Scaling concepts in polymer physics ,
, Handbook of Polymer Synthesis, Characterization, and Processing
, , pp.187-204, 2013.
, Handbook of Polymer Synthesis, Characterization, and Processing
, , pp.105-130, 2013.
Polymer handbook, vol.7, 1989. ,
Free Radical Polymerization, Handbook of Polymer Synthesis, Characterization, and Processing ,
URL : https://hal.archives-ouvertes.fr/hal-00302506
, , pp.65-83, 2013.
Improvement In India-Rubber Fabrics ,
, US3633A, p.1844, 2018.
Sulphur and peroxide vulcanisation of rubber compoundsoverview, Chem Pap, vol.70, issue.12, pp.1533-1555, 2016. ,
Acrylic Polymers, Organic Polymer Chemistry ,
, , 1988.
, , pp.125-173
Materials and compounds, Engineering with rubber: How to design rubber components, p.11, 1992. ,
Crosslinked acrylic pressure-sensitive adhesives. I. Effect of the crosslinking reaction on the peel strength, J Appl Polym Sci, vol.87, issue.9, pp.1493-1502, 2003. ,
Chemical reactions of polymer crosslinking and postcrosslinking at room and medium temperature, Prog Polym Sci, vol.36, issue.2, pp.191-217, 2011. ,
URL : https://hal.archives-ouvertes.fr/hal-00523089
Thiol-enes: Chemistry of the past with promise for the future, J Polym Sci Part Polym Chem, vol.42, issue.21, pp.5301-5339, 2004. ,
Thiol-Ene Click Chemistry, Angew Chem Int Ed, vol.49, issue.9, pp.1540-73, 2010. ,
ATRP of Allyl Methacrylate with Alkyl Methacrylates -Crosslinking of Poly(methacrylate)s with Allyl Ester Side Groups, Macromol Chem Phys, vol.205, issue.18, pp.2429-2466, 2004. ,
A Novel Design Strategy for Fully Physically Linked Double Network Hydrogels with Tough, Fatigue Resistant, and Self-Healing Properties, Adv Funct Mater, vol.25, issue.10, pp.1598-607, 2015. ,
Lamellar Bilayers as Reversible Sacrificial Bonds To Toughen Hydrogel: Hysteresis, Self-Recovery, Fatigue Resistance, and Crack Blunting, Macromolecules, vol.44, issue.22, pp.8916-8940, 2011. ,
Why are double network hydrogels so tough?, Soft Matter, vol.6, issue.12, pp.2583-90, 2010. ,
, 50th Anniversary Perspective: Networks and Gels: Soft but Dynamic and Tough. Macromolecules, vol.50, pp.8297-316, 2017.
Multi-scale multi-mechanism design of tough hydrogels: Building dissipation into stretchy networks, Soft Matter, vol.10, issue.5, pp.672-87, 2014. ,
Hydrogel: Preparation, characterization, and applications: A review, J Adv Res, vol.6, issue.2, pp.105-126, 2015. ,
Soft contact lens polymers: an evolution, Biomaterials, vol.22, issue.24, pp.3273-83, 2001. ,
Hydrogels in drug delivery: Progress and challenges. Polymer, vol.49, pp.1993-2007, 2008. ,
Hydrogels for pharmaceutical and biomedical applications, Crit Rev Ther Drug Carrier Syst, vol.22, issue.2, pp.107-156, 2005. ,
Structure-mechanical property relationship of tough hydrogels, Soft Matter, vol.8, issue.31, pp.8030-8038, 2012. ,
Design and Fabrication of a High-Strength Hydrogel with Ideally Homogeneous Network Structure from Tetrahedronlike Macromonomers, Macromolecules, vol.41, issue.14, pp.5379-84, 2008. ,
Structure Characterization of Tetra-PEG Gel by Small-Angle Neutron Scattering. Macromolecules, vol.42, pp.1344-51, 2009. ,
SANS and SLS Studies on Tetra-Arm PEG Gels in As-Prepared and Swollen States, Macromolecules, vol.42, issue.16, pp.6245-52, 2009. ,
Highly Elastic and Deformable Hydrogel Formed from Tetra-arm Polymers, Macromol Rapid Commun, vol.31, issue.22, pp.1954-1963, 2010. ,
Synthetically Simple, Highly Resilient Hydrogels, Biomacromolecules, vol.13, issue.3, pp.584-592, 2012. ,
The Polyrotaxane Gel: A Topological Gel by Figure-of-Eight Cross-links, Adv Mater, vol.13, issue.7, pp.485-492, 2001. ,
Novel Cross-Linking Concept of Polymer Network: Synthesis, Structure, and Properties of Slide-Ring Gels with Freely Movable Junctions, Polym J, vol.39, issue.6, pp.489-99, 2007. ,
