G. L. Makar and J. Kruger, Corrosion of magnesium, 1993.

G. G. Perrault, The potential-pH diagram of the magnesium-water system, Electroalalytical Chem. Interfacial Electrochem, vol.51, pp.107-119, 1974.

S. H. Salleh, S. Thomas, J. A. Yuwono, K. Venkatesan, and N. Birbilis, Enhanced hydrogen evolution on Mg (OH)2 covered Mg surfaces, Electrochim. Acta, vol.161, pp.144-152, 2015.

G. Williams and H. N. Mcmurray, Localized Corrosion of Magnesium in Chloride-Containing Electrolyte Studied by a Scanning Vibrating Electrode Technique, J. Electrochem. Soc, vol.155, pp.340-349, 2008.

J. D. Hanawalt, Some corrosion characteristics of high purity magnesium alloys, J. Electrochem. Soc, vol.81, pp.423-433, 1942.

T. Cain, S. B. Madden, N. Birbilis, and J. R. Scully, Evidence of the enrichment of transition metal elements on corroding magnesium surfaces using Rutherford backscattering spectrometry, J. Electrochem. Soc, vol.162, pp.228-237, 2015.

Z. P. Cano, M. Danaie, J. R. Kish, J. R. Mcdermid, G. A. Botton et al., Physical characterization of cathodically-activated corrosion filaments on magnesium alloy AZ31B, Corrosion, vol.71, pp.146-159, 2015.

M. Esmaily, J. E. Svensson, S. Fajardo, N. Birbilis, G. S. Frankel et al., Fundamentals and advances in magnesium alloy corrosion, Prog. Mater. Sci, vol.89, pp.92-193, 2017.

I. Giner, O. Ozcan, and G. Grundmeier, situ AFM studies of the stability of MgO(100) in aqueous electrolytes, vol.87, pp.51-59, 2014.

X. Guo, G. Song, J. Hu, and D. Huang, Corrosion inhibition of magnesium (Mg) Alloys, in: Corros, Prev. Magnes. Alloy, pp.61-84, 2013.

S. V. Lamaka, B. Vaghefinazari, D. Mei, R. P. Petrauskas, D. Höche et al., Comprehensive screening of Mg corrosion inhibitors, Corros. Sci, vol.128, pp.224-240, 2017.

T. Ohtsuka and M. Matsuda, In situ Raman spectroscopy for corrosion products of zinc in humidified atmosphere in the presence of sodium chloride precipitate, Corrosion, vol.59, pp.407-413, 2003.

M. C. Bernard, A. Hugot-le-goff, D. Massinon, and N. Phillips, Underpaint corrosion of zinc-coated steel sheet studied by in situ raman spectroscopy, Corros. Sci, vol.35, issue.93, p.90356, 1993.

X. Zhang, K. Xiao, C. Dong, J. Wu, X. Li et al., In situ Raman spectroscopy study of corrosion products on the surface of carbon steel in solution containing Cl-and SO42, Eng. Fail. Anal, vol.18, pp.1981-1989, 2011.

S. Simard, M. Odziemkowski, D. E. Irish, L. Brossard, and H. Ménard, In situ micro-Raman spectroscopy to investigate pitting corrosion product of 1024 mild steel in phosphate and bicarbonate solutions containing chloride and sulfate ions, J. Appl. Electrochem, vol.31, pp.913-920, 2001.

M. J. Pelletier, Quantitative Analysis Using Raman Spectrometry, Appl. Spectrosc, vol.57, pp.20-42, 2003.

G. Goudec and P. Colomban, Raman Spectroscopy of nanomaterials : How spectra relate to disorder, particle size and mechanical properties, Prog. Cryst. Growth Charact

. Mater, , vol.53, pp.1-56, 2007.

J. Angeli, A. Bengtson, A. Bogaerts, V. Hoffmann, V. Hodoroaba et al., Glow discharge optical emission spectrometry: moving towards reliable thin film analysisa short review, J. Anal. At. Spectrom, vol.18, pp.670-679, 2003.

V. Hodoraba, Hydrogen Effect and Analysis in GDS -Applications in Material Science, 2002.

V. D. Hodoroaba, E. B. Steers, V. Hoffmann, W. E. Unger, W. Paatsch et al., Influence of hydrogen on the analytical figures of merit of glow discharge optical emission spectroscopy -friend or foe?, J. Anal. At. Spectrom, vol.18, pp.521-526, 2003.

T. R. Zeitler, J. A. Greathouse, J. D. Gale, and R. T. Cygan, Vibrational analysis of brucite surfaces and the development of an improved force field for molecular simulation of interfaces, J. Phys. Chem. C, vol.118, pp.7946-7953, 2014.

V. Masilamani, H. M. Ghaithan, M. J. Aljaafreh, A. Ahmed, R. Thagafi et al., Using a Spectrofluorometer for Resonance Raman Spectra of Organic Molecules, p.2017, 2017.

J. Yang, C. Blawert, S. V. Lamaka, K. A. Yasakau, L. Wang et al.,

M. L. Di and . Zheludkevich, Corrosion inhibition of pure Mg containing a high level of iron impurity in pH neutral NaCl solution, Corros. Sci. Accepted, 2018.

W. Beetz and X. , On the development of hydrogen from the anode, Philos. Mag. Ser. 4, vol.32, pp.269-278, 1866.

M. Esmaily, J. E. Svensson, S. Fajardo, N. Birbilis, G. S. Frankel et al., Fundamentals and advances in magnesium alloy corrosion, Prog. Mater. Sci, vol.89, pp.92-193, 2017.

S. Thomas, N. V. Medhekar, G. S. Frankel, and N. Birbilis, Corrosion mechanism and hydrogen evolution on Mg, Curr. Opin. Solid State Mater. Sci, vol.19, pp.85-94, 2015.

R. L. Petty, A. W. Davidson, and J. Kleinberg, The Anodic Oxidation of Magnesium Metal: Evidence for the Existence of Unipositive Magnesium, J. Am. Chem. Soc, vol.76, pp.363-366, 1954.

B. Guang, L. Song, A. Atrens, G. L. Song, A. Atrens et al., Corrosion Mechanisms of Magnesium Alloys, vol.1, pp.11-33, 1999.

G. Song and A. Atrens, Recent insights into the mechanism of magnesium corrosion and research suggestions, Adv. Eng. Mater, vol.9, pp.177-183, 2007.

A. Atrens and W. Dietzel, The negative difference effect and unipositive Mg, Adv. Eng. Mater, vol.9, pp.292-297, 2007.

M. E. Straumanis and B. K. Bhatia, Disintegration of Magnesium While Dissolving Anodically in Neutral and Acidic Solutions, J. Electrochem. Soc, vol.110, pp.357-360, 1963.

E. Gulbrandsen, Anodic Behavior of Mg in Hc03-/Co23-Buffer Solutions, Quasi-Steady Measurements, Electrochim. Acta, vol.37, pp.1403-1412, 1992.

J. H. Nordlien, Morphology and structure of oxide films formed on MgAl alloys by exposure to air and water, J. Electrochem. Soc, vol.143, p.2564, 1996.

D. A. Vermilyea and C. F. Kirk, Studies of Inhibition of Magnesium Corrosion, J. Electrochem. Soc, vol.116, pp.1487-1492, 1969.

J. H. Nordlien, S. Ono, N. Masuko, and K. Nisancioglu, A TEM investigation of naturally formed oxide films on pure magnesium, Corros. Sci, vol.39, pp.1397-1414, 1997.

G. L. Song, Corrosion electrochemistry of magnesium (Mg) and its alloys, 2011.

J. R. Kish, Y. Hu, J. Li, W. Zheng, and J. R. Mcdermid, Technical note: Examination of focused ion beam-sectioned surface films formed on am60b mg alloy in an aqueous saline solution, Corrosion, vol.68, pp.468-474, 2012.

S. Feliu, M. C. Merino, R. Arrabal, A. E. Coy, and E. Matykina, XPS study of the effect of aluminium on the atmospheric corrosion of the AZ31 magnesium alloy, Surf. Interface Anal, vol.41, pp.143-150, 2009.

N. Birbilis, G. Williams, K. Gusieva, A. Samaniego, M. A. Gibson et al., Poisoning the corrosion of magnesium, Electrochem. Commun, vol.34, pp.295-298, 2013.

H. Wang, Y. Song, J. Yu, D. Shan, and H. Han, Characterization of Filiform Corrosion of Mg-3Zn Mg Alloy, J. Electrochem. Soc, vol.164, 2017.

G. Williams, H. A. Dafydd, R. Subramanian, and H. N. Mcmurray, The influence of Chloride Ion Concentration on Passivity Breakdown in Magnesium, Corrosion, vol.73, pp.471-481, 2017.

K. Gusieva, C. H. Davies, J. R. Scully, and N. Birbilis, Corrosion of magnesium alloys: the role of alloying, Int. Mater. Rev, vol.60, pp.169-194, 2015.

