O. Bayer, . Angew, and . Chem, , vol.59, pp.257-272, 1947.

D. K. Chattopadhyay and K. V. Raju, Prog. Polym. Sci, vol.32, pp.352-418, 2007.

J. O. Akindoyo, M. D. Beg, S. Ghazali, M. R. Islam, N. Jeyaratnam et al., , vol.6, pp.114453-114482, 2016.

H. Engels, H. Pirkl, R. Albers, R. W. Albach, J. Krause et al., J. Angew. Chem. Int. Ed, vol.52, pp.9422-9441, 2013.

M. Charlon, B. Heinrich, Y. Matter, E. Couzigné, B. Donnio et al., Eur. Polym. J, vol.61, pp.197-205, 2014.

N. N. Pauzi, R. A. Majid, M. H. Dzulkifli, and M. Y. Yahya, Composites Part B-Engineering, vol.67, pp.521-526, 2014.

Z. S. Petrovi?, Polym. Rev, vol.48, pp.109-155, 2008.

S. D. Rajput, D. G. Hundiwale, P. P. Mahulikar, and V. V. Gite, Progress in Organic Coatings, vol.77, pp.1360-1368, 2014.

H. Sardon, A. Pascual, D. Mecerreyes, D. Taton, H. Cramail et al., Macromolecules, vol.48, pp.3153-3165, 2015.

J. Alsarraf, Y. A. Ammar, F. Robert, E. Cloutet, H. Cramail et al., Macromolecules, vol.45, pp.2249-2256, 2012.

O. Coutelier, M. El-ezzi, M. Destarac, F. Bonnette, T. Kato et al., Polym. Chem, vol.3, pp.605-608, 2012.

H. Sardon, J. M. Chan, R. J. Ono, D. Mecerreyes, and J. L. Hedrick, Polym. Chem, vol.5, pp.3547-3550, 2014.

J. Alsarraf, F. Robert, H. Cramail, and Y. Landais, Polym. Chem, vol.4, pp.904-907, 2013.

S. Pyo, P. Persson, M. A. Mollaahmad, K. Sorensen, S. Lundmark et al., Pure Appl. Chem, vol.84, pp.637-661, 2012.

C. Hahn, H. Keul, and M. Möller, Polym. Int, vol.61, pp.1048-1060, 2012.

J. Guan, Y. Song, Y. Lin, X. Yin, M. Zuo et al., Ind. Eng. Chem. Res, vol.50, pp.6517-6527, 2011.

M. S. Kathalewar, P. B. Joshi, A. S. Sabnis, V. C. Malshe, and . Adv, , vol.3, p.4110, 2013.

T. Shimizu, M. Masuda, and H. Minamikawa, Chem. Rev, vol.105, pp.1401-1443, 2005.

T. Zemb, M. Dubois, B. Deme, and T. Gulik-krzywicki, Science, vol.283, pp.816-819, 1999.

J. D. Hartgerink, E. Beniash, and S. I. Stupp, Science, vol.294, pp.1684-1688, 2001.

X. Wang, G. Guerin, H. Wang, Y. Wang, I. Manners et al., Science, vol.317, pp.644-647, 2007.

J. N. Israelachvili, D. J. Mitchell, and B. W. Ninham, J. Chem. Soc. Faraday Trans, vol.72, pp.1525-1568, 1976.

M. Salim, H. Minamikawa, A. Sugimura, R. Hashim, and . Medchemcomm, , vol.5, pp.1602-1618, 2014.

Y. Mai and A. Eisenberg, Chem. Soc. Rev, vol.41, pp.5969-5985, 2012.

P. Alexandridis and B. Lindman, Amphiphilic Block Copolymers: Self-Assembly and Applications, 2000.

H. Klok and S. Lecommandoux, Adv. Mater, vol.13, pp.1217-1229, 2001.

F. S. Bates and G. H. Fredrickson, Phys. Today, vol.52, pp.32-38, 1999.

S. Förster and T. Plantenberg, Angew. Chem., Int. Ed, vol.41, pp.688-714, 2002.

Y. Y. Won, H. T. Davis, and F. S. Bates, Science, vol.283, pp.960-963, 1999.

B. M. Discher, Y. Y. Won, D. S. Ege, J. C. Lee, F. S. Bates et al., Science, vol.284, pp.1143-1146, 1999.

S. Jain and F. S. Bates, Science, vol.300, pp.460-464, 2003.

