GEOPOLYMERS -Inorganic polymeric new materials, Journal of Thermal Analysis, vol.37, issue.8, pp.1633-1656, 1991. ,
Geopolymer Chemistry and Applications, 2008. ,
, , 1959.
Mg-Zr alloy behavior in basic solutions and immobilization in Portland cement and Na-geopolymer with sodium fluoride inhibitor. Surface & Coatings Technology, vol.206, pp.4567-4573, 2012. ,
Corrosion behaviour of Mg alloys in various basic media: application of waste encapsulation of fuel decanning from ungg nuclear reactor, in Magnesium Technology, pp.435-439, 2011. ,
Galvanic corrosion of Mg-Zr fuel cladding and steel immobilized in Portland cement and geopolymer at early ages, Journal of Nuclear Materials, vol.435, issue.1-3, pp.137-140, 2013. ,
Encapsulation of Mg-Zr alloy in metakaolin-based geopolymer, Applied Clay Science, vol.73, pp.86-92, 2013. ,
Solidification/stabilisation of liquid oil waste in metakaolin-based geopolymer, Journal of Nuclear Materials, vol.464, pp.16-19, 2015. ,
Synthesis of Geopolymer Foam for the Decontamination of Liquid Nuclear Waste, Poromechanics Vi: Proceedings of the Sixth Biot Conference on Poromechanics, pp.929-936, 2017. ,
Design of lightweight metakaolin based geopolymer foamed with hydrogen peroxide, Ceramics International, vol.45, issue.1, pp.1322-1330, 2019. ,
Geopolymer technology: the current state of the art, Journal of Materials Science, vol.42, issue.9, pp.2917-2933, 2007. ,
Structure and properties of clay-based geopolymer cements: A review, Progress in Materials Science, vol.83, pp.595-629, 2016. ,
Evidence of a Fractal Percolating Network During Geopolymerization, Journal of the American Ceramic Society, vol.98, issue.5, pp.1580-1587, 2015. ,
Microstructure development of alkaliactivated fly ash cement: a descriptive model, vol.35, pp.1204-1209, 2005. ,
Mechanical properties and compositional heterogeneities of fresh geopolymer pastes. Cement and Concrete Research, vol.48, pp.9-16, 2013. ,
URL : https://hal.archives-ouvertes.fr/hal-01537703
A multinuclear static NMR study of geopolymerisation. Cement and Concrete Research, vol.75, pp.104-109, 2015. ,
URL : https://hal.archives-ouvertes.fr/hal-01515608
The geopolymerisation of alumino-silicate minerals, International Journal of Mineral Processing, vol.59, issue.3, pp.247-266, 2000. ,
Mechanism of kaolinite dissolution at room temperature and pressure Part II: Kinetic study, Geochimica Et Cosmochimica Acta, vol.63, pp.3261-3275, 1999. ,
Relation between rates of aluminosilicate mineral dissolution, pH, temperature, and surface charge, American Journal of Science, vol.296, issue.7, pp.693-728, 1996. ,
General kinetic description of multioxide silicate mineral and glass dissolution, Geochimica Et Cosmochimica Acta, vol.65, issue.21, pp.3703-3719, 2001. ,
Physical Chemistry and Rheology of Fresh Geopolymer for Oil Well Cementing, 2010. ,
URL : https://hal.archives-ouvertes.fr/pastel-00555812
Effect of silicate activator pH on the leaching and material characteristics of waste-based inorganic polymers, Minerals Engineering, vol.14, issue.3, pp.289-304, 2001. ,
Effect of the silicate activator pH on the microstructural characteristics of waste-based geopolymers, International Journal of Mineral Processing, vol.66, issue.1-4, pp.121-143, 2002. ,
Direct measurement of the kinetics of geopolymerisation by in-situ energy dispersive X-ray diffractometry, Journal of Materials Science, vol.42, issue.9, pp.2974-2981, 2007. ,
Mechanism of geopolymerization and factors influencing its development: a review, Journal of Materials Science, vol.42, issue.3, pp.729-746, 2007. ,
Size distribution of colloidal silica in sodium silicate solutions investigated by dynamic light scattering and viscosity measurements, Journal of Colloid and Interface Science, vol.267, issue.2, pp.360-368, 2003. ,
, pH-composition relations in the system Na2O SiO2 H2O at 20° C, vol.258, pp.347-369, 1954.
