Reactor System for High-Throughput Investigation of Phosphonate-Based Inorganic?Organic Hybrid Compounds, Angew. Chem. Int. Ed, pp.46-6857, 2007.

R. Banerjee, A. Phan, B. Wang, C. Knobler, H. Furukawa et al., High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO 2 Capture, Science, pp.319-939, 2008.

. Stock, OH) 2 (OCH 3 ) 4 (H 2 N-bdc) 3 ]?x H 2 O:A12-Connected Porous Metal?Organic Framework with an Unprecedented Aluminum-Containing Brick, Angew. Chem. Int. Ed, issue.4, pp.48-5163, 2009.

A. Long, J. R. Dailly, and . Long, Hydrogen storage and carbon dioxide capture in an iron-based sodalite-type metal-organic framework (Fe-BTT) discovered via high-throughput methods

H. Reinsch and N. Stock, High-throughput studies of highly porous Al-based MOFs, Microporous and Mesoporous Materials, vol.171
DOI : 10.1016/j.micromeso.2012.12.024

O. K. Farha, A. Özgür-yazayd?n, I. Eryazici, C. D. Malliakas, B. G. Hauser et al., De novo synthesis of a metal???organic framework material featuring ultrahigh surface area and gas storage capacities, Nature Chemistry, vol.17, issue.11, pp.944-948, 2010.
DOI : 10.1021/ja0570032

D. C. Cantu, B. P. Mcgrail, and V. Glezakou, Formation Mechanism of the Secondary Building Unit in a Chromium Terephthalate Metal???Organic Framework, Chemistry of Materials, vol.26, issue.22, pp.26-6401, 2014.
DOI : 10.1021/cm5027859

S. Surblé, F. Millange, C. Serre, G. Serre, R. I. Fé-rey et al., An EXAFS study of the formation of a nanoporous metal???organic framework: evidence for the retention of secondary building units during synthesis, Chemical Communications, vol.6, issue.14, pp.14-1518, 2006.
DOI : 10.1039/b600709k

J. A. Rood, W. C. Boggess, B. C. Noll, and K. W. Henderson, Assembly of a Homochiral, Body-Centered Cubic Network Composed of Vertex-Shared Mg12 Cages: Use of Electrospray Ionization Mass Spectrometry to Monitor Metal Carboxylate Nucleation, J. Am. Chem. Soc, pp.129-13675, 2007.

E. Haque, J. H. Jeong, and S. H. Jhung, Synthesis of isostructural porous metal-benzenedicarboxylates: Effect of metal ions on the kinetics of synthesis, CrystEngComm, vol.9, issue.10, pp.2749-2754, 2010.
DOI : 10.1021/cg901562d

N. A. Khan, M. M. Haque, and S. H. Jhung, Accelerated Syntheses of Porous Isostructural

?. Lanthanide and . Benzenetricarboxylates, Ln?BTC) Under Ultrasound at Room Temperature, Eur. J

S. R. Venna, J. B. Jasinski, and M. A. Carreon, Structural Evolution of Zeolitic Imidazolate Framework-8, Journal of the American Chemical Society, vol.132, issue.51, pp.18030-18033, 2010.
DOI : 10.1021/ja109268m

F. Millange, M. I. Medina, N. Guillou, G. Fé-rey, K. M. Golden et al., Time-Resolved In Situ Diffraction Study of the Solvothermal Crystallization of Some Prototypical Metal?Organic Frameworks, Angew. Chem. Int. Ed, pp.49-763, 2010.

J. Petukhov, F. Gascon, and . Kapteijn, Kinetic Control of Metal?Organic Framework Crystallization Investigated by Time-Resolved In Situ X-Ray Scattering, Angew. Chem. Int. Ed, pp.50-9624, 2011.

. Kapteijn, Live encapsulation of a Keggin polyanion in NH 2 -MIL-101 (Al) observed by in situ time resolved X-ray scattering, Chem. Commun, pp.47-8578, 2011.

A. C. Sudik, A. P. Côté, and O. M. Yaghi, Metal-Organic Frameworks Based on Trigonal Prismatic Building Blocks and the New ???acs??? Topology, Inorganic Chemistry, vol.44, issue.9, pp.44-2998, 2005.
DOI : 10.1021/ic050064g

B. Li, H. Wen, W. Zhou, and B. Chen, Porous Metal???Organic Frameworks for Gas Storage and Separation: What, How, and Why?, The Journal of Physical Chemistry Letters, vol.5, issue.20, pp.3468-3479, 2014.
DOI : 10.1021/jz501586e

P. N. Spanopoulos, A. Trikalitis, M. Emwas, and . Eddaoudi, MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum-Based soc-MOF for CH 4

P. Fé-rey, R. Couvreur, and . Gref, Porous metal-organic-framework nanoscale carriers as a potential platform for drug delivery and imaging, Nat Mater, vol.9, pp.172-178, 2010.

