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, , p.4
, Olivier Cador 3 and Grégory Nocton. 1 *
,
, CNRS, ISCR, vol.6226
, , p.69342
, ) Å. These distances are dictated by the crown-ether chelate
, 26 Since there is no available data on thulium crown-ether complexes in the literature, the only possible comparison is with ytterbium derivatives featuring similar ionic radius: in Yb(NPh2)2(18-c-6), 35 the Yb II -O
, H(BH4) distance is 2.4(1) Å. These distances fit well with the Tm-B distances observed by Nief in Tm(BH4)2(dme)2 that range between 2.632(4) Å and 2.656(5) Å and the Tm-H
, 655 Å) and Tm-H(BH4) (between 2.459 Å and 2.551 Å) distances are observed on the Tp'Tm(BH4) complex
, 14 Å) but the Tm-B distance remain similar (2.631 Å). 38 In this particular case, the steric influence of the bulky Cp ttt ligands 40 can explain this long Tm-B distance. Indeed, a homoleptic Tm(BH4) -thulium complexes, in which the equatorial ligand field is dominant, a failed and further work is in progress in this direction, the Tm-H(BH4) distances are much shorter
, (1156 nm) and 8561 cm -1 (1168 nm) are observed, vol.8909, pp.8649-8650, 1133.
, As important conclusions from the analysis of this spectrum, (i) the overall crystal field splitting is rather small (263 cm -1 ) and (ii) the ground mJ state is close to the first excited one References 1
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