Concentration-and pH-dependence of highly alkaline sodium silicate solutions, Journal of Colloid and Interface Science, vol.356, issue.1, pp.37-45, 2011. ,
Influence des paramètres de formulation sur la texturation et la structuration des géopolymères, 2014. ,
Evidence from alkali-metal NMR-spectroscopy for ionpairing in alkaline silicate solutions, Journal of Physical Chemistry, vol.93, issue.5, pp.1733-1737, 1989. ,
Effect of alkali-metal cations on the chemistry of aqueous silicate solutions. Inorganic Chemistry, vol.31, pp.4558-4563, 1992. ,
Silicon-29 NMR Studies of Aqueous Silicate Solutions .1. Chemical Shifts and Equilibria. Inorganic Chemistry, vol.27, pp.4253-4259, 1988. ,
Nature of species present in an aqueous-solution of potassium silicate, Journal of the American Chemical Society, vol.103, issue.6, pp.1577-1578, 1981. ,
Si-29 NMR-studies of aqueous silicate solutions, Journal of the Chemical Society-Faraday Transactions Ii, vol.73, pp.1204-1215, 1977. ,
29 Si NMR-Spectroscopy of Silicate Solutions .II. Dependence of Structure of Silicate Anions in Water Solutions from Na:Si Ratio. Zeitschrift Fur Anorganische Und Allgemeine Chemie, vol.418, pp.17-28, 1975. ,
Aqueous aluminates, silicates, and aluminosilicates, Chemical Society Reviews, vol.23, issue.5, pp.319-325, 1994. ,
The chemistry of silica : solubility, polymerization, colloid and surface properties, and biochemistry. A Wiley-Interscience publication, 1979. ,
Modeling speciation in highly concentrated alkaline silicate solutions. Industrial & Engineering Chemistry Research, vol.44, pp.8899-8908, 2005. ,
Polysilicate Equilibria in Concentrated Sodium Silicate Solutions, Journal of the Chemical Society-Faraday Transactions I, vol.82, pp.3635-3646, 1986. ,
Ion pairing, Chemical Reviews, vol.106, issue.11, pp.4585-4621, 2006. ,
Thermochemistry of aqueous silicate solution precursors to ceramics, Aiche Journal, vol.43, issue.11, pp.2773-2784, 1997. ,
The Determination of Ionization by Ultraviolet Spectrophotometry: Its Validity and its Application to the Measurement of the Strength of Very Weak Bases, Journal of the American Chemical Society, vol.57, issue.11, pp.2103-2115, 1935. ,
The theory of acidity, Journal of the American Chemical Society, vol.50, issue.10, pp.2666-2673, 1928. ,
A series of simple basic indicators. I. The acidity functions of mixtures of sulfuric and perchloric acids with water, Journal of the American Chemical Society, vol.54, issue.7, pp.2721-2739, 1932. ,
Über die Alkalinität starker Lösungen der Alkalihydroxyde, Helvetica Chimica Acta, vol.27, issue.1, pp.348-362, 1944. ,
H0 and related indicator acidity functions, Chemical Reviews, vol.57, issue.1, pp.1-45, 1957. ,
Strongly basic systems .III. H-function for various solvent systems, Canadian Journal of Chemistry-Revue Canadienne De Chimie, vol.42, issue.7, pp.1681-1693, 1964. ,
Correlation of Acidity Functions with Equilibria of p-Nitroaniline in Aqueous Sodium Hydroxide Solution, Transactions of the Faraday Society, vol.59, issue.492, pp.2820-2825, 1963. ,
Ionization of organic compounds .II. Thioacetamide in aqueous sodium hydroxide. The H-acidity function, Canadian Journal of Chemistry-Revue Canadienne De Chimie, vol.40, issue.3, pp.399-407, 1962. ,
Acidity functions for strongly basic solutions, Chemical Reviews, vol.66, issue.2, pp.119-131, 1966. ,
Interplay between silicate and hydroxide ions during geopolymerization, Cement and Concrete Research, 2018. ,
URL : https://hal.archives-ouvertes.fr/cea-02339844
The ionization constant of water over wide ranges of temperature and density, Journal of Physical and Chemical Reference Data, vol.35, issue.1, pp.15-30, 2006. ,