S. Keskin and S. , Biomedical Applications of Metal Organic Frameworks, Industrial & Engineering Chemistry Research, vol.50, issue.4
DOI : 10.1021/ie101312k

M. Wu and Y. Yang, Metal-Organic??Framework (MOF)-Based Drug/Cargo Delivery and Cancer Therapy, Advanced Materials, vol.2, issue.23, p.1606134, 2017.
DOI : 10.1039/C3TB20832J

J. Li, R. J. Kuppler, and H. Zhou, Selective gas adsorption and separation in metal???organic frameworks, Chemical Society Reviews, vol.328, issue.5, pp.38-1477, 2009.
DOI : 10.1007/978-94-017-0245-4_2

Z. Wang, A. Knebel, S. Grosjean, D. Wagner, S. Brä-se et al., Tunable molecular separation by nanoporous membranes, Nature Communications, vol.134, p.13872, 2016.
DOI : 10.1021/ja310323y

URL : http://www.nature.com/articles/ncomms13872.pdf

A. Dhakshinamoorthy and H. Garcia, Metal???organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles, Chem. Soc. Rev., vol.64, issue.16, pp.5750-5765, 2014.
DOI : 10.1016/j.dyepig.2004.03.010

J. Liu, L. Chen, H. Cui, J. Zhang, L. Zhang et al., Applications of metal???organic frameworks in heterogeneous supramolecular catalysis, Chem. Soc. Rev., vol.19, issue.16, pp.43-6011, 2014.
DOI : 10.1002/adfm.200801130

L. E. Kreno, K. Leong, O. K. Farha, M. Allendorf, R. P. Van-duyne et al., Metal???Organic Framework Materials as Chemical Sensors, Metal?Organic Framework Materials as Chemical Sensors, pp.1105-1125, 2012.
DOI : 10.1021/cr200324t

D. Tanaka, A. Henke, K. Albrecht, M. Moeller, K. Nakagawa et al., Rapid preparation of flexible porous coordination polymer nanocrystals with accelerated guest adsorption kinetics, Nature Chemistry, vol.19, issue.130, pp.410-416, 2010.
DOI : 10.1038/nchem.627

C. Serre, C. Mellot-draznieks, S. Surblé, N. Audebrand, Y. Filinchuk et al., Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks, Science, vol.127, issue.46, pp.315-1828, 2007.
DOI : 10.1021/ja054900x

F. Loiseau and G. Fajula, Fé rey, Hydrocarbon Adsorption in the Flexible Metal Organic Frameworks MIL, J. Am. Chem. Soc, vol.130, pp.53-16926, 2008.

A. Schneemann, V. Bon, I. Schwedler, I. Senkovska, S. Kaskel et al., Flexible metal???organic frameworks, Chem. Soc. Rev., vol.18, issue.259, pp.43-6062, 2014.
DOI : 10.1002/chem.201200046

S. S. Nagarkar, A. V. Desai, and S. K. Ghosh, Stimulus-Responsive Metal-Organic Frameworks, Chemistry - An Asian Journal, vol.131, issue.9, pp.2358-2376, 2014.
DOI : 10.1021/ja808210z

L. Sarkisov, R. L. Martin, M. Haranczyk, and B. Smit, On the Flexibility of Metal???Organic Frameworks, Journal of the American Chemical Society, vol.136, issue.6, pp.2228-2231, 2014.
DOI : 10.1021/ja411673b

F. Millange, N. Guillou, R. I. Walton, J. Greneche, I. Margiolaki et al., Fé rey, Effect of the nature of the metal on the breathing steps in MOFs with dynamic frameworks, Chem. Commun, pp.4732-4734, 2008.

