J. D. Rule and J. S. Moore, ROMP Reactivity of endo-and exo-Dicyclopentadiene, Macromolecules, vol.35, issue.21, pp.7878-7882, 2002.

K. J. Ivin and J. C. Mol, 1 -Introduction, Olefin Metathesis and Metathesis Polymerization, pp.1-11, 1997.

C. P. Casey, Nobel Prize in Chemistry. Development of the Olefin Metathesis Method in Organic Synthesis, J. Chem. Educ, vol.83, issue.2, p.192, 2005.

C. W. Bielawski and R. H. Grubbs, Living ring-opening metathesis polymerization, Progress in Polymer Science, vol.32, issue.1, pp.1-29, 2007.

N. Calderon, Olefin metathesis reaction, Acc. Chem. Res, vol.5, issue.4, pp.127-132, 1972.

O. Nuyken and S. Pask, Ring-opening polymerization-an introductory review, Polymers, vol.5, issue.2, pp.361-403, 2013.

T. Davidson, K. Wagener, and D. Priddy, Polymerization of dicyclopentadiene: a tale of two mechanisms, Macromolecules, vol.29, issue.2, pp.786-788, 1996.

P. J. -l.-hérisson and Y. Chauvin, Catalyse de transformation des oléfines par les complexes du tungstène. II. Télomérisation des oléfines cycliques en présence d'oléfines acycliques, Die Makromolekulare Chemie, vol.141, issue.1, pp.161-176, 1971.

T. Davidson and K. Wagener, The polymerization of dicyclopentadiene: an investigation of mechanism, Journal of Molecular Catalysis A: Chemical, vol.133, issue.1-2, pp.67-74, 1998.

S. Hilf and A. F. Kilbinger, Functional end groups for polymers prepared using ringopening metathesis polymerization, Nature Chemistry, vol.1, issue.7, pp.537-546, 2009.

A. Leitgeb, J. Wappel, and C. Slugovc, The ROMP toolbox upgraded, Polymer, vol.51, issue.14, pp.2927-2946, 2010.

S. Sutthasupa, M. Shiotsuki, and F. Sanda, Recent advances in ring-opening metathesis polymerization and application to synthesis of functional materials, Polymer Journal, vol.42, issue.12, pp.905-915, 2010.

W. R. Gutekunst and C. J. Hawker, A General Approach to Sequence-Controlled Polymers Using Macrocyclic Ring Opening Metathesis Polymerization, J. Am. Chem. Soc, vol.137, issue.25, pp.8038-8041, 2015.

R. R. Schrock, J. S. Murdzek, G. C. Bazan, J. Robbins, M. Dimare et al., Synthesis of molybdenum imido alkylidene complexes and some reactions involving acyclic olefins, Journal of the American Chemical Society, vol.112, issue.10, pp.3875-3886, 1990.

J. Heppekausen and A. Fürstner, Rendering Schrock-type Molybdenum Alkylidene Complexes Air Stable: User-Friendly Precatalysts for Alkene Metathesis, Angewandte Chemie International Edition, vol.50, issue.34, pp.7829-7832, 2011.

P. Schwab, M. B. France, J. W. Ziller, and R. H. Grubbs, A Series of Well-Defined Metathesis Catalysts-Synthesis of

, Angewandte Chemie International Edition in English, vol.34, issue.18, pp.2039-2041, 1995.

P. Schwab, R. H. Grubbs, and J. W. Ziller, Synthesis and Applications of RuCl2(CHR')(PR3)2: The Influence of the Alkylidene Moiety on Metathesis Activity, J. Am. Chem. Soc, vol.118, issue.1, pp.100-110, 1996.

M. Scholl, S. Ding, C. W. Lee, and R. H. Grubbs, Synthesis and activity of a new generation of ruthenium-based olefin metathesis catalysts coordinated with 1, 3-dimesityl-4, 5-dihydroimidazol-2-ylidene ligands, Organic Letters, vol.1, issue.6, pp.953-956, 1999.

B. F. Straub, Origin of the High Activity of Second-Generation Grubbs Catalysts

, Angewandte Chemie International Edition, vol.44, issue.37, pp.5974-5978, 2005.

T. Choi and R. H. Grubbs, Controlled Living Ring-Opening-Metathesis Polymerization by a Fast-Initiating Ruthenium Catalyst, Angewandte Chemie, vol.115, issue.15, pp.1785-1788, 2003.

S. Monsaert, A. L. Vila, R. Drozdzak, P. V. Voort, and F. Verpoort, Latent olefin metathesis catalysts, Chemical Society Reviews, vol.38, issue.12, pp.3360-3372, 2009.

E. M. Hoàng, N. S. Allen, C. M. Liauw, E. Fontán, and P. Lafuente, The thermooxidative degradation of metallocene polyethylenes. Part 1: long-term thermal oxidation in the solid state, Polymer degradation and stability, vol.91, issue.6, pp.1356-1362, 2006.

P. Gijsman, J. Hennekens, and J. Vincent, The influence of temperature and catalyst residues on the degradation of unstabilized polypropylene, Polymer Degradation and Stability, vol.39, issue.3, pp.271-277, 1993.

J. Asrar, Reaction injection molding (RIM) system based on metathesis, Journal of Applied Polymer Science, vol.47, issue.2, pp.289-293, 1993.