M. L. Sviatlana, V. Lamaka, J. Gonzalez, D. Mei, and F. Feyerabend, Regine Willumeit-Römer, Local pH and its Evolution near Mg Alloy Surfaces Exposed to Simulated Body Fluids, Adv. Mater. Interfaces, vol.1800169, pp.1-6, 2018.

Z. P. Cano, J. R. Mcdermid, and J. R. Kish, Cathodic Activity of Corrosion Filaments Formed on Mg Alloy AM30, J. Electrochem. Soc, vol.162, pp.732-740, 2015.

G. S. Frankel, S. Fajardo, and M. Lynch, Faraday Discuss, vol.180, pp.11-33, 2015.

G. Williams, N. Birbilis, and H. N. Mcmurray, Controlling factors in localised corrosion morphologies observed for magnesium immersed in chloride containing electrolyte, Faraday Discuss, vol.180, 2015.

G. R. Hoey and M. Cohen, Corrosion of Anodically and Cathodically Polarized Magnesium in Aqueous Media, J. Electrochem. Soc, vol.105, p.245, 1958.

G. Williams, N. Birbilis, and H. N. Mcmurray, The source of hydrogen evolved from a magnesium anode, Electrochem. Commun, vol.36, pp.1-5, 2013.

S. Fajardo and G. S. Frankel, Effect of impurities on the enhanced catalytic activity for hydrogen evolution in high purity magnesium, Electrochim. Acta, vol.165, pp.255-267, 2015.

M. Curioni, F. Scenini, T. Monetta, and F. Bellucci, Correlation between electrochemical impedance measurements and corrosion rate of magnesium investigated by real-time hydrogen measurement and optical imaging, Electrochim. Acta, vol.166, pp.372-384, 2015.

S. Fajardo, C. F. Glover, G. Williams, and G. S. Frankel, The evolution of anodic hydrogen on high purity magnesium in acidic buffer solution, Corrosion, vol.73, pp.482-493, 2017.

K. S. Williams, J. P. Labukas, V. Rodriguez-santiago, and J. W. Andzelm, First Principles Modeling of Water Dissociation on Mg(0001) and Development of a Mg Surface Pourbaix Diagram, Corrosion, vol.71, pp.209-223, 2015.

S. V. Lamaka, O. V. Karavai, A. C. Bastos, M. L. Zheludkevich, and M. G. Ferreira, Monitoring local spatial distribution of Mg2+, pH and ionic currents, Electrochem. Commun, vol.10, pp.259-262, 2008.

A. Seyeux, V. Maurice, and P. Marcus, Oxide Film Growth Kinetics on Metals and Alloys: I. Physical Model, J. Electrochem. Soc, vol.160, pp.189-196, 2013.

C. Wagner, Contribution to the Theory of the Tarnishing Process, J. Phys. Chem, vol.21, pp.25-41, 1933.

N. Cabrera and N. F. Mott, Theory of the oxidation of metals, vol.12, pp.163-184, 1949.

F. P. Fehlner and N. F. Mott, Low-temperature oxidation, Oxid. Met, vol.2, pp.59-99, 1970.

C. Y. Chao, L. F. Lin, and D. D. Macdonald, A Point Defect Model for Anodic Passive Films, p.147

I. Film-growth and . Kinetics, J. Electrochem. Soc, vol.128, p.1981, 1981.

D. D. Macdonald, S. R. Biaggio, and H. Song, Steady State Passive Films Interfacial Kinetic Effects and Diagnostic Criteria, J. Electrochem. Soc, vol.139, pp.170-177, 1992.

A. T. Fromhold, Kinetics of oxide film growth on metal crystals -I. Formulation and numerical solutions, J. Phys. Chem. Solids, vol.24, issue.63, pp.90400-90409, 1963.

A. T. Fromhold, Fundamental Theory of the Growth of Thick Oxide Films on Metals, J. Phys. Soc. Japan, vol.48, pp.2022-2030, 1980.

E. Ghali, Corrosion Resistance of Aluminum and Magnesium Alloys: Understanding, Performance and Testing, 2010.

J. Robertson and J. E. Forrest, Corrosion of carbon steels in high temperature acid chloride solutions, Corros. Sci, vol.32, pp.521-540, 1991.

A. E. Nielsen, Kinetics of Precipitation, 1964.

W. Sun, S. Nesic, and ;. Nace, Basics revisited: kinetics of iron carbonate scale precipitation in CO2 corrosion, pp.1-26, 2006.

J. Robertson, The mechanism of high temperature aqueous corrosion of stainless steels, Corros. Sci, vol.32, pp.90125-90134, 1991.

L. Yin, Y. Jin, C. Leygraf, N. Birbilis, and J. Pan, Numerical Simulation of Micro-Galvanic Corrosion in Al Alloys: Effect of Geometric Factors, J. Electrochem. Soc, vol.164, pp.75-84, 2017.

M. Bartosch, S. Schubert, and F. Berger, Magnesium stents-fundamentals, biological implications and applications beyond coronary arteries, vol.16, pp.3-17, 2015.

D. Höche, C. Blawert, S. V. Lamaka, N. Scharnagl, C. Mendis et al., The effect of iron re-deposition on the corrosion of impurity-containing magnesium, Phys.Chem.Chem.Phys, vol.18, pp.1279-1291, 2015.

S. V. Lamaka, D. Höche, R. P. Petrauskas, C. Blawert, and M. L. Zheludkevich, A new concept for corrosion inhibition of magnesium : Suppression of iron re-deposition, Electrochem. Commun, 2015.

D. Mercier, J. ?wiatowska, S. Zanna, A. Seyeux, and P. Marcus, Role of Segregated Iron at Grain Boundaries on Mg Corrosion, J. Electrochem. Soc, vol.165, pp.42-49, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01868601

N. Birbilis, T. Cain, J. S. Laird, X. Xia, J. R. Scully et al., Nuclear Microprobe Analysis for Determination of Element Enrichment Following Magnesium Dissolution, ECS Electrochem. Lett, vol.4, pp.34-37, 2015.

F. El-taib-heakal, A. M. Fekry, and M. Z. Fatayerji, Influence of halides on the dissolution and passivation behavior of AZ91D magnesium alloy in aqueous solutions, Electrochim. Acta, vol.54, pp.1545-1557, 2009.

L. Wang, T. Shinohara, and B. P. Zhang, Influence of chloride, sulfate and bicarbonate anions on the corrosion behavior of AZ31 magnesium alloy, J. Alloys Compd, vol.496, pp.500-507, 2010.

G. Wu, Y. Fan, A. Atrens, C. Zhai, and W. Ding, Electrochemical behavior of magnesium alloys AZ91D, AZCe2, and AZLa1 in chloride and sulfate solutions, J. Appl

. Electrochem, , vol.38, pp.251-257, 2008.

M. M. Antonijevic and M. B. Petrovic, Copper Corrosion Inhibitors . A review, Rev. Lit. Arts Am, vol.3, pp.1-28, 2008.

B. E. Rani and B. B. Basu, Green inhibitors for corrosion protection of metals and alloys: An overview, Int. J. Corros, p.2012, 2012.

K. Xhanari, M. Fin?gar, M. Hrn?i?, U. Maver, ?. Knez et al., Green corrosion inhibitors for aluminium and its alloys: A review, RSC Adv, vol.7, pp.27299-27330, 2017.

J. Hu, D. Zeng, Z. Zhang, T. Shi, G. L. Song et al., 2-Hydroxy-4-methoxyacetophenone as an environment-friendly corrosion inhibitor for AZ91D magnesium alloy, Corros. Sci, vol.74, pp.35-43, 2013.

N. Dinodi and A. N. Shetty, Alkyl carboxylates as efficient and green inhibitors of magnesium alloy ze41 corrosion in aqueous salt solution, Corros. Sci, vol.85, pp.411-427, 2014.

I. A. Kartsonakis, S. G. Stanciu, A. A. Matei, E. K. Karaxi, R. Hristu et al., Evaluation of the protective ability of typical corrosion inhibitors for magnesium alloys towards the Mg ZK30 variant, Corros. Sci, vol.100, pp.194-208, 2015.

G. Williams, R. Grace, and R. M. Woods, Inhibition of the localized corrosion of mg alloy AZ31 in chloride containing electrolyte, Corrosion, vol.71, pp.184-198, 2015.

J. Hu, D. Huang, G. L. Song, and X. Guo, The synergistic inhibition effect of organic silicate and inorganic Zn salt on corrosion of Mg-10Gd-3Y magnesium alloy, Corros. Sci, vol.53, pp.4093-4101, 2011.

D. Huang, J. Hu, G. L. Song, and X. Guo, , p.149

, inhibitors on the corrosion of Mg-10Gd-3Y-0.5Zr alloy in an ethylene glycol solution at ambient and elevated temperatures, Electrochim. Acta, vol.56, pp.10166-10178, 2011.

S. Thirugnanaselvi, S. Kuttirani, and A. R. Emelda, Effect of Schiff base as corrosion inhibitor on AZ31 magnesium alloy in hydrochloric acid solution, Trans. Nonferrous Met. Soc. China (English Ed, vol.24, issue.14, pp.63278-63285, 2014.