Optical sensor for high pH values, Analytica Chimica Acta, vol.367, issue.1-3, pp.167-173, 1998. ,
Optical sensors for the determination of concentrated hydroxide, Analytical Chemistry, vol.72, issue.5, pp.1078-1083, 2000. ,
Correlation of Reaction Rates with Acidity Functions in Strongly Basic Media .Part 2. Reaction of 2,4-Dinitroaniline With Aqueous Sodium Hydroxide, Transactions of the Faraday Society, vol.59, issue.492, pp.2826-2837, 1963. ,
Modelling one-and two-dimensional solid-state NMR spectra. Magnetic Resonance in Chemistry, vol.40, pp.70-76, 2002. ,
Dissolution processes, hydrolysis and condensation reactions during geopolymer synthesis: Part I -Low Si/Al ratio systems, Journal of Materials Science, vol.42, issue.9, pp.2997-3006, 2007. ,
Dissolution processes, hydrolysis and condensation reactions during geopolymer synthesis: Part II. High Si/Al ratio systems, Journal of Materials Science, vol.42, issue.9, pp.3007-3014, 2007. ,
The distribution of aluminum tetrahedra of silicates and aluminates American Mineralogist, vol.39, p.92, 1954. ,
Understanding the relationship between geopolymer composition, microstructure and mechanical properties, Colloids and Surfaces a-Physicochemical and Engineering Aspects, vol.269, issue.1-3, pp.47-58, 2005. ,
Oscillatory silicon and aluminum aqueous concentrations during experimental aluminosilicate weathering, Geochimica Et Cosmochimica Acta, vol.60, issue.15, pp.2901-2907, 1996. ,
The role of mathematical modelling and gel chemistry in advancing geopolymer technology. Chemical Engineering Research & Design, vol.83, pp.853-860, 2005. ,
Mechanisms and kinetics of gel formation in geopolymers, 2007. ,
Alkaline activation of metakaolin -An isothermal conduction calorimetry study, Journal of Thermal Analysis and Calorimetry, vol.52, issue.3, pp.957-965, 1998. ,
Calorimetric study of alkaline activation of calcium hydroxidemetakaolin solid mixtures. Cement and Concrete Research, vol.31, pp.25-30, 2001. ,
Geopolymerization process of alkali-metakaolinite characterized by isothermal calorimetry, Thermochimica Acta, vol.493, issue.1-2, pp.49-54, 2009. ,
Quantitative kinetic and structural analysis of geopolymers. Part 2. Thermodynamics of sodium silicate activation of metakaolin, Thermochimica Acta, vol.565, pp.163-171, 2013. ,
Quantitative kinetic and structural analysis of geopolymers. Part 1. The activation of metakaolin with sodium hydroxide, Thermochimica Acta, vol.539, pp.23-33, 2012. ,
The role played by the reactive alumina content in the alkaline activation of fly ashes, Microporous and Mesoporous Materials, vol.91, issue.1-3, pp.111-119, 2006. ,
Structural Evolution during Geopolymerization from an Early Age to Consolidated Material, Langmuir, vol.28, issue.22, pp.8502-8510, 2012. ,
Rheological behavior of alkali-activated metakaolin during geopolymerization, Journal of Non-Crystalline Solids, vol.357, issue.21, pp.3565-3571, 2011. ,
Caractérisation de la porosité des géopolymères : évolution temporelle et étude de l'eau confinée, 2016. ,
Structural reorganisation of class F fly ash in alkaline silicate solutions, Colloids and Surfaces a-Physicochemical and Engineering Aspects, vol.211, issue.1, pp.49-66, 2002. ,
Effect of temperature and alkaline concentration on metakaolin leaching kinetics, Ceramics International, vol.40, issue.7, pp.8975-8985, 2014. ,
Analytical expression for the spin-5/2 line-intensities. Molecular Physics, vol.78, pp.307-318, 1993. ,
Die rontgenkleinwinkelstreuung von dichtgepakten kolloiden systemen .2. Kolloid-Zeitschrift and Zeitschrift Fur Polymere, vol.125, pp.51-57, 1952. ,
, Diffusion inélastique de neutrons par temps de vol, 2010.