F. Millange, C. Serre, and G. , Fé rey, Synthesis, structure determination and properties of MIL-53as and MIL-53ht: the first Cr 3+ hybrid inorganic-organic microporous solids

T. Fairen-jimenez, S. E. Duren, P. A. Ashbrook, and . Wright, A novel structural form of, p.53

C. Volkringer, T. Loiseau, N. Guillou, G. Fé-rey, and E. , Elkaï m, A. Vimont, XRD and IR structural investigations of a particular breathing effect in the MOF-type gallium terephthalate, p.53

E. V. Anokhina, M. Vougo-zanda, X. Wang, and A. J. Jacobson, (BDC = Benzenedicarboxylate), a Hybrid Inorganic???Organic Vernier Structure, OH)BDC· 0.75BDCH 2 (BDC = Benzenedicarboxylate), a Hybrid Inorganic?Organic Vernier Structure, pp.15000-15001, 2005.
DOI : 10.1021/ja055757a

O. Shekhah, J. Liu, R. A. Fischer, and C. Woll, MOF thin films: existing and future applications, Chemical Society Reviews, vol.64, issue.5405, pp.40-1081, 2011.
DOI : 10.1016/j.tet.2008.06.036

A. Bé-tard and R. A. Fischer, Metal???Organic Framework Thin Films: From Fundamentals to Applications., Chemical Reviews, vol.112, issue.2, pp.1055-1083, 2012.
DOI : 10.1021/cr200167v

J. Zhuang, A. Terfort, and C. , Formation of oriented and patterned films of metal???organic frameworks by liquid phase epitaxy: A review, Coordination Chemistry Reviews, vol.307, pp.307-391, 2016.
DOI : 10.1016/j.ccr.2015.09.013

S. Hermes, F. Schröder, R. Chelmowski, C. Wöll, and R. A. Fischer, -Terminated Self-Assembled Monolayers on Au(111), Journal of the American Chemical Society, vol.127, issue.40, pp.13744-13745, 2005.
DOI : 10.1021/ja053523l

E. Biemmi, C. Scherb, and T. Bein, O Tunable with Functionalized Self-Assembled Monolayers, Journal of the American Chemical Society, vol.129, issue.26
DOI : 10.1021/ja0701208

C. Carbonell, I. Imaz, and D. Maspoch, Single-Crystal Metal???Organic Framework Arrays, Journal of the American Chemical Society, vol.133, issue.7
DOI : 10.1021/ja2002428

D. Evers, R. A. Zacher, and C. Fischer, Step-by-Step Route for the Synthesis of Metal?Organic Frameworks, J. Am. Chem. Soc, vol.129, pp.15118-15119, 2007.

M. Kubo, W. Chaikittisilp, and T. Okubo, Oriented Films of Porous Coordination Polymer Prepared by Repeated in Situ Crystallization, Chemistry of Materials, vol.20, issue.9, pp.2887-2889, 2008.
DOI : 10.1021/cm800371b

H. Guo, Y. Zhu, S. Qiu, J. A. Lercher, and H. Zhang, Coordination Modulation Induced Synthesis of Nanoscale Eu 1-x Tb x Metal-Organic Frameworks for Luminescent Thin Films, Adv. Mater, pp.22-4190, 2010.

R. Ameloot, L. Stappers, J. Fransaer, L. Alaerts, B. F. Sels et al., Patterned Growth of Metal-Organic Framework Coatings by Electrochemical Synthesis, Chemistry of Materials, vol.21, issue.13, pp.2580-2582, 2009.
DOI : 10.1021/cm900069f

R. Ameloot, L. Pandey, M. V. Auweraer, L. Alaerts, B. F. Sels et al., Patterned film growth of metal???organic frameworks based on galvanic displacement, Chemical Communications, vol.19, issue.21, pp.46-3735, 2010.
DOI : 10.1002/adma.200903867

M. Li and M. Dinc?, Reductive Electrosynthesis of Crystalline Metal???Organic Frameworks, Journal of the American Chemical Society, vol.133, issue.33
DOI : 10.1021/ja2041546

M. Li and M. Dinc?, On the Mechanism of MOF-5 Formation under Cathodic Bias, Chemistry of Materials, vol.27, issue.9
DOI : 10.1021/acs.chemmater.5b00899

D. Falcaro, R. De-vos, and . Ameloot, Electrochemical Film Deposition of the Zirconium Metal?Organic Framework UiO-66 and Application in a Miniaturized Sorbent Trap, Chem. Mater, pp.27-1801, 2015.

P. Vos, R. Vereecken, and . Ameloot, Chemical vapour deposition of zeolitic imidazolate framework thin films, Nat Mater, vol.15, pp.304-310, 2016.

M. D. Allendorf and V. Stavila, From conventional to conformal, Nature Materials, vol.112, issue.3, pp.255-257, 2016.
DOI : 10.1021/ar5000314

D. Zacher, A. Baunemann, S. Hermes, and R. A. Fischer, Deposition of microcrystalline [Cu 3 (btc) 2 ] and [Zn 2 (bdc) 2 (dabco)] at alumina and silica surfaces modified with patterned self assembled organic monolayers: evidence of surface selective and oriented growth, J. Mater. Chem, p.27

C. Scherb, A. Schödel, and T. Bein, Directing the Structure of Metal?Organic Frameworks by Oriented Surface Growth on an Organic Monolayer, Angew. Chem. Int. Ed, pp.47-5777, 2008.