J. Hu, D. Huang, G. Zhang, G. L. Song, and X. Guo, Research on the inhibition mechanism of tetraphenylporphyrin on AZ91D magnesium alloy, Corros. Sci, vol.63, pp.367-378, 2012.

J. Lei, L. Li, and F. Pan, Environmental Friendly Corrosion Inhibitors for Magnesium Alloys, Magnes. Alloy. -Corros. Surf. Treat, pp.47-64, 2010.

D. Landolt, Corrosion and surface chemistry of metals, 2007.

E. Slavcheva and G. Schmitt, Screening of new corrosion inhibitors via electrochemical noise analysis, Mater. Corros, vol.53, pp.647-655, 2002.

N. H. Helal and W. A. Badawy, Environmentally safe corrosion inhibition of Mg-Al-Zn alloy in chloride free neutral solutions by amino acids, Electrochim. Acta, vol.56, pp.6581-6587, 2011.

A. Frignani, V. Grassi, F. Zanotto, and F. Zucchi, Inhibition of AZ31 Mg alloy corrosion by anionic surfactants, Corros. Sci, vol.63, pp.29-39, 2012.

D. Huang, Y. Tu, G. Song, X. Guo, and E. T. Al, Inhibition Effects of Pyrazine and Piperazine on the Corrosion of Mg-10Gd-3Y-0 . 5Zr Alloy in an, Ethylene Glycol Solution, pp.36-38, 2013.

N. Dang, Y. H. Wei, L. F. Hou, Y. G. Li, and C. L. Guo, Investigation of the inhibition effect of the environmentally friendly inhibitor sodium alginate on magnesium alloy in sodium chloride solution, Mater. Corros, vol.66, pp.1354-1362, 2015.

R. P. Eischens and W. A. Pliskin, The Infrared Spectra of Adsorbed Molecules, Adv. Catal, vol.10, pp.1-56, 1958.

W. Stumm and M. V. Blber, An In-Situ ATR-FTIR Study: The Surface Coordination of Salicylic Acid on Aluminum and Iron(III) Oxides, vol.28, pp.763-768, 1994.

A. Davantès and G. Lefèvre, In situ real time infrared spectroscopy of sorption of (poly)molybdate ions into layered double hydroxides, J. Phys. Chem. A, vol.117, p.150, 2013.

, , pp.12922-12929

V. Shkirskiy, P. Keil, H. Hintze-bruening, F. Leroux, P. Vialat et al., Factors Affecting MoO 4 2-Inhibitor Release from Zn 2 Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings, ACS Appl. Mater. Interfaces, vol.7, pp.25180-25192, 2015.
URL : https://hal.archives-ouvertes.fr/hal-01276535

A. Zoubir, Raman Imaging Techniques and Applications, 2012.

P. Colomban, Potential and Drawbacks of Raman (Micro)Spectrometry for the Understanding of Iron and Steel Corrosion, New Trends Dev. Automot. Syst. Eng, pp.567-584, 2011.

A. Quentmeier, Glow Discharge Optical Emission Spectroscopy (GD-OES), in: H

, Surf. Thin Film Anal. Princ. Instrimentation, Appl, 2002.

D. Wei, S. Chen, and Q. Liu, Review of fluorescence suppression techniques in Raman spectroscopy, Appl. Spectrosc. Rev, vol.50, pp.387-406, 2015.

I. A. Clegg, N. J. Everall, B. King, H. Melvin, and C. Norton, On-Line Analysis Using Raman Spectroscopy for Process Control during the Manufacture of Titanium Dioxide, Appl. Spectrosc, vol.55, pp.1138-1150, 2001.

W. A. England, S. N. Jenny, and D. A. Greenhalgh, Chromium Oxide Film Thickness Measurements Using Spontaneous Raman Scattering, J. Raman Spectrosc, vol.15, pp.156-159, 1984.

E. J. Hutchinson, D. Shu, and F. Laplant, Measurement of Fluid Film Thickness on Curved Surfaces by Raman Spectroscopy, Appl. Spectrosc, vol.49, pp.1275-1278, 1995.

L. Black, G. C. Allen, and P. C. Frost, Quantification of Raman Spectra for the Primary Atmospheric Corrosion Products of Lead, Appl. Spectrosc, vol.49, pp.1299-1304, 1995.

M. Assirelli, W. Xu, and W. Chew, Reactor kinetics studies via process raman spectroscopy, multivariate chemometrics, and kinetics modeling, Org. Process Res

, Dev, vol.15, pp.610-621, 2011.

E. Dropsit, D. Chapron, P. Bourson, S. Hoppe, and A. Durand, On the exploitation of optical signal from Raman spectroscopy for in-situ conversion monitoring of emulsion polymerization, AIP Conf. Proc, p.1914, 2017.
URL : https://hal.archives-ouvertes.fr/hal-01498461

D. De-waal, A. M. Heyns, and K. J. Range, A Raman spectroscopic determination of the 151

, kinetics of decomposition of ammonium chromate (NH4)2CrO4, J. Solid State Chem, vol.80, pp.170-177, 1989.

L. J. Bonales, V. Muñoz-iglesias, D. Santamaría-pérez, M. Caceres, D. Fernandez-remolar et al., Quantitative Raman spectroscopy as a tool to study the kinetics and formation mechanism of carbonates, Spectrochim. Acta -Part A Mol

, Biomol. Spectrosc, vol.116, pp.26-30, 2013.

A. Tomandl, M. Wolpers, and K. Ogle, The alkaline stability of phosphate coatings II: In situ Raman spectroscopy, Corros. Sci, vol.46, pp.183-188, 2004.

R. Rodriguez, S. Vargas, M. Estevez, F. Quintanilla, A. Trejo-lopez et al., Use of Raman spectroscopy to determine the kinetics of chemical transformation in yogurt production, Vib. Spectrosc, vol.68, pp.133-140, 2013.

S. Li, Q. Guan, G. Meng, X. Chang, J. Wei et al., Revealing chemical processes and kinetics of drug action within single living cells via plasmonic Raman probes, Sci. Rep, vol.7, p.2296, 2017.

N. J. Everall, Modeling and Measuring the Effect of Refraction on the Depth Resolution of Confocal Raman Microscopy, Appl. Spectrosc, vol.54, pp.772-782, 2000.

M. C. Bernard, A. Hugot-le-goff, D. Massinon, and N. Phillips, Underpaint corrosion of zinc-coated steel sheet studied by in situ raman spectroscopy, Corros. Sci, vol.35, issue.93, p.90356, 1993.

P. Delichere, A. Hugot-le-goff, and S. Joiret, Study of thin corrosion films by in situ Raman spectroscopy combined with direct observation of nuclear reactions, Surf. Interface Anal, vol.12, pp.419-423, 1988.

D. Abourazzouk and A. H. Goff, Corrosion of Ni-Cr dental alloys studied by in situ Raman spectroscipy: role of beryllium, Corros. Sci, vol.35, pp.809-815, 1993.

N. Boucherit, A. Hugot-le-goff, and S. Joiret, Raman studies of corrosion films grown on iron and iron-molybdenum (Fe-6Mo) in pitting conditions, Corros. Sci, vol.32, pp.497-507, 1991.

R. L. Farrow and A. S. Nagelberg, Raman spectroscopy of surface oxides at elevated temperatures, Appl. Phys. Lett, vol.36, pp.945-947, 1980.

A. H. Goff and C. Pallotta, Situ Raman Spectroscopy for the Study of Iron Relation to Solution Composition Passivity in A, J. Electrochem. Soc, vol.132, pp.2805-2806, 1985.

T. Ohtsuka, K. Kubo, and N. Sato, Raman Spectroscopy of Thin Corrosion Films on Iron, vol.152

, At 100 To 150 C in Air, Corrosion, vol.42, pp.476-481, 1986.

D. Thierry, D. Persson, and C. Leygraf, Situ Raman Spectroscopy Combined with X-Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe-Cr Single Crystals, J. Electrochem. Soc, vol.135, p.305, 1988.

J. Weissenrieder and C. Leygraf, Situ Studies of Filiform Corrosion of Iron, J. Electrochem. Soc, vol.151, p.165, 2004.

L. Kouisni, M. Azzi, M. Zertoubi, F. Dalard, and S. Maximovitch, Phosphate coatings on magnesium alloy AM60 part 1: Study of the formation and the growth of zinc phosphate films, Surf. Coatings Technol, vol.185, pp.58-67, 2004.
URL : https://hal.archives-ouvertes.fr/hal-00417961

J. Zhang, C. Dai, J. Wei, Z. Wen, S. Zhang et al., Degradable behavior and bioactivity of micro-arc oxidized AZ91D Mg alloy with calcium phosphate/chitosan composite coating in m-SBF, Colloids Surfaces B Biointerfaces, vol.111, pp.179-187, 2013.

A. A. Zuleta, E. Correa, C. Villada, M. Sepúlveda, J. G. Castaño et al., Comparative study of different environmentally friendly (Chromium-free) methods for surface modification of pure magnesium, Surf. Coatings Technol, vol.205, pp.5254-5259, 2011.