C. Slugovc, Industrial applications of olefin metathesis polymerization, Olefin Metathesis: Theory and Practice, pp.329-333, 2014.

P. Y. Le-gac, D. Choqueuse, M. Paris, G. Recher, C. Zimmer et al., Durability of polydicyclopentadiene under high temperature, high pressure and seawater (offshore oil production conditions), Polymer Degradation and Stability, vol.98, issue.3, pp.809-817, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00961264

Y. Hu, Y. Zhang, and S. Nutt, Thermal oxidation aging of polydicyclopentadiene and composites, Polymer Composites, vol.39, issue.5, pp.1742-1751, 2018.

T. R. Long, Influence of molecular weight between crosslinks on the mechanical properties of polymers formed via ring-opening metathesis, Soft matter, vol.14, issue.17, pp.3344-3360, 2018.

P. Y. Le-gac, V. L. Saux, M. Paris, and Y. Marco, Ageing mechanism and mechanical degradation behaviour of polychloroprene rubber in a marine environment: Comparison of accelerated ageing and long term exposure, Polymer Degradation and Stability, vol.97, issue.3, pp.288-296, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00703271

K. T. Gillen and R. L. Clough, Rigorous experimental confirmation of a theoretical model for diffusion-limited oxidation, Polymer, vol.33, issue.20, pp.4358-4365, 1992.

S. Wu, Secondary relaxation, brittle-ductile transition temperature, and chain structure, Journal of Applied Polymer Science, vol.46, issue.4, pp.619-624, 1992.

H. L. Bos and J. J. Nusselder, Toughness of model polymeric networks in the glassy state: effect of crosslink density, Polymer, vol.35, issue.13, pp.2793-2799, 1994.

W. D. Cook, A. E. Mayr, and G. H. Edward, Yielding behaviour in model epoxy thermosets -II. Temperature dependence, Polymer, vol.39, issue.16, pp.3725-3733, 1998.

E. D. Crawford and A. J. Lesser, Brittle to ductile: Fracture toughness mapping on controlled epoxy networks, Polymer Engineering & Science, vol.39, issue.2, pp.385-392, 1999.

J. Pascault, H. Sautereau, J. Verdu, and R. J. Williams, Thermosetting polymers, vol.477, 2002.
URL : https://hal.archives-ouvertes.fr/hal-00870591

E. Espuche, J. Galy, J. Gérard, J. Pascault, and H. Sautereau, Influence of crosslink density and chain flexibility on mechanical properties of model epoxy networks, Macromolecular Symposia, vol.93, issue.1, pp.107-115, 1995.

N. Rasoldier, Model systems for thermo-oxidised epoxy composite matrices, Composites Part A: Applied Science and Manufacturing, vol.39, issue.9, pp.1522-1529, 2008.
URL : https://hal.archives-ouvertes.fr/hal-00320015

E. A. Dimarzio, On the second-order transition of a rubber, Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry, vol.68, issue.6, p.611, 1964.

T. G. Fox and S. Loshaek, Influence of molecular weight and degree of crosslinking on the specific volume and glass temperature of polymers, Journal of Polymer Science, vol.15, issue.80, pp.371-390, 1955.

M. C. Celina, Review of polymer oxidation and its relationship with materials performance and lifetime prediction, Polymer Degradation and Stability, vol.98, issue.12, pp.2419-2429, 2013.

R. M. Koerner, A. E. Lord, and Y. H. Hsuan, Arrhenius modeling to predict geosynthetic degradation, Geotextiles and Geomembranes, vol.11, issue.2, pp.151-183, 1992.

P. Richters, Initiation process in the oxidation of polypropylene, Macromolecules, vol.3, issue.2, pp.262-264, 1970.

L. Achimsky, L. Audouin, and J. Verdu, Kinetic study of the thermal oxidation of polypropylene, Polymer Degradation and Stability, vol.57, issue.3, pp.231-240, 1997.

N. Khelidj, X. Colin, L. Audouin, J. Verdu, C. Monchy-leroy et al., Oxidation of polyethylene under irradiation at low temperature and low dose rate. Part II. Low temperature thermal oxidation, Polymer Degradation and Stability, vol.91, issue.7, pp.1598-1605, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00199223

M. Coquillat, J. Verdu, X. Colin, L. Audouin, and R. Nevière, Thermal oxidation of polybutadiene. Part 1: Effect of temperature, oxygen pressure and sample thickness on the thermal oxidation of hydroxyl-terminated polybutadiene, Polymer Degradation and Stability, vol.92, issue.7, pp.1326-1333, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00199759

X. Colin and J. Verdu, Strategy for studying thermal oxidation of organic matrix composites, Composites Science and Technology, vol.65, issue.3-4, pp.411-419, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00110952

E. Richaud, Durabilité des Géotextiles en Polypropylène

J. Bolland and G. Gee, Kinetic studies in the chemistry of rubber and related materials

, The kinetics of oxidation of unconjugated olefins, Transactions of the Faraday Society, vol.42, pp.236-243, 1946.

J. Bolland and G. Gee, Kinetic studies in the chemistry of rubber and related materials

, Thermochemistry and mechanisms of olefin oxidation, Transactions of the Faraday Society, vol.42, pp.244-252, 1946.

L. Audouin, V. Gueguen, A. Tcharkhtchi, and J. Verdu, Close loop' mechanistic schemes for hydrocarbon polymer oxidation, Journal of Polymer Science Part A: Polymer Chemistry, vol.33, issue.6, pp.921-927, 1995.