A. Schoedel, C. Scherb, and T. Bein, Oriented Nanoscale Films of Metal?Organic Frameworks By Room-Temperature Gel-Layer Synthesis, Angew. Chem. Int. Ed, pp.49-7225, 2010.

P. Horcajada, C. Serre, D. Grosso, C. Boissiè-re, S. Perruchas et al., Colloidal Route for Preparing Optical Thin Films of Nanoporous Metal-Organic Frameworks, Advanced Materials, vol.21, issue.19, pp.1931-1935, 2009.
DOI : 10.1002/adma.200801851

URL : https://hal.archives-ouvertes.fr/hal-00411435

C. Soler-illia and . Sanchez, Adsorption properties in high optical quality nanoZIF-8 thin films with tunable thickness, J. Mater. Chem, vol.20, pp.7676-7681, 2010.

Y. Yoo and H. Jeong, Heteroepitaxial Growth of Isoreticular Metal???Organic Frameworks and Their Hybrid Films, Crystal Growth & Design, vol.10, issue.3, pp.1283-1288, 2010.
DOI : 10.1021/cg9013027

X. Zou, G. Zhu, F. Zhang, M. Guo, and S. Qiu, Facile fabrication of metal???organic framework films promoted by colloidal seeds on various substrates, CrystEngComm, vol.130, issue.2, pp.352-354, 2010.
DOI : 10.1021/ja8039794

Y. Hu, X. Dong, J. Nan, W. Jin, X. Ren et al., Metal???organic framework membranes fabricated via reactive seeding, Chem. Commun., vol.127, issue.2, pp.47-737, 2011.
DOI : 10.1021/ja054668v

G. Hill, P. Brusatin, and . Falcaro, ZnO as an Efficient Nucleating Agent for Rapid, Room Temperature Synthesis and Patterning of Zn-Based Metal?Organic Frameworks, Chem. Mater, pp.27-690, 2015.

D. Gimona, H. J. Gomez, R. Whitfield, A. Riccò, B. Patelli et al., A new method to position and functionalize metal-organic framework crystals, Nat. Commun, vol.2, issue.237, 2011.

J. Gascon, S. Aguado, and F. Kapteijn, Manufacture of dense coatings of Cu3(BTC)2 (HKUST-1) on ??-alumina, Microporous and Mesoporous Materials, vol.113, issue.1-3, pp.132-138, 2008.
DOI : 10.1016/j.micromeso.2007.11.014

U. Mueller, M. Schubert, F. Teich, H. Puetter, K. Schierle-arndt et al., Metal-organic frameworks-prospective industrial applications, J. Mater. Chem, pp.16-626, 2006.
DOI : 10.1002/chin.200623294

G. Decher, Fuzzy Nanoassemblies: Toward Layered Polymeric Multicomposites, Science, vol.277, issue.5330, pp.277-1232, 1997.
DOI : 10.1126/science.277.5330.1232

O. Shekhah, Layer-by-Layer Method for the Synthesis and Growth of Surface Mounted Metal-Organic Frameworks (SURMOFs), Materials, vol.3, issue.2, pp.1302-1315, 2010.
DOI : 10.1039/b811010g

K. Yusenko, M. Meilikhov, D. Zacher, F. Wieland, C. Sternemann et al., Step-by-step growth of highly oriented and continuous seeding layers of, Cu 2 (ndc) 2 (dabco)] on bare oxide and nitride substrates, pp.12-2086, 2010.

J. Zhuang, J. Friedel, and A. Terfort, The oriented and patterned growth of fluorescent metal???organic frameworks onto functionalized surfaces, Beilstein Journal of Nanotechnology, vol.3, issue.570, 2012.
DOI : 10.3762/bjnano.3.66

X. Yu, J. Zhuang, J. Scherr, T. Abu-husein, and A. Terfort, Minimization of Surface Energies and Ripening Outcompete Template Effects in the Surface Growth of Metal?Organic Frameworks, Angew. Chem. Int. Ed, pp.55-8348, 2016.

R. Makiura, S. Motoyama, Y. Umemura, H. Yamanaka, O. Sakata et al., Surface nano-architecture of a metal???organic framework, Nature Materials, vol.16, issue.7, pp.565-571, 2010.
DOI : 10.1038/nmat2769

D. Vos, Direct Patterning of Oriented Metal?Organic Framework Crystals via Control over Crystallization Kinetics in Clear Precursor Solutions, Adv. Mater, vol.22, pp.2685-2688, 2010.