D. Iqbal, A. Sarfraz, M. Stratmann, and A. Erbe, Solvent-starved conditions in confinement cause chemical oscillations excited by passage of a cathodic delamination front, Chem. Commun, vol.51, pp.16041-16044, 2015.

R. Posner, A. M. Jubb, G. S. Frankel, M. Stratmann, and H. C. Allen, Simultaneous in situ Kelvin probe and Raman spectroscopy analysis of electrode potentials and molecular structures at polymer covered salt layers on steel, Electrochim. Acta, vol.83, pp.327-334, 2012.

D. Iqbal, A. Sarfraz, and A. Erbe, Gradient in defect density of ZnO nanorods grown by cathodic delamination, a corrosion process, leads to end-specific luminescence, Nanoscale Horizons, vol.3, pp.58-65, 2018.

E. S. Sherif, R. M. Erasmus, and J. D. Comins, In situ Raman spectroscopy and electrochemical techniques for studying corrosion and corrosion inhibition of iron in sodium chloride solutions, Electrochim. Acta, vol.55, pp.3657-3663, 2010.

J. D. Ramsey and R. L. Mccreery, Situ Raman Microscopy of Chromate Effects on Corrosion Pits in Aluminum Alloy, J. Electrochem. Soc, vol.146, 1999.

P. Cao, R. Gu, and Z. Tian, Electrochemical and surface-enhanced raman spectroscopy studies on inhibition of iron corrosion by benzotriazole, Langmuir, vol.18, pp.7609-7615, 2002.

F. Zhang, T. Brinck, B. D. Brandner, P. M. Claesson, A. Dedinaite et al., In situ confocal Raman micro-spectroscopy and electrochemicalstudies of mussel adhesive protein and ceria composite film on carbonsteel in salt solutions, Electrochim. Acta, vol.107, pp.276-291, 2013.

A. Samaniego, B. L. Hurley, and G. S. Frankel, On the evidence for univalent Mg, J. Electroanal. Chem, vol.737, pp.123-128, 2015.

A. Bengtson and S. Hanstrom, Proc. Fifth Int. Conf. Prog, pp.47-54, 1999.

P. L. Larkins, The effect of water vapour on atom production by glow-discharge sputtering, Spectrochim. Acta Part B At. Spectrosc, vol.46, pp.291-299, 1991.

T. J. Loving and W. W. Harrison, Simultaneous analysis of an abnormal glow discharge by atomic absorption spectrometry and mass spectrometry, Anal. Chem, vol.55, pp.1523-1526, 1983.

K. R. Hess and W. W. Harrison, The Role of Metastable Atoms in Glow Discharge Ionization Processes, vol.60, pp.691-696, 1988.

P. H. Ratliff and W. W. Harrison, The effects of water vapor in glow discharge mass spectrometry, Spectrochim. Acta Part B At. Spectrosc, vol.49, pp.80145-80147, 1994.

A. Bogaerts and R. Gijbels, Effects of adding hydrogen to an argon glow discharge: overview of relevant processes and some qualitative explanations, J. Anal. At. Spectrom, vol.15, pp.441-449, 2000.

V. Hodoroaba, V. Hoffmann, E. B. Steers, and K. Wetzig, Investigations of hydrogen in an argon glow discharge, J. Anal. At. Spectrom, vol.15, pp.1075-1080, 2000.

V. Hodoroaba, E. B. Steers, V. Hoffman, and K. Wetzig, The effect of small quantities of hydrogen on a glow discharge in neon . Comparison with the argon case, J. Anal. At. Spectrom, vol.16, pp.43-49, 2001.

R. Payling, M. Aeberhard, and D. Delfosse, Improved quantitative analysis of hard coatings by radiofrequency glow discharge optical emission spectrometry (rf-GD-OES), J. Anal. At. Spectrom, vol.16, pp.50-55, 2001.

T. W. Cain, I. Gonzalez-afanador, N. Birbilis, and J. R. Scully, The Role of Surface Films and Dissolution Products on the Negative Difference Effect for Magnesium: Comparison of Cl ? versus Cl ? Free Solutions, J. Electrochem. Soc, vol.164, pp.300-311, 2017.

E. C. Transactions and T. E. Society, Chloride Ion Concentration Effects on Passivity Breakdown in Magnesium G. Williams, vol.58, pp.23-34, 2014.

Y. Yang, F. Scenini, and M. Curioni, A study on magnesium corrosion by real-time imaging and electrochemical methods: Relationship between local processes and hydrogen evolution, Electrochim. Acta, vol.198, pp.174-184, 2016.

P. Dauphin-ducharme and J. Mauzeroll, Surface Analytical Methods Applied to Magnesium Corrosion

S. Lebouil, O. Gharbi, P. Volovitch, and K. Ogle, Mg dissolution in phosphate and chloride electrolytes : Insight into the mechanism of the negative difference effect, Corrosion, vol.71, pp.234-241, 2015.

J. ?wiatowska, P. Volovitch, and K. Ogle, The anodic dissolution of Mg in NaCl and Na2SO4 electrolytes by atomic emission spectroelectrochemistry, Corros. Sci, vol.52, pp.2372-2378, 2010.

O. Gharbi and N. Birbilis, Clarifying the Dissolution Mechanisms and Electrochemistry of Mg 2 Si as a Function of Solution pH, J. Electrochem. Soc, vol.165, pp.497-501, 2018.

G. S. Frankel, A. Samaniego, and N. Birbilis, Evolution of hydrogen at dissolving magnesium surfaces, Corros. Sci, vol.70, pp.104-111, 2013.

D. S. Gandel, N. Birbilis, M. A. Easton, and M. A. Gibson, The Influence of Mn on the Corrosion of Al-Free Mg Alloys, 18th Int, Corros. Cong, vol.8, pp.1-9, 2011.

G. Baril and N. Pébère, Corrosion of pure magnesium in aerated and deaerated sodium sulphate solutions, Corros. Sci, vol.43, pp.95-95, 2001.

G. Baril, G. Galicia, C. Deslouis, N. Pébère, B. Tribollet et al., An Impedance Investigation of the Mechanism of Pure Magnesium Corrosion in Sodium Sulfate 155

. Solutions, J. Electrochem. Soc, vol.154, p.108, 2007.

L. G. Bland, K. Gusieva, and J. R. Scully, Effect of Crystallographic Orientation on the Corrosion of Magnesium: Comparison of Film Forming and Bare Crystal Facets using Electrochemical Impedance and Raman Spectroscopy, Electrochim. Acta, vol.227, pp.136-151, 2017.

R. Baddour-hadjean and J. P. Pereira-ramos, Raman microspectrometry applied to the study of electrode materials for lithium batteries, Chem. Rev, vol.110, pp.1278-1319, 2010.

B. Downs, S. Robinson, H. Yang, P. Mooney, and . Project, Dep. Geosci. Univ. Arizona, 2015.

O. S. Pokrovsky and J. Schott, Experimental study of brucite dissolution and precipitation in aqueous solutions: Surface speciation and chemical affinity control, Geochim. Cosmochim. Acta, vol.68, pp.31-45, 2004.

S. R. Soniya and V. M. Nair, Synthesis and Characterization of Nanostructured Mg(OH)2 and MgO, Int. J. Sci. Res, vol.5, pp.197-203, 2016.

C. Henrist, J. P. Mathieu, C. Vogels, A. Rulmont, and R. Cloots, Morphological study of magnesium hydroxide nanoparticles precipitated in dilute aqueous solution, J. Cryst. Growth, vol.249, pp.321-330, 2003.

B. Dabir, R. W. Peters, and J. D. Stevens, Precipitation Kinetics of Magnesium Hydroxide in a Scaling System, Ind. Eng. Chem. Fundam, vol.21, pp.298-305, 1982.

K. Zeppenfeld, Electrochemical removal of calcium and magnesium ions from aqueous solutions, Desalination, vol.277, pp.99-105, 2011.

C. S. Grove, R. V. Jelinek, and H. M. Schoen, Crystallization from Solution, Adv. Chem. Eng, vol.3, 1962.

J. A. Dirksen and T. A. Ring, Fundamentals of Crystallization: Kinetic Effects on Particle Size Distributions and Morphology, vol.46, pp.2389-2427, 1991.

G. Williams, H. A. Dafydd, and R. Grace, The localised corrosion of Mg alloy AZ31 in chloride containingelectrolyte studied by a scanning vibrating electrode technique, Electrochim. Acta, vol.109, pp.489-501, 2013.

G. Lefèvre, V. Pichot, and M. Fédoroff, Controlling particle morphology during growth of 156

, bayerite in aluminate solutions, Chem. Mater, vol.15, pp.2584-2592, 2003.

H. A. Straten and P. L. Bruyn, Precipitation from Supersaturated Aluminate Solutions, J. Colloid Interface Sci, vol.102, pp.260-277, 1984.

J. H. Parker, D. W. Feldman, and M. Ashkin, Raman Scattering by Optical Modes of Metals, Light Scatt. Spectra Solids Proc. Int. Conf. Held New York Univ, pp.389-397, 1968.