X. Colin, B. Fayolle, L. Audouin, and J. Verdu, About a quasi-universal character of unstabilised polyethylene thermal oxidation kinetics, Polymer Degradation and Stability, vol.80, issue.1, pp.67-74, 2003.
URL : https://hal.archives-ouvertes.fr/hal-00113813

X. Colin, Aging of polyethylene pipes transporting drinking water disinfected by chlorine dioxide. I. Chemical aspects, Polymer Engineering & Science, vol.49, issue.7, pp.1429-1437, 2009.

A. François-heude, E. Richaud, E. Desnoux, and X. Colin, A general kinetic model for the photothermal oxidation of polypropylene, Journal of Photochemistry and Photobiology A: Chemistry, vol.296, pp.48-65, 2015.

M. Coquillat, J. Verdu, X. Colin, L. Audouin, and R. Nevière, Thermal oxidation of polybutadiene. Part 2: Mechanistic and kinetic schemes for additive-free non-crosslinked polybutadiene, Polymer Degradation and Stability, vol.92, issue.7, pp.1334-1342, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00199759

X. Colin, L. Audouin, and J. Verdu, Kinetic modelling of the thermal oxidation of polyisoprene elastomers. Part 1: Unvulcanized unstabilized polyisoprene, Polymer Degradation and Stability, vol.92, issue.5, pp.886-897, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00199728

P. Y. Le-gac, G. Roux, J. Verdu, P. Davies, and B. Fayolle, Oxidation of unvulcanized, unstabilized polychloroprene: A kinetic study, Polymer Degradation and Stability, vol.109, pp.175-183, 2014.

E. Ernault, E. Richaud, and B. Fayolle, Thermal oxidation of epoxies: Influence of diamine hardener, Polymer Degradation and Stability, vol.134, pp.76-86, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01473986

D. C. Nonhebel, D. C. Nonhebel, J. Walton, and J. C. Walton, Free-radical chemistry: structure and mechanism. CUP Archive, 1974.

M. Coquillat, Vieillissement des propergols à matrice polybutadiène: modélisation cinétique de l'oxydation, 2007.

M. Guyader, L. Audouin, X. Colin, J. Verdu, and S. Chevalier, Epoxides in the thermal oxidation of polybutadiene, Polymer Degradation and Stability, vol.91, issue.11, pp.2813-2815, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00192092

G. A. Russell, Deuterium-isotope Effects in the Autoxidation of Aralkyl Hydrocarbons. Mechanism of the Interaction of PEroxy Radicals 1, Journal of the American Chemical Society, vol.79, issue.14, pp.3871-3877, 1957.

J. A. Howard and K. U. Ingold, Self-reaction of sec-butylperoxy radicals. Confirmation of the Russell mechanism, Journal of the American Chemical Society, vol.90, issue.4, pp.1056-1058, 1968.

E. Richaud, P. Y. Le-gac, and J. Verdu, Thermooxidative aging of polydicyclopentadiene in glassy state, Polymer Degradation and Stability, vol.102, pp.95-104, 2014.
URL : https://hal.archives-ouvertes.fr/hal-00977089

X. Colin, L. Audouin, and J. Verdu, Determination of thermal oxidation rate constants by an inverse method. Application to polyethylene, Polymer Degradation and Stability, vol.86, issue.2, pp.309-321, 2004.
URL : https://hal.archives-ouvertes.fr/hal-00084591

E. Richaud, F. Farcas, P. Bartoloméo, B. Fayolle, L. Audouin et al., Effect of oxygen pressure on the oxidation kinetics of unstabilised polypropylene, Polymer Degradation and Stability, vol.91, issue.2, pp.398-405, 2006.

J. , Chemical and photochemical behaviour of phenolic antioxidants in polymer stabilization-a state of the art report, Part I, Polymer Degradation and Stability, vol.40, issue.2, pp.217-232, 1993.

J. , Chemical and photochemical behaviour of phenolic antioxidants in polymer stabilization: A state of the art report, part II, Polymer Degradation and Stability, vol.39, issue.1, pp.103-115, 1993.

J. , Mechanistic action of phenolic antioxidants in polymers-A review, Polymer Degradation and Stability, vol.20, issue.3-4, pp.181-202, 1988.

P. Gijsman and M. Gitton, Hindered amine stabilisers as long-term heat stabilisers for polypropylene, Polymer Degradation and Stability, vol.66, issue.3, pp.365-371, 1999.

F. L. Gugumus, Polyolefin stabilization: from single stabilizers to complex systems, pp.1-38, 2000.

P. Gijsman, A review on the mechanism of action and applicability of Hindered Amine Stabilizers, Polymer Degradation and Stability, vol.145, pp.2-10, 2017.

T. Toda, E. Mori, and K. Murayama, Studies on Stable Free Radicals. IX. Peroxy Acid Oxidation of Hindered Secondary Amines to Nitroxide Radicals, Bulletin of the chemical society of Japan, vol.45, issue.6, pp.1904-1908, 1972.

D. J. Carlsson, K. H. Chan, and D. M. Wiles, Polypropylene Photostabilization by Tetramethylpiperidine Species, Photodegradation and Photostabilization of Coatings, vol.151, pp.51-63, 1981.