I. Stassen, N. Campagnol, J. Fransaer, P. Vereecken, D. De-vos et al., Solvent-free synthesis of supported ZIF-8 films and patterns through transformation of deposited zinc oxide precursors, CrystEngComm, vol.520, issue.45, pp.15-9308, 2013.
DOI : 10.1016/j.tsf.2011.11.058

O. Louvain, S. Sakata, and . Kitagawa, Mesoscopic architectures of porous coordination polymers fabricated by pseudomorphic replication, Nat Mater, vol.11, pp.717-723, 2012.
URL : https://hal.archives-ouvertes.fr/hal-01220949

K. Khaletskaya, S. Turner, M. Tu, S. Wannapaiboon, A. Schneemann et al., Self-Directed Localization of ZIF-8 Thin Film Formation by Conversion of ZnO Nanolayers, Advanced Functional Materials, vol.17, issue.30, pp.24-4804, 2014.
DOI : 10.1002/chem.201101595

F. Hinterholzinger, C. Scherb, T. Ahnfeldt, N. Stock, and T. Bein, Oriented growth of the functionalized metal???organic framework CAU-1 on ???OH- and ???COOH-terminated self-assembled monolayers, Physical Chemistry Chemical Physics, vol.127, issue.17, pp.12-4515, 2010.
DOI : 10.1039/b924657f

F. Schreiber, Structure and growth of self-assembling monolayers, Progress in Surface Science, vol.65, issue.5-8, pp.151-257, 2000.
DOI : 10.1016/S0079-6816(00)00024-1

O. I. Lebedev, F. Millange, C. Serre, G. Van-tendeloo, and G. , Fé rey, First Direct Imaging of Giant Pores of the Metal?Organic Framework MIL-101, Chem. Mater, pp.17-6525, 2005.

F. Millange, C. Serre, N. Guillou, G. Fé-rey, and R. I. Walton, Structural Effects of Solvents on the Breathing of Metal?Organic Frameworks: An In Situ Diffraction Study, Angew. Chem. Int. Ed, pp.47-4100, 2008.

G. Fé-rey, M. Latroche, C. Serre, F. Millange, T. Loiseau et al., Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M, OH)(O 2 C-C 6 H 4 -CO 2 ) (M = Al 3+ , Cr 3+ ), pp.53-2976, 2003.

T. R. Whitfield, X. Wang, L. Liu, and A. J. Jacobson, Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions, Solid State Sciences, vol.7, issue.9, pp.1096-1103, 2005.
DOI : 10.1016/j.solidstatesciences.2005.03.007

X. Wallart, C. Henry-de-villeneuve, and P. Allongue, Truly Quantitative XPS Characterization of Organic Monolayers on Silicon: Study of Alkyl and Alkoxy Monolayers on H???Si(111), Journal of the American Chemical Society, vol.127, issue.21
DOI : 10.1021/ja0430797

URL : https://hal.archives-ouvertes.fr/hal-00125385

A. Moraillon, A. C. Gouget-laemmel, F. Ozanam, and J. N. , Amidation of Monolayers on Silicon in Physiological Buffers:??? A Quantitative IR Study, The Journal of Physical Chemistry C, vol.112, issue.18, pp.112-7158, 2008.
DOI : 10.1021/jp7119922

S. Ciampi, J. B. Harper, and J. J. Gooding, Wet chemical routes to the assembly of organic monolayers on silicon surfaces via the formation of Si???C bonds: surface preparation, passivation and functionalization, Chemical Society Reviews, vol.78, issue.551, pp.39-2158, 2010.
DOI : 10.1103/PhysRevB.38.6084

J. M. Buriak, Organometallic Chemistry on Silicon and Germanium Surfaces, Chemical Reviews, vol.102, issue.5, pp.1271-1308, 2002.
DOI : 10.1021/cr000064s

P. Thissen, O. Seitz, and Y. J. , Wet chemical surface functionalization of oxide-free silicon, Progress in Surface Science, vol.87, issue.9-12, pp.272-290, 2012.
DOI : 10.1016/j.progsurf.2012.10.003

J. Allongue and . Chazalviel, Well-Defined Carboxyl-Terminated Alkyl Monolayers Grafted onto H?Si(111): Packing Density from a Combined AFM and Quantitative IR Study, Langmuir, pp.22-153, 2006.