J. R. Ferraro, Low-Frequency Vibrations of Inorganic and Coordination Compounds, 2012.

J. Kapitán, M. Dra?ínský, J. Kaminský, L. Benda, and P. Bou?, Theoretical modeling of magnesium Ion imprints in the Raman scattering of water, J. Phys. Chem. B, vol.114, pp.3574-3582, 2010.

E. S. Gnanakumar, R. R. Gowda, S. Kunjir, T. G. Ajithkumar, P. R. Rajamohanan et al., MgCl2·6CH3OH: A simple molecular adduct and its influence as a porous support for olefin polymerization, ACS Catal, vol.3, pp.303-311, 2013.

R. J. Capwell, Raman spectra of crystalline and molten MgCl2, Chem. Phys. Lett, vol.12, pp.443-446, 1972.

M. Taheri, J. R. Kish, N. Birbilis, M. Danaie, E. A. Mcnally et al., Electrochimica Acta Towards a Physical Description for the Origin of Enhanced Catalytic Activity of Corroding Magnesium Surfaces, Electrochim. Acta, vol.116, pp.396-403, 2014.

A. Atrens, G. Song, F. Cao, Z. Shi, and P. K. Bowen, Advances in Mg corrosion and research suggestions, J. Magnes. Alloy, vol.1, pp.177-200, 2013.

G. S. Frankel, S. Fajardo, and M. Lynch, Faraday Discuss, vol.180, pp.11-33, 2015.

G. Baril, G. Galicia, C. Deslouis, N. Pébère, B. Tribollet et al., An Impedance Investigation of the Mechanism of Pure Magnesium Corrosion in Sodium Sulfate Solutions, J. Electrochem. Soc, vol.154, p.108, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00806016

S. Thomas, N. V. Medhekar, G. S. Frankel, and N. Birbilis, Corrosion mechanism and hydrogen evolution on Mg, Curr. Opin. Solid State Mater. Sci, vol.19, pp.85-94, 2015.

S. N. Mathaudhu, A. A. Luo, N. R. Neelameggham, E. A. Nyberg, and W. H. Sillekens, Essential readings in magnesium technology, 2014.

M. Liu, S. Zanna, H. Ardelean, I. Frateur, P. Schmutz et al., A first quantitative XPS study of the surface films formed, by exposure to water, on Mg and on the Mg-Al intermetallics: Al3Mg2 and Mg17Al12, Corros. Sci, vol.51, pp.1115-1127, 2009.

K. A. Unocic, H. H. Elsentriecy, M. P. Brady, H. M. Meyer, G. L. Song et al., Transmission Electron Microscopy Study of Aqueous Film Formation and Evolution on Magnesium Alloys, J. Electrochem. Soc, vol.161, pp.302-311, 2014.

L. Yang, X. Zhou, M. Curioni, S. Pawar, H. Liu et al., Corrosion Behavior of Pure Magnesium with Low Iron Content in 3.5 wt% NaCl Solution, J. Electrochem. Soc, vol.162, pp.362-368, 2015.

L. Yang, X. Zhou, S. M. Liang, R. Schmid-fetzer, Z. Fan et al., Effect of traces of silicon on the formation of Fe-rich particles in pure magnesium and the corrosion susceptibility of magnesium, J. Alloys Compd, vol.619, pp.396-400, 2015.

D. Mercier, A. Seyeux, S. Zanna, J. Swiatowska, and P. Marcus, Chemical surface analyses: towards the understanding of magnesium corrosion, 2016.

R. Payling, J. Delwyn, and A. Bengston, Glow Discharge Optical Emission Spectrometry, 1997.

J. M. Hernández-lópez, A. Nemcova, X. L. Zhong, H. Liu, M. A. Arenas et al., Formation of barrier-type anodic films on ZE41 magnesium alloy in a fluoride/glycerol electrolyte, Electrochim. Acta, vol.138, pp.124-131, 2014.

M. S. Palagonia, A. Nemcova, I. Kubena, M. Smid, S. Gao et al., Behavior of Alloying Elements during Anodizing of Mg-Cu and Mg-W Alloys in a Fluoride/Glycerol Electrolyte, vol.162, pp.487-494, 2015.

A. Martín, A. Menéndez, R. Pereiro, N. Bordel, and A. Sanz-medel, Modifying argon glow discharges by hydrogen addition: Effects on analytical characteristics of optical emission and mass spectrometry detection modes, Anal. Bioanal. Chem, vol.388, pp.1573-1582, 2007.

I. S. Molchan, G. E. Thompson, P. Skeldon, N. Trigoulet, P. Chapon et al.,

L. Malherbe, N. Revilla, P. Bordel, T. Belenguer, A. Nelis et al.,

M. Guillot, J. Ganciu, M. Michler, and . Hohl, The concept of plasma cleaning in glow discharge spectrometry, J. Anal. At. Spectrom, vol.24, pp.734-741, 2009.

S. Cremel, E. Gadatek, and P. Chapon, Breakthrough on GDOES Analysis Applied to Rough Metal Surfaces, p.38, 2016.

V. Hodoraba, Wasserstoffeffekt und -analyse in der GDS -Anwendungen in der Werkstoffforschung ( Hydrogen Effect and Analysis in GDS -Applications in Material Science ), 2002.

L. Rossrucker, A. Samaniego, J. Grote, A. M. Mingers, C. A. Laska et al., The pH Dependence of Magnesium Dissolution and Hydrogen Evolution during Anodic Polarization, J. Electrochem. Soc, vol.162, pp.333-339, 2015.

N. Birbilis, G. Williams, K. Gusieva, A. Samaniego, M. A. Gibson et al., Poisoning the corrosion of magnesium, Electrochem. Commun, vol.34, pp.295-298, 2013.

W. Fürbeth and M. Stratmann, The delamination of polymeric coatings from electrogalvanised steel -a mechanistic approach, Corros. Sci, vol.43, pp.207-227, 2001.

I. Puigdomenech, MEDUSA (Chemical Equilibrium Diagrams), 2010.

D. Schloffer, S. Bozorgi, P. Sherstnev, C. Lenardt, and B. Gollas, Manufacturing and characterization of magnesium alloy foils for use as anode materials in rechargeable magnesium ion batteries, J. Power Sources, vol.367, pp.138-144, 2017.

H. Hornberger, S. Virtanen, and A. R. Boccaccini, Biomedical coatings on magnesium alloys -A review, Acta Biomater, vol.8, pp.2442-2455, 2012.

Y. Zhang, J. Xu, Y. C. Ruan, M. K. Yu, M. O'laughlin et al.,

J. Shi, S. Wang, J. Q. Chen, D. H. Feng, X. Chow et al.,

L. Zheng and . Qin, Implant-derived magnesium induces local neuronal production of CGRP to improve bone-fracture healing in rats, Nat. Med, vol.22, pp.1160-1169, 2016.

J. Gonzalez, R. Q. Hou, E. P. Nidadavolu, R. Willumeit-römer, and F. Feyerabend, Magnesium degradation under physiological conditions -Best practice, Bioact. Mater, vol.3, pp.174-185, 2018.

M. A. Deyab, Decyl glucoside as a corrosion inhibitor for magnesium-air battery, J. Power Sources, vol.325, pp.98-103, 2016.

F. W. Richey, B. D. Mccloskey, and A. C. Luntz, Mg Anode Corrosion in Aqueous Electrolytes and Implications for Mg-Air Batteries, J. Electrochem. Soc, vol.163, pp.958-963, 2016.

M. Deng, D. Höche, S. V. Lamaka, D. Snihirova, and M. L. Zheludkevich, Mg-Ca binary alloys as anodes for primary Mg-air batteries, J. Power Sources, vol.396, pp.109-118, 2018.

D. Höche, S. V. Lamaka, B. Vaghefinazari, T. Braun, R. P. Petrauskas et al., Performance boost for primary magnesium cells using iron complexing agents as electrolyte additives, Sci. Rep, vol.8, pp.1-9, 2018.

M. Yuasa, X. Huang, K. Suzuki, M. Mabuchi, and Y. Chino, Discharge properties of Mg-Al-Mn-Ca and Mg-Al-Mn alloys as anode materials for primary magnesium-air batteries, J. Power Sources, vol.297, pp.449-456, 2015.

A. Alamdari, M. R. Rahimpour, N. Esfandiari, and E. Nourafkan, Kinetics of magnesium hydroxide precipitation from sea bittern, Chem. Eng. Process. Process Intensif, vol.47, pp.215-221, 2008.

W. F. Murphy and H. J. Bernstein, Raman Spectra and an Assignment of the Vibrational Stretching Region of Water, J. Phys. Chem, vol.76, pp.1147-1152, 1971.

B. Humbert, M. Alnot, and F. Quilès, Infrared and Raman spectroscopical studies of salicylic and salicylate derivatives in aqueous solution, Spectrochim. Acta -Part A Mol
URL : https://hal.archives-ouvertes.fr/hal-01935302

, Biomol. Spectrosc, vol.54, pp.465-476, 1998.

M. C. Alvarez-ros, S. Sánchez-cortés, and J. V. García-ramos, Vibrational study of the salicylate interaction with metallic ions and surfaces, Spectrochim. Acta -Part A Mol

, Biomol. Spectrosc, vol.56, pp.2471-2477, 2000.