J. Sedlá?, J. Petru?j, J. Pác, and M. Navrátil, Polymer photostabilization by HALS derivatives: the role of piperidine-hydroperoxide association, Polymer, vol.21, issue.1, pp.5-7, 1980.

P. Gijsman, New synergists for hindered amine light stabilizers, Polymer, vol.43, issue.5, pp.1573-1579, 2002.

E. Richaud, X. Colin, C. Monchy-leroy, L. Audouin, and J. Verdu, Polyethylene stabilization against thermal oxidation by a trimethylquinoleine oligomer, Polymer Degradation and Stability, vol.94, issue.3, pp.410-420, 2009.

L. Audouin, V. Langlois, J. Verdu, and J. C. De-bruijn, Role of oxygen diffusion in polymer ageing: kinetic and mechanical aspects, Journal of Materials Science, vol.29, issue.3, pp.569-583, 1994.

M. Celina, J. Wise, D. K. Ottesen, K. T. Gillen, and R. L. Clough, Oxidation profiles of thermally aged nitrile rubber, Polymer Degradation and Stability, vol.60, issue.2-3, pp.493-504, 1998.

M. Celina, J. Wise, D. K. Ottesen, K. T. Gillen, and R. L. Clough, Correlation of chemical and mechanical property changes during oxidative degradation of neoprene, Polymer Degradation and Stability, vol.68, issue.2, pp.171-184, 2000.

M. C. Celina and A. Quintana, Oxygen diffusivity and permeation through polymers at elevated temperature, Polymer, vol.150, pp.326-342, 2018.

V. Defauchy, Kinetic analysis of polydicyclopentadiene oxidation, Polymer Degradation and Stability, vol.142, pp.169-177, 2017.

M. C. Celina, A. R. Dayile, and A. Quintana, A perspective on the inherent oxidation sensitivity of epoxy materials, Polymer, vol.54, issue.13, pp.3290-3296, 2013.

J. S. Arrieta, E. Richaud, B. Fayolle, and F. Nizeyimana, Thermal oxidation of vinyl ester and unsaturated polyester resins, Polymer degradation and stability, vol.129, pp.142-155, 2016.

E. Courvoisier, Y. Bicaba, and X. Colin, Multi-scale and multi-technique analysis of the thermal degradation of poly (ether ether ketone), Polymer degradation and stability, vol.151, pp.65-79, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01825312

M. R. Kessler and S. R. White, Cure kinetics of the ring-opening metathesis polymerization of dicyclopentadiene, Journal of Polymer Science Part A: Polymer Chemistry, vol.40, issue.14, pp.2373-2383, 2002.

J. Huang and G. Rempel, Ziegler-Natta catalysts for olefin polymerization: mechanistic insights from metallocene systems, Progress in Polymer Science, vol.20, issue.3, pp.459-526, 1995.

Z. Osawa, Role of metals and metal-deactivators in polymer degradation, Polymer Degradation and Stability, vol.20, issue.3-4, pp.203-236, 1988.

F. Haber and J. Weiss, On the catalysis of hydroperoxide, Naturwissenschaften, vol.20, issue.51, pp.948-50, 1932.

Z. Osawa, T. Shibamiya, and T. Kawamata, Catalytic action of metallic salts in autoxidation and polymerization. IV. Polymerization of methyl methacrylate by cobalt(II) or (III) acetylacetonate-tert-butyl hydroperoxide or dioxane hydroperoxide, Journal of Polymer Science Part A-1: Polymer Chemistry, vol.8, issue.10, pp.2957-2969, 1970.

J. Barto? and V. Horanská, Radical reactions initiated by chelate complexes of transition metals. VII. Effect of some copper chelates on the decomposition of cumene hydroperoxide in benzene, Die Makromolekulare Chemie, vol.157, issue.1, pp.87-101, 1972.

X. Li and H. Koseki, Thermal decomposition kinetic of liquid organic peroxides, Journal of Loss Prevention in the Process Industries, vol.18, pp.460-464, 2005.

S. Skounas, C. Methenitis, G. Pneumatikakis, and M. Morcellet, Kinetic studies and mechanism of hydrogen peroxide catalytic decomposition by Cu (II) complexes with polyelectrolytes derived from l-alanine and glycylglycine, Bioinorganic chemistry, p.64

V. Defauchy, Kinetic analysis of polydicyclopentadiene oxidation, Polymer Degradation and Stability, vol.142, pp.169-177, 2017.

E. Richaud, F. Farcas, B. Fayolle, L. Audouin, and J. Verdu, Hydroperoxide titration by DSC in thermally oxidized polypropylene, Polymer Testing, vol.25, issue.6, pp.829-838, 2006.

Y. Ouldmetidji, L. Gonon, S. Commereuc, and V. Verney, A differential scanning calorimetry method to study polymer photoperoxidation, Polymer Testing, vol.20, issue.7, pp.765-768, 2001.

E. Richaud, P. Y. Le-gac, and J. Verdu, Thermooxidative aging of polydicyclopentadiene in glassy state, Polymer Degradation and Stability, vol.102, pp.95-104, 2014.
URL : https://hal.archives-ouvertes.fr/hal-00977089

D. J. Carlsson, R. Brousseau, and D. M. Wiles, Reactions of sulfur dioxide with oxidized polyolefins, Polymer Degradation and Stability, vol.15, issue.1, pp.67-79, 1986.