L. Zhang and A. Eisenberg, Science, vol.268, pp.1728-1731, 1995.

L. Zhang, K. Yu, and A. Eisenberg, Science, vol.272, pp.1777-1779, 1996.

L. Zhang and A. Eisenberg, J. Am. Chem. Soc, vol.118, pp.3168-3181, 1996.

L. Zhang and A. Eisenberg, Polym. Adv. Technol, vol.9, pp.677-699, 1998.

N. S. Cameron, M. K. Corbierre, and A. Eisenberg, Can. J. Chem, vol.77, pp.1311-1326, 1999.

S. A. Jenekhe and X. L. Chen, Science, vol.279, pp.1903-1907, 1998.

L. Jia, A. Cao, D. Lévy, B. Xu, P. Albouy et al., Soft Matter, vol.5, pp.3446-3451, 2009.

S. A. Jenekhe and X. L. Chen, Science, vol.283, pp.372-375, 1999.

J. Yang, R. Piñol, F. Gubellini, D. Lévy, P. Albouy et al., Introduction Langmuir, vol.22, pp.7907-7911, 2006.

E. G. Bellomo, M. D. Wyrsta, L. Pakstis, D. J. Pochan, and T. J. Deming, Nat. Mater, vol.3, pp.244-248, 2004.

J. Yang, D. Lévy, W. Deng, P. Keller, and M. Li, Chem. Commun, pp.4345-4347, 2005.

R. Piñol, L. Jia, F. Gubellini, D. Lévy, P. Albouy et al., Macromolecules, vol.40, pp.5625-5627, 2007.

L. Jia, P. Albouy, A. Cicco, A. Cao, and M. Li, Polymer, vol.52, pp.2565-2575, 2011.

X. Zhang, S. Boissé, C. Bui, P. Albouy, A. Brûlet et al., Soft Matter, vol.8, pp.1130-1141, 2012.

L. Jia, D. Cui, J. Bignon, A. Di-cicco, J. Wdzieczak-bakala et al., Biomacromolecules, vol.15, pp.2206-2217, 2014.

L. Zhou, D. Zhang, S. Hocine, A. Pilone, S. Trépout et al., Polym. Chem, vol.8, pp.4776-4780, 2017.

M. Ding, J. Li, H. Tan, and Q. Fu, Soft Matter, vol.8, pp.5414-5428, 2012.

M. Bil, J. Ryszkowska, P. Woz?niak, K. J. Kurzyd?owski, M. Lewandowska-szumie? et al., , vol.6, pp.2501-2510, 2010.

Z. Li and J. Li, J. Phys. Chem. B, vol.117, pp.14763-14774, 2013.

M. Ding, X. He, Z. Wang, J. Li, H. Tan et al., Biomaterials, vol.32, pp.9515-9524, 2011.

Y. Zhang and R. X. Zhuo, Biomaterials, vol.26, pp.6736-6742, 2005.

C. Gong, X. Wei, X. Wang, Y. Wang, G. Guo et al., Z. Nanotechnology, p.215103, 2010.

C. Gong, Y. Wang, X. Wang, X. Wei, Q. Wu et al., Z. J. Nanopart. Res, vol.13, pp.721-731, 2011.

X. F. Cheng, Y. Jin, B. Z. Fan, R. Qi, H. P. Li et al., Acs Macro Letters, vol.5, pp.238-243, 2016.

E. Ibarboure, A. Baron, E. Papon, and . Rodriguez-hernandez, J. Thin Solid Films, 2009.

S. Penczek and G. Moad, Pure Appl. Chem, vol.80, pp.2163-2193, 2008.

O. Nuyken and S. D. Pask, Polymers, vol.5, pp.361-403, 2013.

H. R. Allcock, J. Macromol. Sci. Revs. Macromol. Chem, p.149, 1970.

H. K. Hall and A. K. Schneider, J. Am. Chem. Soc, vol.80, pp.6409-6412, 1958.

C. W. Bielawski and R. H. Grubbs, Prog. Polym. Sci, vol.32, pp.1-29, 2007.

A. Hamitou, T. Ouhadi, R. Jerome, and P. Teyssié, J. Polym. Sci., Part A: Polym. Chem, vol.15, pp.865-873, 1977.

K. Hashimoto, Prog. Polym. Sci, vol.25, pp.1411-1462, 2000.

J. Sebenda and J. Hauer, Polym. Bull, vol.5, pp.529-534, 1981.

H. Kricheldorf, In Pencze S (ed) Models of biopolymers by ring opening polymerization