Investigation of activation kinetics in geopolymer paste using quasielastic neutron scattering. Construction and Building Materials, vol.120, pp.181-188, 2016. ,
In situ quasi-elastic neutron scattering study of the hydration of tricalcium silicate, Chemistry of Materials, vol.10, issue.1, pp.397-402, 1998. ,
Dissolution behaviour of source materials for synthesis of geopolymer binders: A kinetic approach, International Journal of Mineral Processing, vol.153, pp.80-86, 2016. ,
Kinetics of geopolymerization: Role of Al2O3 and SiO2. Cement and Concrete Research, vol.37, pp.512-518, 2007. ,
The effect of silica availability on the mechanism of geopolymerisation, vol.41, pp.210-216, 2011. ,
Effect of Alumina Release Rate on the Mechanism of Geopolymer Gel Formation, Chemistry of Materials, vol.22, issue.18, pp.5199-5208, 2010. ,
A surface complex-reaction model for the pH-dependence of corundum and kaolinite dissolution rates, Geochimica Et Cosmochimica Acta, vol.52, issue.11, pp.2609-2623, 1988. ,
Kaolinite and smectite dissolution rate in high molar KOH solutions at 35 degrees and 80 degrees C. Applied Geochemistry, vol.13, pp.905-916, 1998. ,
Kaolinite dissolution at 25-degrees-C, 60-degrees-C, and 80-degrees-C, American Journal of Science, vol.290, issue.7, pp.797-810, 1990. ,
Dissolution of aluminosilicate minerals and by-products in alkaline media, Journal of Materials Science, vol.42, issue.9, pp.2967-2973, 2007. ,
Kinetic study of the dissolution of metakaolin with hydrofluoric acid, Indian Journal of Chemical Technology, vol.25, issue.3, pp.287-293, 2018. ,
Dissolution kinetics of Amazonian metakaolin in nitric acid, vol.64, pp.86-90, 2018. ,
Dissolution kinetics of Amazonian metakaolin in hydrochloric acid, vol.52, pp.75-82, 2017. ,
Dissolution kinetics of metakaolin in sulfuric acid: Comparison between heterogeneous and homogeneous reaction methods, Applied Clay Science, pp.159-162, 2014. ,
An experimental study of illite dissolution kinetics as a function of pH from 1.4 to 12.4 and temperature from 5 to 50 degrees C, Geochimica Et Cosmochimica Acta, vol.67, pp.3583-3594, 2003. ,
Glass dissolution as a function of pH and its implications for understanding mechanisms and future experiments, Geochimica Et Cosmochimica Acta, vol.219, pp.111-123, 2017. ,
An experimental study of the dissolution rates of simulated aluminoborosilicate waste glasses as a function of pH and temperature under dilute conditions, Applied Geochemistry, vol.23, issue.9, pp.2559-2573, 2008. ,
Kinetics of fly ash leaching in strongly alkaline solutions, Journal of Materials Science, vol.46, issue.3, pp.590-597, 2011. ,
Mechanisms of Defense Waste Glass Dissolution AU -Barkatt, Aaron. Nuclear Technology, vol.73, issue.2, pp.140-164, 1986. ,
Tris(trimethylsilyl)methane as an internal C-13 NMR chemical shift thermometer. Magnetic Resonance in Chemistry, vol.36, pp.118-124, 1998. ,
Modelling the formation of geopolymers, 2006. ,
Energy changes when kaolin minerals are heated, Clay Minerals Bulletin, vol.2, issue.13, pp.265-274, 2018. ,
Selected values of chemical thermodynamic properties: tables for the first thirty-four elements in the standard order of arrangement, U.S. Bureau of Standards NBS technical note, vol.270, issue.3, p.p, 1975. ,
Isothermal calorimetry and in-situ XRD study of the NaOH activated fly ash, metakaolin and slag, Cement and Concrete Research, vol.103, pp.110-122, 2018. ,
Molecular mechanisms responsible for the structural changes occurring during geopolymerization: Multiscale simulation, Aiche Journal, vol.58, issue.7, pp.2241-2253, 2012. ,
Mécanisme de prise et rhéologie de liants géopolymères modèles, 2013. ,