J. Scheirs, D. Carlsson, and S. Bigger, A review of the methods for detecting and characterizing hydroperoxide groups in oxidized polyolefins, Polymer-Plastics Technology and Engineering, vol.34, issue.1, p.116, 1995.

P. Y. Le-gac, D. Choqueuse, M. Paris, G. Recher, C. Zimmer et al., Durability of polydicyclopentadiene under high temperature, high pressure and seawater (offshore oil production conditions), Polymer Degradation and Stability, vol.98, issue.3, pp.809-817, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00961264

E. Richaud, P. Y. Le-gac, and J. Verdu, Thermooxidative aging of polydicyclopentadiene in glassy state, Polymer Degradation and Stability, vol.102, pp.95-104, 2014.
URL : https://hal.archives-ouvertes.fr/hal-00977089

E. Richaud, F. Farcas, P. Bartoloméo, B. Fayolle, L. Audouin et al., Effect of oxygen pressure on the oxidation kinetics of unstabilised polypropylene, Polymer Degradation and Stability, vol.91, issue.2, pp.398-405, 2006.

X. Colin, L. Audouin, and J. Verdu, Determination of thermal oxidation rate constants by an inverse method. Application to polyethylene, Polymer Degradation and Stability, vol.86, issue.2, pp.309-321, 2004.
URL : https://hal.archives-ouvertes.fr/hal-00084591

M. Coquillat, J. Verdu, X. Colin, L. Audouin, and R. Nevière, Thermal oxidation of polybutadiene. Part 2: Mechanistic and kinetic schemes for additive-free non-crosslinked polybutadiene, Polymer Degradation and Stability, vol.92, issue.7, pp.1334-1342, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00199759

P. Y. Le-gac, G. Roux, J. Verdu, P. Davies, and B. Fayolle, Oxidation of unvulcanized, unstabilized polychloroprene: A kinetic study, Polymer Degradation and Stability, vol.109, pp.175-183, 2014.

M. J. Abadie, M. Dimonie, C. Couve, and V. Dragutan, New catalysts for linear polydicyclopentadiene synthesis, European Polymer Journal, vol.36, issue.6, pp.1213-1219, 2000.

J. Villarreal, J. Laane, S. Bush, and W. Harris, Vibrational spectra and normal coordinate analysis for cyclopentene, cyclopentene-1-d1, cyclopentene-1, 2, 3, 3-d4 and cyclopentene-d8, Spectrochimica Acta Part A: Molecular Spectroscopy, vol.35, issue.4, pp.331-338, 1979.

D. Nava, T. R. De-parada, E. González, N. Boscàn, and C. Cruz, An infrared spectroscopic comparison of cis-and trans-CH=CH and vinyl CH=CH2 group frequencies of some hexenes, heptenes, and stereospecific and non-stereospecific polybutadienes, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol.52, issue.10, pp.1201-1210, 1996.

D. Lin-vien, N. B. Colthup, W. G. Fateley, and J. G. Grasselli, CHAPTER 6 -Alkenes," in The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules, pp.73-94, 1991.

J. G. Calvert and J. N. Pitts, Photochemistry, 1966.

H. L. Mcmurry and V. Thornton, Correlation of Infrared Spectra, Anal. Chem, vol.24, issue.2, pp.318-334, 1952.

R. M. Elder, J. W. Andzelm, and T. W. Sirk, A molecular simulation study of the glass transition of cross-linked poly (dicyclopentadiene) networks, Chemical Physics Letters, vol.637, pp.103-109, 2015.

D. B. Knorr, Overcoming the structural versus energy dissipation trade-off in highly crosslinked polymer networks: ultrahigh strain rate response in polydicyclopentadiene, Composites Science and Technology, vol.114, pp.17-25, 2015.

G. A. Russell, Deuterium-isotope Effects in the Autoxidation of Aralkyl Hydrocarbons. Mechanism of the Interaction of PEroxy Radicals 1, Journal of the American Chemical Society, vol.79, issue.14, pp.3871-3877, 1957.

J. A. Howard and K. U. Ingold, Self-reaction of sec-butylperoxy radicals. Confirmation of the Russell mechanism, Journal of the American Chemical Society, vol.90, issue.4, pp.1056-1058, 1968.

L. Audouin, V. Gueguen, A. Tcharkhtchi, and J. Verdu, Close loop' mechanistic schemes for hydrocarbon polymer oxidation, Journal of Polymer Science Part A: Polymer Chemistry, vol.33, issue.6, pp.921-927, 1995.

N. C. Billingham and M. N. Grigg, The kinetic order of decomposition of polymer hydroperoxides assessed by chemiluminescence, Polymer Degradation and Stability, vol.83, issue.3, pp.441-451, 2004.

N. C. Billingham, E. T. Then, and A. Kron, Chemiluminescence from peroxides in polypropylene: II. Luminescence and kinetics of peroxide decomposition, Polymer Degradation and Stability, vol.55, issue.3, pp.339-346, 1997.

L. Zlatkevich, On the kinetic order of decomposition of polymeric hydroperoxides, Polymer degradation and stability, vol.83, issue.2, pp.369-371, 2004.

G. Gutiérrez, F. Fayolle, G. Régnier, and J. Medina, Thermal oxidation of claynanoreinforced polypropylene, Polymer Degradation and Stability, vol.95, issue.9, pp.1708-1715, 2010.