B. Crc and . Raton, , pp.1-132, 1990.

J. J. Cheng and T. Deming, J. In Peptide-Based Materials

T. Deming and . Ed, , vol.310, pp.1-26, 2012.

H. K. Hall, J. Am. Chem. Soc, vol.80, pp.6404-6409, 1958.

V. M. Rothe, G. Reinisch, W. Jaeger, I. Schopov, . Makromol et al., , vol.54, pp.183-204, 1962.

A. Luisier, P. E. Bourban, and J. A. Manson, J. Polym. Sci., Part A: Polym. Chem, vol.40, pp.3406-3415, 2002.

B. Lebedev, V. Veridusova, H. Höcker, and H. Keul, Macromol. Chem. Phys, vol.203, pp.1114-1125, 2002.

S. Neffgen, J. Kusan, T. Fey, H. Keul, and H. Höcker, Macromol. Chem. Phys, vol.201, pp.2108-2114, 2000.

S. P. Mcmanus, C. A. Larson, and R. A. Hearn, Synth. Commun, vol.3, pp.177-180, 1973.

L. R. Hawkins and R. A. Bannard, Can. J. Chem, vol.36, pp.220-227, 1958.

J. Kusan, H. Keul, and H. Höcker, Macromolecules, vol.34, pp.389-395, 2001.

V. Chiono, P. Mozetic, M. Boffito, S. Sartori, E. Gioffredi et al., Interface Focus, vol.4, 2014.

S. Oishi, J. Yoshimoto, and S. Saito, J. Am. Chem. Soc, vol.131, pp.8748-8749, 2009.

. Chapter, Controlled anionic ring opening polymerization of 5-membered cyclic carbamates to polyurethanes 105

A. Bouzide and G. Sauve, Tetrahedron Letters, vol.43, pp.1961-1964, 2002.

H. Deng, Z. Shen, L. Li, H. Yin, and J. Chen, J. Appl. Polym. Sci, p.40503, 2014.

J. M. Messman and R. F. Storey, J. Polym. Sci., Part A: Polym. Chem, vol.42, pp.6238-6247, 2004.

T. J. Schwartz, S. D. Lyman, A. H. Motagamwala, M. A. Mellmer, and J. A. Dumesic, , vol.6, pp.2047-2054, 2016.

Z. He, C. Ke, B. Z. Tang, and . Omega, , vol.3, pp.3267-3277, 2018.

I. Chapter, Synthesis and self-assembly of polyurethane-based amphiphilic linear diblock copolymers

G. Riess, G. Hurtrez, P. Bahadur, . Block, and . Copolymers, Encyclopedia of polymer science and engineering, vol.2, pp.324-434, 1985.

G. Riess, Prog. Polym. Sci, vol.28, pp.1107-1170, 2003.

Y. Mai and A. Eisenberg, Chem. Soc. Rev, vol.41, pp.5969-5985, 2012.

M. Karayianni and S. Pispas, Fluorescence Studies of Polymer Containing Systems, pp.27-63, 2016.

L. Zhang and A. Eisenberg, J. Am. Chem. Soc, vol.118, pp.3168-3181, 1996.

H. B. Feng, X. Y. Lu, W. Y. Wang, N. G. Kang, and J. W. Mays, Polymers, vol.9, p.494, 2017.

C. J. Hawker and K. L. Wooley, Science, vol.309, pp.1200-1205, 2005.

J. Wang and K. Matyjaszewski, J. Am. Chem. Soc, vol.117, pp.5614-5615, 1995.

J. Chiefari, Y. K. Chong, F. Ercole, J. Krstina, J. Jeffery et al., Macromolecules, vol.31, pp.5559-5562, 1998.

M. K. Georges, R. P. Veregin, P. M. Kazmaier, G. K. Hamer, and . Macromolecules, , vol.26, pp.2987-2988, 1993.

W. A. Braunecker and K. Matyjaszewski, Prog. Polym. Sci, vol.32, pp.93-146, 2007.

X. W. Wei, C. Y. Gong, M. Y. Gou, S. Z. Fu, Q. F. Guo et al., Z. Y. Int. J. Pharm, vol.381, pp.1-18, 2009.

M. H. Huang, S. M. Li, D. W. Hutmacher, J. T. Schantz, C. A. Vacanti et al., Biomed. Mater. Res. A, vol.69, pp.417-427, 2004.