D. Philip, A. John, C. Y. Panicker, H. T. Varghese, and . Ft-raman, FT-IR and surface enhanced Raman scattering spectra of sodium salicylate, Spectrochim. Acta -Part A

, Mol. Biomol. Spectrosc, vol.57, pp.1561-1566, 2001.

M. A. Elbagerma, G. Azimi, H. G. Edwards, A. I. Alajtal, and I. J. Scowen, In situ monitoring of pH titration by Raman spectroscopy, Spectrochim. Acta -Part A Mol

, Biomol. Spectrosc, vol.75, pp.1403-1410, 2010.

P. J. Goulet and R. F. Aroca, Chemical adsorption of salicylate on silver -A systematic approach to the interpretation of surface-enhanced vibrational spectra, Can. J. Chem, vol.82, pp.987-997, 2004.

E. C. Yost, M. I. Tejedortejedor, and M. A. Anderson, Insitu cir-ftir characterization of salicylate complexes at the goethite aqueous-solution interface, Environ. Sci. Technol, vol.24, pp.822-828, 1990.

G. ?widerski, M. Kalinowska, I. Rusinek, M. Samsonowicz, Z. Rz?czy?ska et al., Spectroscopic (IR, Raman) and thermogravimetric studies of 3d-metal cinchomeronates and dinicotinates, J. Therm. Anal. Calorim, vol.126, pp.1521-1532, 2016.

M. Karabacak, S. Bilgili, and A. Atac, Molecular structure investigation of neutral, dimer and anion forms of 3,4-pyridinedicarboxylic acid: A combined experimental and theoretical study, Spectrochim. Acta -Part A Mol. Biomol. Spectrosc, vol.135, pp.270-282, 2015.

L. Wasylina, E. Kucharska, Z. Weglinski, and A. Puszko, Chemistry of Heterocyclic Compounds, vol.35, pp.210-218, 1999.

Y. Song, X. Wang, S. Zhang, J. Wang, S. Gao et al., Lanthanide-Coordination Polymers with Pyridinedicarboxylic Acids : Syntheses , Structures , and Luminescent Properties, pp.681-691, 2016.

I. L. Ardelean, L. B. Stoencea, D. Ficai, A. Ficai, R. Trusca et al., , p.161

E. Andronescu, Development of Stabilized Magnetite Nanoparticles for Medical Applications, J. Nanomater, p.2017, 2017.

S. R. Ryu, I. Noda, and Y. M. Jung, Positional Fluctuation of IR Absorption Peaks: Frequency Shift of a Single Band or Relative Intensity Changes of Overlapped Bands, Am. Lab, vol.43, pp.40-43, 2011.

S. O. Ryu, I. Noda, and Y. M. Jung, What is the Origin of Positional Fluctuation of Spectral Features : True Frequency Shift or Relative Intensity Changes of Two Overlapped Bands ?, vol.64, pp.1017-1021, 2010.

L. Pan, T. Frydel, M. B. Sander, X. Huang, and J. Li, The Effect of pH on the Dimensionality of Coordination Polymers, pp.1271-1283, 2001.

M. C. Das, S. K. Ghosh, E. C. Sañudo, and P. K. Bharadwaj, Coordination polymers with pyridine-2,4,6-tricarboxylic acid and alkaline-earth/lanthanide/transition metals: Synthesis and X-ray structures, J. Chem. Soc. Dalt. Trans, pp.1644-1658, 2009.

B. Ay, N. Do?an, E. Yildiz, and I. Kani, A novel three dimensional samarium(III) coordination polymer with an unprecedented coordination mode of the 2,5-pyridinedicarboxylic acid ligand: Hydrothermal synthesis, crystal structure and luminescence property, Polyhedron, vol.88, pp.176-181, 2015.

S. Caglar, E. Dilek, S. H. Alisir, and B. Caglar, New copper ( II ) complexes including pyridine-2 , 5-dicarboxylic acid : synthesis , spectroscopic , thermal properties , crystal structure and how these complexes interact with purified PON 1 enzyme, p.8972, 2016.

R. K. Vakiti, B. D. Garabato, N. P. Schieber, M. J. Rucks, Y. Cao et al., Synthesis and Characterization of Two-and Three-Dimensional Calcium Coordination Polymers Built with Benzene-1 , 3 , 5-tricarboxylate and / or Pyrazine-2-carboxylate, 2012.

, Appendices This part of dissertation presents complementary results which were obtained during PhD study, vol.164

T. B. Abbott, Magnesium: Industrial and Research Developments Over the Last 15

, Corrosion, vol.71, pp.120-127, 2015.

F. W. Bach, M. Schaper, and C. Jaschik, Influence of Lithium on hcp Magnesium Alloys, Materials Science Forum, pp.1037-1030, 2003.

R. Ninomiya and K. Miyake, A study of superlight and superplastic Mg-Li based alloys, Journal of Japan Institute of Light Metals, vol.51, pp.509-513, 2001.

H. Haferkamp, R. Boehm, U. Holzkamp, C. Jaschik, V. Kaese et al.,

, Processing and Applications in Magnesium Lithium Alloys, Materials Transactions, vol.42, pp.1160-1166, 2001.

A. M. Russell, L. S. Chumbley, V. B. Gantovnik, K. Xu, Y. Tian et al., Anomalously high impact fracture toughness in B.C.C. Mg-Li between 4.2K and 77K, Scripta Materialia, vol.39, pp.1663-1667, 1998.

D. K. Xu, T. T. Zu, M. Yin, Y. B. Xu, and E. H. Han, Mechanical properties of the icosahedral phase reinforced duplex Mg-Li alloy both at room and elevated temperatures, Journal of Alloys and Compounds, vol.582, pp.161-166, 2014.

C. Yang, T. Lui, L. Chen, and H. Hung, Tensile mechanical properties and failure behaviors with the ductile-to-brittle transition of the ?+?-type Mg-Li-Al-Zn alloy, Scripta Materialia, pp.1141-1144, 2009.

W. A. Counts, M. Friák, D. Raabe, and J. Neugebauer, Using ab initio calculations in designing bcc Mg-Li alloys for ultra-lightweight applications, Acta Materialia, vol.57, pp.69-76, 2009.

J. Song, T. Wen, and J. Wang, Vibration fracture properties of a lightweight Mg-Li-Zn alloy, Scripta Materialia, vol.56, pp.529-532, 2007.

E. Ghali, W. Dietzel, and K. Kainer, General and localized corrosion of magnesium alloys: A critical review, J. of Materi Eng and Perform, vol.13, pp.7-23, 2004.

A. A. Nayeb-hashemi and J. B. Clark,

, Phase diagrams of binary magnesium alloys, pp.184-194, 1988.

Y. Song, D. Shan, R. Chen, and E. H. Han, Corrosion characterization of Mg-8Li alloy in NaCl solution, Corrosion Science, vol.51, pp.1087-1094, 2009.

P. D. Frost, F. W. Fink, H. A. Pray, and J. H. Jackson,

, Atmosphere Corrosion Tests on Magnesium Lithium Alloys, Journal of The Electrochemical Society, vol.102, pp.215-218, 1955.

W. Xu, N. Birbilis, G. Sha, Y. Wang, J. E. Daniels et al., A highspecific-strength and corrosion-resistant magnesium alloy, Nature Materials, vol.14, pp.1229-1235, 2015.

K. Gusieva, C. H. Davies, J. R. Scully, and N. Birbilis, Corrosion of magnesium alloys: the role of alloying, International Materials Reviews, vol.60, pp.169-194, 2015.

M. Esmaily, J. E. Svensson, S. Fajardo, N. Birbilis, G. S. Frankel et al.,

S. Arrabal, L. G. Thomas, and . Johansson, Fundamentals and advances in magnesium alloy corrosion, Progress in Materials Science, vol.89, pp.92-193, 2017.

R. W. Revie, H. H. Uhlig-;-r, L. Zeng, Y. F. Sun, H. Z. Zheng et al., Corrosion and characterisation of dual phase Mg-Li-Ca alloy in Hank's solution: The influence of microstructural features, Corrosion Science, vol.79, pp.69-82, 2008.

M. C. Lin, C. Y. Tsai, and J. Y. Uan, Electrochemical behaviour and corrosion performance of Mg-Li-Al-Zn anodes with high Al composition, Corrosion Science, vol.51, pp.2463-2472, 2009.

F. Witte, V. Kaese, H. Haferkamp, E. Switzer, A. Meyer-lindenberg et al.,

H. Windhagen, In vivo corrosion of four magnesium alloys and the associated bone response, Biomaterials, vol.26, pp.3557-3563, 2005.

L. Hou, M. Raveggi, X. Chen, W. Xu, K. J. Laws et al., Investigating the Passivity and Dissolution of a Corrosion Resistant Mg-33at

, Aqueous Chloride Using Online ICP-MS, Journal of The Electrochemical Society, vol.163, pp.324-329, 2016.