E. M. Hoàng, N. S. Allen, C. M. Liauw, E. Fontán, and P. Lafuente, The thermooxidative degradation of metallocene polyethylenes. Part 1: long-term thermal oxidation in the solid state, Polymer degradation and stability, vol.91, issue.6, pp.1356-1362, 2006.

E. M. Hoàng, N. S. Allen, C. M. Liauw, E. Fontán, and P. Lafuente, The thermooxidative degradation of metallocene polyethylenes: Part 2: Thermal oxidation in the melt state, Polymer degradation and stability, vol.91, issue.6, pp.1363-1372, 2006.

E. Richaud, F. Farcas, B. Fayolle, L. Audouin, and J. Verdu, Hydroperoxide titration by DSC in thermally oxidized polypropylene, Polymer Testing, vol.25, issue.6, pp.829-838, 2006.

J. C. Chien, E. J. Vandenberg, and H. Jabloner, Polymer reactions. III. Structure of polypropylene hydroperoxide, Journal of Polymer Science Part A-1: Polymer Chemistry, vol.6, issue.2, pp.381-392, 1968.

J. C. Chien and H. Jabloner, Polymer reactions. IV. Thermal decomposition of polypropylene hydroperoxides, Journal of Polymer Science Part A-1: Polymer Chemistry, vol.6, issue.2, pp.393-402, 1968.

C. L. Mcgann, Air Activated Self-Decontaminating Polydicyclopentadiene PolyHIPE Foams for Rapid Decontamination of Chemical Warfare Agents, Macromolecular rapid communications, vol.39, issue.12, p.1800194, 2018.

X. Colin, L. Audouin, and J. Verdu, Kinetic modelling of the thermal oxidation of polyisoprene elastomers. Part 1: Unvulcanized unstabilized polyisoprene, Polymer Degradation and Stability, vol.92, issue.5, pp.886-897, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00199728

G. A. Russell, The Rates of Oxidation of Aralkyl Hydrocarbons. Polar Effects in Free Radical Reactions1,2, J. Am. Chem. Soc, vol.78, issue.5, pp.1047-1054, 1956.

P. Gijsman, J. Hennekens, and J. Vincent, The mechanism of the low-temperature oxidation of polypropylene, Polymer Degradation and Stability, vol.42, issue.1, pp.95-105, 1993.

W. H. Richardson, Metal Ion Decomposition of Hydroperoxides. IV. Kinetics and Products of Copper Salt Catalyzed Decomposition of t-Butyl Hydroperoxide, J. Am. Chem. Soc, vol.88, issue.5, pp.975-979, 1966.

A. V. Tobolsky, D. J. Metz, and R. B. Mesrobian, Low Temperature Autoxidation of Hydrocarbons: the Phenomenon of Maximum Rates1,2, J. Am. Chem. Soc, vol.72, issue.5, pp.1942-1952, 1950.

V. Defauchy, Kinetic analysis of polydicyclopentadiene oxidation, Polymer Degradation and Stability, vol.142, pp.169-177, 2017.

E. T. Denisov, Polymer oxidation and antioxidant action, 2000.

K. T. Gillen, J. Wise, and R. L. Clough, General solution for the basic autoxidation scheme, Polymer Degradation and Stability, vol.47, issue.1, pp.149-161, 1995.

Y. Hu, Y. Zhang, and S. Nutt, Thermal oxidation aging of polydicyclopentadiene and composites, Polymer Composites, vol.39, issue.5, pp.1742-1751, 2018.

T. R. Long, Influence of molecular weight between crosslinks on the mechanical properties of polymers formed via ring-opening metathesis, Soft matter, vol.14, issue.17, pp.3344-3360, 2018.

J. S. Arrieta, E. Richaud, B. Fayolle, and F. Nizeyimana, Thermal oxidation of vinyl ester and unsaturated polyester resins, Polymer degradation and stability, vol.129, pp.142-155, 2016.

E. Ernault, J. Dirrenberger, E. Richaud, and B. Fayolle, Prediction of stress induced by heterogeneous oxidation: Case of epoxy/amine networks, Polymer Degradation and Stability, vol.162, pp.112-121, 2019.
URL : https://hal.archives-ouvertes.fr/hal-02086883

, Last, it seems that stabilizers lead to an increase in the thickness of the oxidized layer. The effect on mechanical damage remains to be described but the use of kinetic model can help

F. Gugumus, Aspects of the stabilization mechanisms of phenolic antioxidants in polyolefins, Die Angewandte Makromolekulare Chemie: Applied Macromolecular Chemistry and Physics, vol.137, issue.1, pp.189-225, 1985.

J. , Chemical and photochemical behaviour of phenolic antioxidants in polymer stabilization: A state of the art report, part II, Polymer Degradation and Stability, vol.39, issue.1, pp.103-115, 1993.

J. , Chemical and photochemical behaviour of phenolic antioxidants in polymer stabilization-a state of the art report, Part I, Polymer Degradation and Stability, vol.40, issue.2, pp.217-232, 1993.

F. Gugumus, Current trends in mode of action of hindered amine light stabilizers, Polymer Degradation and Stability, vol.40, issue.2, pp.167-215, 1993.

F. Gugumus and N. Lelli, Light stabilization of metallocene polyolefins, Polymer degradation and stability, vol.72, issue.3, pp.407-421, 2001.

N. Allen, K. Fatinikun, J. Gardette, and J. Lemaire, Thermal and photo-sensitised oxidation of polypropylene: Influence of hindered piperidine compounds, Polymer Degradation and Stability, vol.3, issue.4, pp.243-252, 1981.