J. K. Oh, Soft Matter, vol.7, pp.5096-5108, 2011.

X. H. Wu, A. El-ghzaoui, S. M. Li, and . Langmuir, , vol.27, pp.8000-8008, 2011.

T. Steinbach and F. R. Wurm, Angew. Chem., Int. Ed, vol.54, pp.6098-6108, 2015.

S. Y. Zhang, J. Zou, F. W. Zhang, M. Elsabahy, S. E. Felder et al., J. Am. Chem. Soc, vol.134, pp.18467-18474, 2012.

C. Y. Sun, Y. C. Ma, Z. Y. Cao, D. D. Li, F. Fan et al., ACS Appl. Mater. Interfaces, vol.6, pp.22709-22718, 2014.

I. Chapter, Synthesis and self-assembly of polyurethane-based amphiphilic linear diblock copolymers

Y. C. Wang, L. Y. Tang, Y. Li, and . Wang, J. Biomacromolecules, vol.10, pp.66-73, 2009.

L. Zhou, D. Zhang, S. Hocine, A. Pilone, S. Trépout et al., Polym. Chem, vol.8, pp.4776-4780, 2017.

S. Venkataraman, A. L. Lee, H. T. Maune, J. L. Hedrick, V. M. Prabhu et al., Macromolecules, vol.46, pp.4839-4846, 2013.

E. G. Bellomo, M. D. Wyrsta, L. Pakstis, D. J. Pochan, and T. J. Deming, Nat. Mater, vol.3, pp.244-248, 2004.

E. P. Holowka, D. J. Pochan, and T. J. Deming, J. Am. Chem. Soc, vol.127, pp.12423-12428, 2005.

X. Lin, X. He, C. Hu, Y. Chen, Y. Mai et al., Synthesis and self-assembly of polyurethane-based amphiphilic graft copolymers, Polym. Chem, vol.7, pp.2815-2820, 2016.