Y. Song, D. Shan, R. Chen, and E. H. Han, Investigation of surface oxide film on magnesium lithium alloy, Journal of Alloys and Compounds, vol.484, pp.585-590, 2009.

B. Lafuente, R. T. Downs, H. Yang, and N. Stone, The power of databases: The RRUFF project, Highlights in Mineralogical Crystallography, 2015.

M. V. Kral, B. C. Muddle, and J. F. Nie, Crystallography of the bcc/hcp transformation in a Mg-8Li alloy, vol.460, pp.227-232, 2007.

B. Liu, M. Zhang, and R. Wu, Effects of Nd on microstructure and mechanical properties of as-cast LA141 alloys, Materials Science and Engineering: A, vol.487, pp.347-351, 2008.

C. Ke, Y. Wu, Y. Qiu, J. Duan, N. Birbilis et al., Influence of surface chemistry on the formation of crystalline hydroxide coatings on Mg alloys in liquid water and steam systems, Corrosion Science, vol.113, pp.145-159, 2016.

J. H. Nordlien, S. Ono, N. Masuko, and K. Nisancioglu, A TEM investigation of naturally formed oxide films on pure magnesium, Corrosion Science, vol.39, pp.1397-1414, 1997.

M. Taheri, R. C. Phillips, J. R. Kish, and G. A. Botton, Analysis of the surface film formed on Mg by exposure to water using a FIB cross-section and STEM-EDS, Corrosion Science, pp.222-228, 2012.

J. H. Nordlien, K. Nisancioglu, S. Ono, and N. Masuko, Morphology and Structure

, Water Formed Oxides on Ternary MgAl Alloys, Journal of The Electrochemical Society, vol.144, pp.461-466, 1997.

M. Shahabi-navid, M. Esmaily, J. Svensson, M. Halvarsson, L. Nyborg et al.,

L. Cao and . Johansson, NaCl-Induced Atmospheric Corrosion of the MgAl Alloy AM50-The Influence of CO2, Journal of The Electrochemical Society, vol.161, pp.277-287, 2014.

A. Botha and C. A. Strydom, Preparation of a magnesium hydroxy carbonate from magnesium hydroxide, Hydrometallurgy, vol.62, pp.175-183, 2001.

R. C. Phillips and J. R. Kish, Nature of Surface Film on Matrix Phase of Mg Alloy AZ80 Formed in Water, Corrosion, pp.813-820, 2013.

A. Pardo, M. C. Merino, A. E. Coy, R. Arrabal, F. Viejo et al., Corrosion behaviour of magnesium/aluminium alloys in 3.5 wt.% NaCl, vol.50, pp.823-834, 2008.

J. H. Nordlien, K. Ni?ancio?u, S. Ono, and N. Masuko, Morphology and Structure

, Oxide Films Formed on MgAl Alloys by Exposure to Air and Water, Journal of The Electrochemical Society, vol.143, pp.2564-2572, 1996.

G. R. Williams and D. O'hare, A Kinetic Study of the Intercalation of Lithium Salts into Al(OH)3, The Journal of Physical Chemistry B, vol.110, pp.10619-10629, 2006.

P. Visser, Y. Gonzalez-garcia, J. M. Mol, and H. Terryn, Mechanism of Passive Layer Formation on AA2024-T3 from Alkaline Lithium Carbonate Solutions in the Presence of Sodium Chloride, Journal of The Electrochemical Society, vol.165, pp.60-70, 2018.

P. Visser, Y. Liu, X. Zhou, T. Hashimoto, G. E. Thompson et al., The corrosion protection of AA2024-T3 aluminium alloy by leaching of lithium-containing salts from organic coatings, Faraday Discussions, p.180

C. Q. Li, D. K. Xu, X. Chen, B. J. Wang, R. Z. Wu et al., Composition and microstructure dependent corrosion behaviour of Mg-Li alloys, Electrochimica Acta, vol.260, pp.55-64, 2018.

Y. W. Song, D. Y. Shan, R. S. Chen, and E. H. Han, Corrosion resistance of Mg-8.8Li alloy compared with AZ91, vol.46, p.719, 2011.

(. Brucite and . Mg, , vol.2, p.3695

M. Hydrocalcites,

. Nesquehonite, , p.1525

, Magnesite (MgCO, vol.3, p.1445

M. Hydrocalcites, Mg x Zn 6-x Al 2 (OH) 16 CO 3 Á4H 2 O), vol.495, p.1061

. Magnesite, , vol.216, p.1091

, AlO 6 -groups in gels, pp.505-515

N. Benzekri, M. Keddam, and H. Takenouti, AC responce of a rotating ring-disk electrode: application to 2-D and 3-D film formation in anodic processes, Electrochim. Acta, vol.34, pp.1159-1166, 1989.

T. T. Tran, B. Tribollet, and E. M. Sutter, New insights into the cathodic dissolution of aluminium using electrochemical methods, Electrochim. Acta, vol.216, pp.58-67, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01394958

A. D. King, N. Birbilis, and J. R. Scully, Accurate Electrochemical Measurement of Magnesium Corrosion Rates; a Combined Impedance, Mass-Loss and Hydrogen Collection Study, Electrochim. Acta, vol.121, pp.394-406, 2014.

G. Galicia, N. Pébère, B. Tribollet, and V. Vivier, Local and global electrochemical impedances applied to the corrosion behaviour of an AZ91 magnesium alloy, Corros. Sci, vol.51, pp.1789-1794, 2009.

B. Tribollet and M. E. Orazem, Electrochemical Impedance Spectroscopy, 2008.

G. Baril and N. Pebere, The corrosion of pure magnesium in aerated and deaerated sodium sulphate solutions, Corros. Sci, vol.43, pp.471-484, 2001.

S. Thomas, N. Birbilis, M. S. Venkatraman, and I. S. Cole, Corrosion of Zinc as a Function of pH, Corrosion, vol.68, pp.15009-15010, 2012.

L. Jiang, P. Volovitch, M. Wolpers, and K. Ogle, Activation and inhibition of Zn-Al and Zn-Al-Mg coatings on steel by nitrate in phosphoric acid solution, Corros. Sci, vol.60, pp.256-264, 2012.

J. Rodriguez, L. Chenoy, A. Roobroeck, S. Godet, and M. Olivier, Effect of the electrolyte pH on the corrosion mechanisms of Zn-Mg coated steel, Corros. Sci, vol.108, pp.47-59, 2016.

S. Tanaka, K. Honda, Y. Takahashi, Y. Morimoto, M. Kurosaki et al., The performance of Zn-Al-Mg-Si hot-dip galvanized steel sheet, Proc Galvatech '01, Int. Conf. Zinc Zinc Alloy Coat. Steel, pp.153-160, 2001.

K. Nishimura, H. Shindo, K. Kato, and Y. Morimoto, Microstructure and corrosion behavior of Zn-Mg-Al hot dip galvanized steel sheet, Proc Galvatech '98, Int. Conf. Zinc Zinc Alloy Coat. Steel, pp.437-442, 1998.

T. Tsujimura, A. Komatsu, and A. Andoh, Influence of Mg content in coating layer and coating structure on corrosion resistance of hot-dip Zn-Al-Mg alloy coated steel sheet, Proc Galvatech '01, Int. Conf. Zinc Zinc Alloy Coat. Steel, pp.145-152, 2001.

S. Schürz, G. H. Luckeneder, M. Fleischanderl, P. Mack, H. Gsaller et al., Chemistry of corrosion products on Zn-Al-Mg alloy coated steel, vol.52, pp.3271-3279, 2010.

M. Dutta, A. K. Halder, and S. B. Singh, Morphology and properties of hot dip Zn-Mg and Zn-Mg-Al alloy coatings on steel sheet, Surf. Coatings Technol, vol.205, pp.2578-2584, 2010.

S. Schuerz, M. Fleischanderl, G. H. Luckeneder, K. Preis, T. Haunschmied et al., Corrosion behaviour of Zn-Al-Mg coated steel sheet in sodium chloride-containing environment, Corros. Sci, vol.51, pp.2355-2363, 2009.

P. Volovitch, C. Allely, and K. Ogle, Understanding corrosion via corrosion product characterization: I. Case study of the role of Mg alloying in Zn-Mg coating on steel, Corros. Sci, vol.51, pp.1251-1262, 2009.

D. Persson, D. Thierry, N. Lebozec, and T. Prosek, In situ infrared reflection spectroscopy studies of the initial atmospheric corrosion of Zn-Al-Mg coated steel, Corros. Sci, vol.72, pp.54-63, 2013.

T. Prosek, A. Nazarov, U. Bexell, D. Thierry, and J. Serak, Corrosion mechanism of model zinc-magnesium alloys in atmospheric conditions, Corros. Sci, vol.50, pp.2216-2231, 2008.

M. Azevedo, C. Allély, K. Ogle, and P. Volovitch, Corrosion mechanisms of Zn(Mg,Al) coated steel: 2. The effect of Mg and Al alloying on the formation and properties of corrosion products in different electrolytes, Corros. Sci, vol.90, pp.482-490, 2015.