J. Malik, D. Tuan, and E. ?pirk, Lifetime prediction for HALS-stabilized LDPE and PP, Polymer degradation and stability, vol.47, issue.1, pp.1-8, 1995.

P. Hrdlovi? and ?. Chmela, Oligomeric Stabilizers of HALS Type; Influence of Polarity and Molecular Mass on Efficiency, International Journal of Polymeric Materials, vol.13, issue.1-4, pp.245-254, 1990.

J. Malík and G. Ligner, Hindered amine light stabilizers: introduction, Plastics Additives, pp.353-359, 1998.

K. Anto? and J. Sedlá?, Influence of brominated flame retardant thermal decomposition products on HALS, Polymer Degradation and Stability, vol.90, issue.1, pp.188-194, 2005.

J. Malík, A. Hrivík, and D. Alexyová, Physical loss of hindered amine light stabilizers from polyethylene, Polymer Degradation and Stability, vol.35, issue.2, pp.125-130, 1992.

J. Malík, A. Hrivík, and E. Tomová, Diffusion of hindered amine light stabilizers in low density polyethylene and isotactic polypropylene, Polymer Degradation and Stability, vol.35, issue.1, pp.61-66, 1992.

E. Richaud, B. Fayolle, and J. Verdu, Polypropylene stabilization by hindered phenols -Kinetic aspects, Polymer Degradation and Stability, vol.96, issue.1, pp.1-11, 2011.

E. Denisov and I. , Afanas'ev, Oxidation and Antioxidants in Organic Chemistry and Biology, 2005.

E. Richaud, Kinetic modelling of phenols consumption during polyethylene thermal oxidation, European Polymer Journal, vol.49, issue.8, pp.2223-2232, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00860174

M. Coquillat, Vieillissement des propergols à matrice polybutadiène: modélisation cinétique de l'oxydation

E. Richaud, X. Colin, C. Monchy-leroy, L. Audouin, and J. Verdu, Polyethylene stabilization against thermal oxidation by a trimethylquinoleine oligomer, Polymer Degradation and Stability, vol.94, issue.3, pp.410-420, 2009.

E. T. Denisov, Mechanism of regeneration of hindered nitroxyl and aromatic amines, Polymer Degradation and Stability, vol.25, issue.2-4, pp.209-215, 1989.

J. Chateauneuf, J. Lusztyk, and K. U. Ingold, Absolute rate constants for the reactions of some carbon-centered radicals with 2,2,6,6-tetramethyl-1-piperidinoxyl, The Journal of Organic Chemistry, vol.53, issue.8, pp.1629-1632, 1988.

J. Nicolas, Y. Guillaneuf, C. Lefay, D. Bertin, D. Gigmes et al., Nitroxidemediated polymerization, Progress in Polymer Science, vol.38, issue.1, pp.63-235, 2013.
URL : https://hal.archives-ouvertes.fr/hal-01460403

D. Bauer and J. Gerlock, Photo-stabilisation and photo-degradation of organic coatings containing a hindered amine light stabiliser: Part III-Kinetics of stabilisation during free radical oxidation, Polymer degradation and stability, vol.14, issue.2, pp.97-112, 1986.

A. Faucitano, A. Buttafava, F. Martinotti, and P. Bortolus, First electron spin resonance identification of a nitrogen peroxy radical as intermediate in the photooxidation of 2,2,6,6-tetramethylpiperidine derivatives, J. Phys. Chem, vol.88, issue.6, pp.1187-1190, 1984.

E. T. Denisov and I. B. , Afanas' ev, Oxidation and antioxidants in organic chemistry and biology, 2005.

P. Gijsman, W. Dong, A. Quintana, and M. Celina, Influence of temperature and stabilization on oxygen diffusion limited oxidation profiles of polyamide 6, Polymer Degradation and Stability, vol.130, pp.83-96, 2016.

E. Ernault, J. Dirrenberger, E. Richaud, and B. Fayolle, Prediction of stress induced by heterogeneous oxidation: Case of epoxy/amine networks, Polymer Degradation and Stability, vol.162, pp.112-121, 2019.
URL : https://hal.archives-ouvertes.fr/hal-02086883

F. Djouani, E. Richaud, B. Fayolle, and J. Verdu, Modelling of thermal oxidation of phosphite stabilized polyethylene, Polymer Degradation and Stability, vol.96, issue.7, pp.1349-1360, 2011.
URL : https://hal.archives-ouvertes.fr/hal-02455174

P. Y. Le-gac, D. Choqueuse, M. Paris, G. Recher, C. Zimmer et al., Durability of polydicyclopentadiene under high temperature, high pressure and seawater (offshore oil production conditions), Polymer Degradation and Stability, vol.98, issue.3, pp.809-817, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00961264

I. Merdas, F. Thominette, A. Tcharkhtchi, and J. Verdu, Factors governing water absorption by composite matrices, Composites Science and technology, vol.62, issue.4, pp.487-492, 2002.

B. Fayolle and J. Verdu, Vieillissement physique des matériaux polymères, 2002.

E. Gaudichet-maurin, Caractérisation et vieillissement d'une membrane d'ultrafiltration d'eau, 2005.

B. Pomes, I. Derue, A. Lucas, J. Nguyen, and E. Richaud, Water ageing of urethane dimethacrylate networks, Polymer degradation and stability, vol.154, pp.195-202, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01825761

E. M. Davis and Y. A. Elabd, Water clustering in glassy polymers, The Journal of Physical Chemistry B, vol.117, issue.36, pp.10629-10640, 2013.