I. V. Chapter, Synthesis and self-assembly of polyurethane-based amphiphilic graft copolymers

I. V. Chapter, Synthesis and self-assembly of polyurethane-based amphiphilic graft copolymers

S. S. Sheiko, B. S. Sumerlin, and K. Matyjaszewski, Prog. Polym. Sci, vol.33, pp.759-785, 2008.

C. Feng, Y. J. Li, D. Yang, J. H. Hu, X. H. Zhang et al., Chem. Soc. Rev, vol.40, pp.1282-1295, 2011.

M. F. Zhang and A. H. Mu?ller, J. Polym. Sci. Part A: Polym. Chem, vol.43, pp.3461-3481, 2005.

N. C. Kaneider, S. Dunzendorfer, and C. J. Wiedermann, Biochemistry, vol.43, pp.237-244, 2004.

J. E. Scott, Biochemistry, vol.35, pp.8795-8799, 1996.

S. S. Sheiko, F. C. Sun, A. Randall, D. Shirvanyants, M. Rubinstein et al., Nature, vol.440, pp.191-194, 2006.

I. Park, S. S. Sheiko, A. Nese, and K. Matyjaszewski, Macromolecules, vol.42, pp.1805-1807, 2009.

M. B. Runge and N. B. Bowden, J. Am. Chem. Soc, vol.129, pp.10551-10560, 2007.

J. L. Mynar, T. L. Choi, M. Yoshida, V. Kim, C. J. Hawker et al., Chem. Commun, pp.5169-5171, 2005.

B. Helms, J. L. Mynar, C. J. Hawker, and J. M. Fréchet, J. Am. Chem. Soc, vol.126, pp.15020-15021, 2004.

H. F. Gao and K. Matyjaszewski, J. Am. Chem. Soc, vol.129, pp.6633-6639, 2007.

A. C. Engler, H. I. Lee, and P. T. Hammond, Angew. Chem., Int. Ed, vol.48, pp.9334-9338, 2009.

A. B. Lowe, Polym. Chem, vol.1, pp.17-36, 2010.

S. Cesana, J. Auernheimer, R. Jordan, H. Kessler, and O. Nuyken, Macromol. Chem. Phys, vol.207, pp.183-192, 2006.

G. L. Cheng, A. Böker, M. F. Zhang, G. Krausch, and A. H. Mu?ller, Macromolecules, vol.34, pp.6883-6888, 2001.

M. Wintermantel, M. Gerle, K. Fischer, M. Schmidt, I. Wataoka et al., Macromolecules, vol.29, pp.978-983, 1996.

I. V. Chapter, Synthesis and self-assembly of polyurethane-based amphiphilic graft copolymers

K. Yamada, M. Miyazaki, K. Ohno, T. Fukuda, and M. Minoda, Macromolecules, vol.32, pp.290-293, 1999.

Y. Xia, J. A. Kornfield, and R. H. Grubbs, Macromolecules, vol.42, pp.3761-3766, 2009.

B. S. Sumerlin, D. Neugebauer, and K. Matyaszewski, Macromolecules, vol.38, pp.702-708, 2005.

D. Neugebauer, B. S. Sumerlin, and K. Matyaszewski, Polymer, vol.45, pp.8173-8179, 2004.

C. H. Cai, J. P. Lin, T. Chen, X. H. Tian, and . Langmuir, , vol.26, pp.2791-2797, 2010.

K. Ferji, C. Nouvel, J. Babin, M. Li, C. Gaillard et al., , vol.4, pp.1119-1122, 2015.

X. H. Zhang, Z. Shen, C. Feng, D. Yang, Y. G. Li et al., Macromolecules, vol.42, pp.4249-4256, 2009.

D. C. Wan, H. T. Pu, and G. J. Yang, React. Funct. Polym, vol.68, pp.431-435, 2008.

, H NMR spectra were recorded either on Bruker Avance 300 MHz

. Mhz, Avance III HD 400 MHz or NEO 500 MHz at 298 K. 2D NMR (COSY, NOESY, HSQC and HMBC) spectra were recorded on Bruker

, Deuterated chloroform (CDCl3) was used as the solvent. NMR chemical shifts were recorded in parts per million referenced to the residual solvent proton

, GC was used to characterize the ratios of diastereomers in the starting vinyl cyclohexeneoxide and the final CHU monomer. The GC spectra were recorded on a GC-2010 Plus (SHIMADZU) instrument

, Size Exclusion Chromatography (SEC) The number-average molecular weights (Mn) and molecular weight distributions of polymers (polydispersity index, PDI) were evaluated by size exclusion chromatography (SEC), using Agilent 1260, Infinity Series GPC

, Monodisperse poly(styrene) polymers were used as calibration standards

M. Ms, Matrix-assisted laser desorption ionization-time of flight mass spectrometry

. Maldi-tof, -MS characterization of polymers was performed on UltrafleXtreme mass spectrometer (Bruker Daltonics, Bremen) using trans-2-[3-(4-tert-Butylphenyl)-Chapter V, Materials and methods

, 04 mol) was dissolved in 100 mL toluene and triethylamine (TEA, 5.06 g, 0.05 mol) was added dropwise in the ice-water bath. Then ethyl chloroformate (5.43 g, 0.05 mol) was added dropwise in the ice-water bath. The mixture was stirred at room temperature for 3 h. After stopping the reaction, toluene was removed by rotary evaporation and 120 mL water was added. 1:1 as eluent

C. , 13 C{ 1 H} NMR (CDCl3): ? 157, vol.1

. Thirdly, 1-hydroxy-2-carbamate-cyclohexane (3, 3.00 g, 16 mmol) was dissolved in 75 mL tetrahydrofuran (THF) and sodium hydride (60 % dispersion in mineral oil, vol.1, p.28

, After stopping the reaction, THF was removed by rotary evaporation and 120 mL water was added. Then the aqueous solution was extracted by EA (3 × 30 mL). The crude product was chromatographed on a silica gel using DCM and EA with a volume ratio of 4:1 as eluent, and the pure product was cyclic urethane 4 (1.88 g, yield: 83%). 1 H NMR (CDCl3): ? 5, vol.15

L. Zhou and D. Zhang, Co-first author

S. Hocine, A. Pilone, S. Trépout, S. Marco, C. Thomas et al., Transition from smectic nanofibers to smectic vesicles in the self-assemblies of PEG-b-liquid crystal polycarbonates, Polym. Chem, vol.8, pp.4776-4780, 2017.

D. Zhang, Polymerization of Cyclic Carbamates: A Practical Route to Aliphatic Polyurethanes
URL : https://hal.archives-ouvertes.fr/hal-02357495

D. Zhang, Synthesis and self-assembly of polyurethane-based amphiphilic linear diblock copolymers

D. Zhang, Synthesis and self-assembly of polyurethane-based amphiphilic graft copolymers