T. Prosek, J. Hagstrom, D. Persson, N. Fuertes, F. Lindberg et al., Effect of the microstructure of Zn-Al and Zn-Al-Mg model alloys on corrosion stability, Corros. Sci, 2016.

M. Morishita, K. Koyama, and Y. Mori, Inhibition of anodic dissolution ofzinc-plated steel by electro-deposition of magnesium from a molten salt, ISIJ Int, vol.95, pp.447-455, 2004.

R. Hausbrand, M. Rohwerder, M. Stratmann, C. Scherdt, B. Schuhmacher et al., Model study on the corrosion of magnesium-containing zinc coating on steel sheets, Proc Galvatech '01, Int. Conf. Zinc Zinc Alloy Coat. Steel, pp.161-167, 2001.

T. Prosek, D. Persson, J. Stoulil, and D. Thierry, Composition of corrosion products formed on Zn-Mg, Zn-Al and Zn-Al-Mg coatings in model atmospheric conditions, Corros. Sci, vol.86, pp.231-238, 2014.

M. Azevedo, C. Allély, K. Ogle, and P. Volovitch, Corrosion mechanisms of Zn(Mg, Al) coated steel in accelerated tests and natural exposure: 1. The role of electrolyte composition in the nature of corrosion products and relative corrosion rate, Corros. Sci, vol.90, pp.472-481, 2015.

F. Thébault, B. Vuillemin, R. Oltra, C. Allely, K. Ogle et al., Influence of magnesium content on the corrosion resistance of the cut-edges of Zn ÀMgcoated steel, vol.97, pp.100-106, 2015.

S. O. Klemm, J. Schauer, B. Schuhmacher, and A. W. Hassel, High throughput electrochemical screening and dissolution monitoring of Mg-Zn material libraries, Electrochim. Acta, vol.56, pp.9627-9636, 2011.

E. Diler, S. Rioual, B. Lescop, D. Thierry, and B. Rouvellou, Chemistry of corrosion products of Zn and MgZn pure phases under atmospheric conditions, Corros. Sci, vol.65, pp.178-186, 2012.

R. Krieg, M. Rohwerder, S. Evers, B. Schuhmacher, and J. Schauer-pass, Cathodic self-healing at cut-edges: The effect of Zn 2+ and Mg 2+ ions, Corros. Sci, vol.65, pp.119-127, 2012.

N. Lebozec, D. Thierry, M. Rohwerder, D. Persson, G. Luckeneder et al., Effect of carbon dioxide on the atmospheric corrosion of Zn-Mg-Al coated steel, Corros. Sci, vol.74, pp.379-386, 2013.

N. C. Hosking, M. A. Ström, P. H. Shipway, and C. D. Rudd, Corrosion resistance of zincmagnesium coated steel, Corros. Sci, vol.49, pp.3669-3695, 2007.

P. Volovitch, T. N. Vu, C. Allély, A. Abdel, and K. Ogle, Understanding corrosion via corrosion product characterization: II. Role of alloying elements in improving the corrosion resistance of Zn-Al-Mg coatings on steel, Corros. Sci, vol.53, pp.2437-2445, 2011.

T. Ishikawa, M. Ueda, K. Kandori, and T. Nakayama, Air permeability of the artificially synthesized Zn-Al-Mg alloy rusts, Corros. Sci, vol.49, pp.2547-2556, 2007.

J. Duchoslav, R. Steinberger, M. Arndt, T. Keppert, G. Luckeneder et al., Evolution of the surface chemistry of hot dip galvanized Zn-Mg-Al and Zn coatings on steel during short term exposure to sodium chloride containing environments, Corros. Sci, vol.91, pp.311-320, 2015.

M. Azevedo, C. Allely, K. Ogle, and P. Volovitch, Corrosion mechanisms of Zn(Mg,Al) coated steel: The effect of HCO 3 À and N H 4 + ions on the intrinsic reactivity of the coating, Electrochim. Acta, vol.153, pp.159-169, 2015.

K. Ogle and S. Weber, Anodic Dissolution of 304 Stainless Steel Using Atomic Emission Spectroelectrochemistry, J. Electrochem. Soc, vol.147, p.1770, 2000.

V. Shkirskiy and K. Ogle, A novel coupling of electrochemical impedance spectroscopy with atomic emission spectroelectrochemistry: Application to the open circuit dissolution of zinc, Electrochim. Acta, vol.168, pp.167-172, 2015.

K. Ogle, M. Serdechnova, M. Mokaddem, and P. Volovitch, The cathodic dissolution of Al, Al 2 Cu, and Al alloys, Electrochim. Acta, vol.56, 2011.

S. M. Moon and S. Pyun, The corrosion of pure aluminium uring cathodic ploarization in aqeous solutions, Corros. Sci, vol.39, pp.399-408, 1997.

B. P. Caldwell and V. J. Alano, Rates of solution of zinc and aluminum while cathodic, Trans. Electrochem. Soc, vol.76, p.271, 1939.

M. Serdechnova, P. Volovitch, F. Brisset, and K. Ogle, On the cathodic dissolution of Al and Al alloys, Electrochim. Acta, 2013.

M. Mokaddem, P. Volovitch, F. Rechou, R. Oltra, and K. Ogle, The anodic and cathodic dissolution of Al and Al-Cu-Mg alloy, Electrochim. Acta, vol.55, pp.3779-3786, 2010.

S. Thomas, N. V. Medhekar, G. S. Frankel, and N. Birbilis, Corrosion mechanism and hydrogen evolution on Mg, Curr. Opin. Solid State Mater. Sci, vol.19, pp.85-94, 2015.

J. T. Kloprogge, L. Hickey, and R. L. Frost, FT-Raman and FT-IR spectroscopic study of synthetic Mg/Zn/Al-hydrotalcites, J. Raman Spectrosc, vol.35, pp.967-974, 2004.

M. C. Bernard, A. Hugot-le-goff, D. Massinon, and N. Phillips, Underpaint corrosion of zinc-coated steel sheet studied by in situ raman spectroscopy, Corros. Sci, vol.35, pp.1339-1349, 1993.

S. Xu, M. Liao, H. Zeng, X. Liu, J. Du et al., Surface modification and dissolution behavior of Mg-Al hydrotalcite particles, J. Taiwan Inst. Chem. Eng, vol.56, pp.174-180, 2015.

O. F. Lopes, V. R. De-mendonça, A. Umar, M. S. Chuahan, R. Kumar et al., Zinc hydroxide/oxide and zinc hydroxy stannate photocatalysts as potential scaffolds for environmental remediation, New J. Chem, pp.4624-4630, 2015.

V. Russo, M. Ghidelli, P. Gondoni, C. S. Casari, and A. L. Bassi, Multi-wavelength Raman scattering of nanostructured Al-doped zinc oxide, J. Appl. Phys, vol.115, pp.1-10, 2014.

Y. Chen, P. Schneider, B. Liu, S. Borodin, B. Ren et al., Electronic structure and morphology of dark oxides on zinc generated by electrochemical treatment, Phys. Chem. Chem. Phys, vol.15, pp.9812-9822, 2013.

P. V. Thomas, V. Ramakrishnan, and V. K. Vaidyan, Oxidation studies of aluminum thin films by Raman spectroscopy, Thin Solid Films, vol.170, pp.90619-90625, 1989.

D. Wang, L. M. Hamm, R. J. Bodnar, and P. M. Dove, Raman spectroscopic characterization of the magnesium content in amorphous calcium carbonates, J. Raman Spectrosc, vol.43, pp.543-548, 2012.

N. S. Azmat, K. D. Ralston, B. C. Muddle, and I. S. Cole, Corrosion of Zn under acidified marine droplets, Corros. Sci, vol.53, pp.1604-1615, 2011.

R. L. Frost, W. N. Martens, and K. L. Erickson, Thermal decomposition of the hydrotalcite: Thermogravimetric analysis and hot stage Raman spectroscopic study, J. Therm. Anal. Calorim, vol.82, pp.603-608, 2005.

B. Lafuente, R. T. Downs, H. Yang, and N. Stone, The power of databases: The RRUFF project, 2016.

S. R. Soniya and V. M. Nair, Synthesis and Characterization of Nanostructured Mg (OH)2 and MgO, Int. J. Sci. Res, vol.5, pp.197-203, 2016.

S. F. Agnew and J. R. Schoonover, Microstructural Properties of High Level Waste Concentrates and Gels with Raman and Infrared Spectroscopies, 1996.

I. Puigdomenech, Hydra/Medusa Chemical Equilibrium Database and Plotting Software KTH Royal Institute of Technology

R. L. David, Handbook of Chemistry and Physics, 2003.

K. Ogle, A. Tomandl, and N. Meddahi, In situ monitoring of dissolutionprecipitation mechanisms using coupled quartz crystal microbalance/ atomic emission spectroelectrochemistry, Innov. Pre-Treatment Tech. to Prev. Corros. Met. Surfaces, pp.158-172, 2007.

E. Samson, J. Marchand, and K. A. Snyder, Calculation of ionic diffusion coefficients on the basis of migration test results, Mater. Struct. Constr, vol.36, pp.156-165, 2003.