B. H. Zimm and J. L. Lundberg, Sorption of vapors by high polymers, The Journal of Physical Chemistry, vol.60, issue.4, pp.425-428, 1956.

J. Lundberg, Clustering theory and vapor sorption by high polymers, Journal of Macromolecular Science, Part B: Physics, vol.3, issue.4, pp.693-710, 1969.

P. Y. Le-gac, G. Roux, P. Davies, B. Fayolle, and J. Verdu, Water clustering in polychloroprene, Polymer, vol.55, issue.12, pp.2861-2866, 2014.
URL : https://hal.archives-ouvertes.fr/hal-01058318

M. Kurata, Thermodynamics of Polymer Solutions, 1982.

J. Burke, Solubility parameters: theory and application, The Book and Paper Group Annual, vol.3, pp.13-58, 1984.

D. W. Van-krevelen and K. Nijenhuis, Chapter 7 -Cohesive Properties and Solubility, Properties of Polymers, pp.189-227, 2009.

J. Crank, The mathematics of diffusion, 1979.

E. Courvoisier, Analyse et modélisation cinétique du vieillissement thermique des matrices PEI et PEEK et ses conséquences sur l'absorption d'eau, Ecole nationale supérieure d'arts et métiers -ENSAM, 2017.

H. G. Carter and K. G. Kibler, Langmuir-type model for anomalous moisture diffusion in composite resins, Journal of Composite Materials, vol.12, issue.2, pp.118-131, 1978.

A. Tcharkhtchi, P. Bronnec, and J. Verdu, Water absorption characteristics of diglycidylether of butane diol-3, 5-diethyl-2, 4-diaminotoluene networks, Polymer, vol.41, issue.15, pp.5777-5785, 2000.

S. Popineau, C. Rondeau-mouro, C. Sulpice-gaillet, and M. E. Shanahan, Free/bound water absorption in an epoxy adhesive, Polymer, vol.46, issue.24, pp.10733-10740, 2005.
URL : https://hal.archives-ouvertes.fr/hal-00157171

P. Gilormini and J. Verdu, On the role of hydrogen bonding on water absorption in polymers, Polymer, vol.142, pp.164-169, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01743020

C. Wilhelm and J. Gardette, Infrared identification of carboxylic acids formed in polymer photooxidation, Journal of Applied Polymer Science, vol.51, issue.8, pp.1411-1420, 1994.

E. Richaud, P. Y. Le-gac, and J. Verdu, Thermooxidative aging of polydicyclopentadiene in glassy state, Polymer Degradation and Stability, vol.102, pp.95-104, 2014.
URL : https://hal.archives-ouvertes.fr/hal-00977089

E. Richaud, F. Farcas, B. Fayolle, L. Audouin, and J. Verdu, Hydroperoxide titration by DSC in thermally oxidized polypropylene, Polymer Testing, vol.25, issue.6, pp.829-838, 2006.

F. M. Rugg, J. J. Smith, and R. C. Bacon, Infrared spectrophotometric studies on polyethylene. II. Oxidation, Journal of Polymer Science, vol.13, issue.72, pp.535-547, 1954.

M. Coquillat, J. Verdu, X. Colin, L. Audouin, and R. Nevière, Thermal oxidation of polybutadiene. Part 2: Mechanistic and kinetic schemes for additive-free non-crosslinked polybutadiene, Polymer Degradation and Stability, vol.92, issue.7, pp.1334-1342, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00199759

J. L. Henry, A. L. Ruaya, and A. Garton, The kinetics of polyolefin oxidation in aqueous media, Journal of Polymer Science Part A: Polymer Chemistry, vol.30, issue.8, pp.1693-1703, 1992.

, Conclusions and prospects

, Field-joint en milieu marine, sa prévision de durée de vie sera divisée en deux parties à étudier: l'oxydation thermique et le lien avec les propriétés techniques (mécanique, interaction avec l'eau)

C. Dans-ce, pour l'exploitation pétrolière en mer et plus généralement pour le vieillissement dans l'eau. En service, le matériau PDCPD est soumis à de l'eau de mer et à un profil de température en fonction de l'épaisseur du revêtement. Ainsi, l'oxydation thermique du PDCPD influencera potentiellement le comportement d'absorption d'eau. L'objectif de ce chapitre est d'étudier les propriétés de, nous nous focaliserons sur l'application potentielle du PDCPD en tant que « Field Joint

, µm) de PDCPD sans stabilisants, présentant une humidité relative (HR) comprise entre 10 et 90% à trois températures, à l'aide d'un appareil DVS. Les échantillons de PDCPD ont tout d'abord été oxydés à 25°C, 50°C et 70°C pour différentes durées de vieillissement. Ensuite, des échantillons non vieillis et des échantillons oxydés ont été prélevés pour mener des expériences de sorption d, Des expériences de sorption d'eau ont été réalisées sur des films minces

L. Figure and A. , 28 présente la courbe typique de changement de masse pour le PDCPD non vieilli

, Il est clair que l'absorption maximale d'eau dans le matériau non vieilli est très faible (généralement inférieure à 0,3%) à cause de sa structure apolaire