A. Faucheux, F. Yang, P. Allongue, C. Henry-de-villeneuve, F. Ozanam et al., Thermal decomposition of alkyl monolayers covalently grafted on (111) silicon, Applied Physics Letters, vol.13, issue.19, p.88, 2006.
DOI : 10.1103/PhysRevB.72.045317

H. Hä-kkinen, The gold???sulfur interface at the nanoscale, Nature Chemistry, vol.114, issue.413, pp.443-455, 2012.
DOI : 10.1021/jp1015438

S. H. Chen and C. W. Frank, Infrared and fluorescence spectroscopic studies of self-assembled n-alkanoic acid monolayers, Langmuir, vol.5, issue.4, pp.5-978, 1989.
DOI : 10.1021/la00088a017

Y. R. Luo, Comprehensive Handbook of Chemical Bond Energies, 2007.
DOI : 10.1201/9781420007282

M. L. Munford and R. , Cortè s; P. Allongue, The preparation of ideally ordered flat HSi(111) surface, Sensors and Materials, vol.13, pp.259-269, 2001.

V. Allongue, H. Kieling, and . Gerischer, Etching mechanism and atomic structure of H-Si(111) surfaces prepared in NH 4 F, Electrochim. Acta, pp.40-1353, 1995.

F. Schreiber, Structure and growth of self-assembling monolayers, Progress in Surface Science, vol.65, issue.5-8, pp.151-257, 2000.
DOI : 10.1016/S0079-6816(00)00024-1

R. Maoz and J. Sagiv, On the formation and structure of self-assembling monolayers. I. A comparative atr-wettability study of Langmuir???Blodgett and adsorbed films on flat substrates and glass microbeads, Journal of Colloid and Interface Science, vol.100, issue.2, pp.465-496, 1984.
DOI : 10.1016/0021-9797(84)90452-1

J. C. Love, L. A. Estroff, J. K. Kriebel, R. G. Nuzzo, and G. M. Whitesides, Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology, Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology, pp.1103-1170, 2005.
DOI : 10.1021/cr0300789

C. Lai, C. Chiang, P. Lin, K. Yang, C. C. Hua et al., Crystals, ACS Applied Materials & Interfaces, vol.5, issue.9, pp.3530-3540, 2013.
DOI : 10.1021/am401121w

URL : https://hal.archives-ouvertes.fr/tel-01294159

J. W. Hsu, W. M. Clift, and L. N. Brewer, Zinc Oxide Growth Morphology on Self-Assembled Monolayer Modified Silver Surfaces, Langmuir, vol.24, issue.10, pp.24-5375, 2008.
DOI : 10.1021/la703919w

D. Wang, J. Liu, Q. Huo, Z. Nie, W. Lu et al., Surface-Mediated Growth of Transparent, Oriented, and Well-Defined Nanocrystalline Anatase Titania Films, Journal of the American Chemical Society, vol.128, issue.42
DOI : 10.1021/ja0655993

E. Biemmi, C. Scherb, and T. Bein, Oriented Growth of the Metal Organic Framework Cu 3 (BTC) 2 (H 2 O) 3 · xH 2 O Tunable with Functionalized Self-Assembled Monolayers, J. Am. Chem

O. Shekhah, Layer-by-Layer Method for the Synthesis and Growth of Surface Mounted Metal-Organic Frameworks (SURMOFs), Materials, vol.3, issue.2, pp.1302-1315, 2010.
DOI : 10.1039/b811010g

D. Zacher, A. Baunemann, S. Hermes, and R. A. Fischer, Deposition of microcrystalline [Cu 3 (btc) 2 ] and [Zn 2 (bdc) 2 (dabco)] at alumina and silica surfaces modified with patterned self assembled organic monolayers: evidence of surface selective and oriented growth, J. Mater. Chem, pp.17-2785, 2007.

C. Scherb, A. Schödel, and T. Bein, Directing the Structure of Metal?Organic Frameworks by Oriented Surface Growth on an Organic Monolayer, Angew. Chem. Int. Ed, pp.47-5777, 2008.

A. Schoedel, C. Scherb, and T. Bein, Oriented Nanoscale Films of Metal?Organic Frameworks By Room-Temperature Gel-Layer Synthesis, Angew. Chem. Int. Ed, pp.49-7225, 2010.

O. I. Lebedev, F. Millange, C. Serre, G. Van-tendeloo, and G. , Fé rey, First Direct Imaging of Giant Pores of the Metal?Organic Framework MIL-101, Chem. Mater, pp.17-6525, 2005.

C. Serre, C. Mellot-draznieks, S. Surblé, N. Audebrand, Y. Filinchuk et al., Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks, Science, vol.127, issue.46, pp.315-1828, 2007.
DOI : 10.1021/ja054900x

T. R. Whitfield, X. Wang, L. Liu, and A. J. Jacobson, Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions, Solid State Sciences, vol.7, issue.9, pp.1096-1103, 2005.
DOI : 10.1016/j.solidstatesciences.2005.03.007

P. Zhao, N. Cao, J. Su, W. Luo, and G. Cheng, NiIr Nanoparticles Immobilized on the Pores of MIL-101 as Highly Efficient Catalyst toward Hydrogen Generation from Hydrous Hydrazine, ACS Sustainable Chemistry & Engineering, vol.3, issue.6, pp.1086-1093, 2015.
DOI : 10.1021/acssuschemeng.5b00009

S. Surblé, C. Serre, C. Mellot-draznieks, F. Millange, and G. , Fé rey, A new isoreticular class of metal-organic-frameworks with the MIL-88 topology, Chem. Commun, pp.284-286, 2006.

F. Millange, C. Serre, and G. , Fé rey, Synthesis, structure determination and properties of MIL-53as and MIL-53ht: the first Cr 3+ hybrid inorganic-organic microporous solids: Cr ? (OH)·, Chem. Commun, pp.822-823, 2002.

F. Millange, C. Serre, N. Guillou, G. Fé-rey, and R. I. Walton, Structural Effects of Solvents on the Breathing of Metal?Organic Frameworks: An In Situ Diffraction Study, Angew. Chem. Int. Ed, pp.47-4100, 2008.

J. Petukhov, F. Gascon, and . Kapteijn, Kinetic Control of Metal?Organic Framework Crystallization Investigated by Time-Resolved In Situ X-Ray Scattering, Angew. Chem. Int. Ed, pp.50-9624, 2011.

G. Fé-rey, C. Mellot-draznieks, C. Serre, F. Millange, J. Dutour et al., A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area, Science, p.309, 2005.

L. Qin, Z. Li, Z. Xu, X. Guo, and G. Zhang, Organic-acid-directed assembly of iron???carbon oxides nanoparticles on coordinatively unsaturated metal sites of MIL-101 for green photochemical oxidation, Applied Catalysis B: Environmental, vol.179, pp.179-500, 2015.
DOI : 10.1016/j.apcatb.2015.06.001

Y. Zhang, J. Wan, Y. Wang, and Y. Ma, ???Cl, RSC Advances, vol.23, issue.118, pp.97589-97597, 2015.
DOI : 10.1002/adma.201101356

N. Stock and S. Biswas, Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites, Chemical Reviews, vol.112, issue.2, pp.933-969, 2012.
DOI : 10.1021/cr200304e

G. Fé-rey, Hybrid porous solids: past, present, future, Chem. Soc. Rev., vol.294, issue.123, pp.191-214, 2008.
DOI : 10.1126/science.1062126

C. Gerardin, M. In, L. Allouche, M. Haouas, and F. Taulelle, In Situ pH Probing of Hydrothermal Solutions by NMR, Situ pH Probing of Hydrothermal Solutions by NMR, pp.1285-1292, 1999.
DOI : 10.1021/cm980766m

D. Riou and G. , Fé rey, Hybrid open frameworks (MIL-n) Part 3 Crystal structures of the HT and LT forms of MIL-7: a new vanadium propylenediphosphonate with an open-framework. Influence of the synthesis temperature on the oxidation state of vanadium within the same structural type, J

C. Livage, C. Egger, M. Nogues, and G. Fé-rey, Hybrid open frameworks (MIL-n). Part 5 Synthesis and crystal structure of MIL-9: a new three-dimensional ferrimagnetic cobalt(II) carboxylate with a two-dimensional array of edge-sharing Co octahedra with 12-membered rings, Journal of Materials Chemistry, vol.8, issue.12, pp.2743-2747, 1998.
DOI : 10.1039/a802714e

S. Surblé, C. Serre, C. Mellot-draznieks, F. Millange, and G. , Fé rey, A new isoreticular class of metal-organic-frameworks with the MIL-88 topology, Chem. Commun, pp.284-286, 2006.

E. Biemmi, T. Bein, and N. Stock, Synthesis and characterization of a new metal organic framework structure with a 2D porous system: (H2NEt2)2[Zn3(BDC)4]???3DEF, Solid State Sciences, vol.8, issue.3-4, pp.363-370, 2006.
DOI : 10.1016/j.solidstatesciences.2006.02.025

U. Mueller, M. Schubert, F. Teich, H. Puetter, K. Schierle-arndt et al., Metal-organic frameworks-prospective industrial applications, J. Mater. Chem, pp.16-626, 2006.
DOI : 10.1002/chin.200623294

O. I. Lebedev, F. Millange, C. Serre, G. Van-tendeloo, and G. , Fé rey, First Direct Imaging of Giant Pores of the Metal?Organic Framework MIL-101, Chem. Mater, pp.17-6525, 2005.

M. Li and M. Dinc?, Reductive Electrosynthesis of Crystalline Metal???Organic Frameworks, Journal of the American Chemical Society, vol.133, issue.33
DOI : 10.1021/ja2041546

H. Li, M. Eddaoudi, M. O-'keeffe, and O. M. Yaghi, Design and synthesis of an exceptionally stable and highly porous metal-organic framework, Nature, pp.402-276, 1999.

J. R. Long and O. M. Yaghi, The pervasive chemistry of metal???organic frameworks, Chemical Society Reviews, vol.38, issue.5
DOI : 10.1039/b903811f

D. J. Tranchemontagne, J. L. Mendoza-cortes, M. O-'keeffe, and O. M. Yaghi, Secondary building units, nets and bonding in the chemistry of metal???organic frameworks, Chemical Society Reviews, vol.19, issue.suppl. 2, pp.38-1257, 2009.
DOI : 10.1007/s00706-003-0031-3

S. Liu, C. Wang, H. Zhai, and D. Li, Hydrolysis of N,N-dimethylformamide catalyzed by the

H. Keggin, PMo 12 O 40 ]: isolation and crystal structure analysis of, J. Mol. Struct, pp.654-215, 2003.

T. Cottineau, M. Richard-plouet, J. Mevellec, and L. Brohan, -Dimethylformamide in New Nanostructurated Titanium Oxide Hybrid Organic???Inorganic Sols and Gel, The Journal of Physical Chemistry C, vol.115, issue.25, pp.115-12269, 2011.
DOI : 10.1021/jp201864g

V. G. Golubev, T. P. Ryumina, and Z. K. , Corrosion of stainless steels in the dimethylformamide media of polyvinyl chloride fibre manufacturing, Fibre Chemistry, vol.18, issue.4, pp.317-321, 1987.
DOI : 10.1007/BF00556560

E. Buncel and E. A. Symons, The inherent instability of dimethylformamide???water systems containing hydroxide ion, J. Chem. Soc. D, vol.0, issue.3, pp.164-165, 1970.
DOI : 10.1039/C29700000164

Y. Wan, M. Alterman, M. Larhed, and A. Hallberg, Dimethylformamide as a Carbon Monoxide Source in Fast Palladium-Catalyzed Aminocarbonylations of Aryl Bromides, The Journal of Organic Chemistry, vol.67, issue.17, pp.6232-6235, 2002.
DOI : 10.1021/jo025965a

J. Petukhov, F. Gascon, and . Kapteijn, Kinetic Control of Metal?Organic Framework Crystallization Investigated by Time-Resolved In Situ X-Ray Scattering, Angew. Chem. Int. Ed, pp.50-9624, 2011.

. Gascon, Molecular Promoting of Aluminum Metal?Organic Framework Topology MIL-101 by N,N-Dimethylformamide, Inorg. Chem, vol.53, pp.882-887, 2014.

K. I. Bercaw and . Goldberg, NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist, Organometallics, pp.29-2176, 2010.

H. M. Kothari, E. A. Kulp, S. J. Limmer, P. Poizot, E. W. Bohannan et al., Electrochemical deposition and characterization of Fe 3 O 4 films produced by the reduction of

M. L. Ohnsorg, C. K. Beaudoin, and M. E. Anderson, Fundamentals of MOF Thin Film Growth via Liquid-Phase Epitaxy: Investigating the Initiation of Deposition and the Influence of Temperature, Langmuir, vol.31, issue.22, pp.31-6114, 2015.
DOI : 10.1021/acs.langmuir.5b01333

C. Serre, C. Mellot-draznieks, S. Surblé, N. Audebrand, Y. Filinchuk et al., Role of Solvent-Host Interactions That Lead to Very Large Swelling of Hybrid Frameworks, Science, vol.127, issue.46, pp.315-1828, 2007.
DOI : 10.1021/ja054900x

S. Surblé, C. Serre, C. Mellot-draznieks, F. Millange, and G. , Fé rey, A new isoreticular class of metal-organic-frameworks with the MIL-88 topology, Chem. Commun, pp.284-286, 2006.