Slide-ring materials using topological supramolecular architecture. Curr Opin Solid State Mater Sci, vol.14, pp.28-34, 2010. ,
Studies on double networks in natural rubber vulcanizates, J Appl Polym Sci, vol.91, issue.2, pp.1068-76, 2004. ,
Some physical characteristics of double-networked natural rubber, J Appl Polym Sci, vol.65, issue.5, pp.917-941, 1997. ,
The Mechanical Behavior of Double Network Elastomers, Rubber Chem Technol, vol.67, issue.2, pp.359-65, 1994. ,
Effect of deformation during crosslinking on elastic properties of rubbers, Polym Sci USSR, vol.25, issue.1, pp.204-212, 1983. ,
Elastic properties of networks formed from oriented chain molecules. Part 2.-Composite networks, Trans Faraday Soc, vol.61, pp.2772-2783, 1965. ,
Elastic properties of networks formed from oriented chain molecules. Kolloid-Z Z Fu?r Polym, vol.186, pp.1-15, 1962. ,
Failure Properties of Natural Rubber Double Networks, Rubber Chem Technol, vol.68, issue.1, pp.124-155, 1995. ,
Fatigue crack growth of double-networked natural rubber, Polymer, vol.39, issue.11, pp.2209-2214, 1998. ,
Orientation Effects in Rubber Double Networks, Rubber Chem Technol, vol.63, issue.2, pp.285-97, 1990. ,
Mechanical and Optical Behavior of Double Network Rubbers, Macromolecules, vol.33, issue.11, pp.4132-4139, 2000. ,
Permanent Set of Cross-Linking Networks: Comparison of Theory with Molecular Dynamics Simulations, Macromolecules, vol.39, issue.16, pp.5521-5551, 2006. ,
Molecular Dynamics Simulations of Polymer Networks Undergoing Sequential Cross-Linking and Scission Reactions. Macromolecules, vol.40, pp.131-140, 2007. ,
Entanglement Networks of 1,2-Polybutadiene Cross-Linked in States of Strain. I. Cross-Linking at 0 °, vol.7, p.6, 1974. ,
Entanglement Networks of 1,2-Polybutadiene Cross-Linked in States of Strain. II. Application of the Mooney-Rivlin Equation to Networks Cross-Linked at O°. Macromolecules, vol.8, pp.87-96, 1975. ,
Swelling and elastic anisotropies of an amorphous elastomer crosslinked in the strained state. 1,2-polybutadiene, J Polym Sci Polym Lett Ed, vol.20, issue.6, pp.341-347, 1982. ,
Mechanical and thermo-mechanical studies of double networks based on thermoplastic elastomers, J Polym Sci Part B Polym Phys, vol.48, issue.7, pp.778-89, 2010. ,
A physical and mechanical study of prestressed competitive double network thermoplastic elastomers, Macromolecules, vol.44, issue.6, pp.1480-90, 2011. ,
Preparation and characterization of dual curable adhesives containing epoxy and acrylate functionalities, React Funct Polym, vol.73, issue.4, pp.641-647, 2013. ,
Double-Network Hydrogels with Extremely High Mechanical Strength, Adv Mater, vol.17, issue.14, pp.1155-1163, 2003. ,
Innovative tough elastomers: Designed sacrificial bonds in multiple networks, 2013. ,
URL : https://hal.archives-ouvertes.fr/tel-01362511
Synthesis and Kinetics Study of Vinyl Ester Resin in the Presence of Triethylamine, Iran Polym J, vol.15, issue.11, pp.871-879, 2006. ,
, , vol.20, pp.317-344, 2005.
Kinetics and mechanism of esterification of epoxy resin with methacrylic acid in the presence of tertiary amines, Adv Polym Technol, vol.24, issue.1, pp.1-13, 2005. ,
Kinetic modelling of crosslinking reactions for cycloaliphatic epoxides with hydroxyl-and carboxyl-functionalized acrylic copolymers: 1. pH and temperature effects, Polymer, vol.39, issue.23, pp.5747-59, 1998. ,
Catalytic effects of substituted pyridines and quinolines on the reaction of phenyl glycidyl ether and benzoic acid, J Org Chem, vol.32, issue.8, pp.2405-2414, 1967. ,
Study of Epoxy Compounds. VII. 1,2 Base-Catalyzed Reaction of Substituted Phenyl Glycidyl Ethers with Benzoic Acid, J Org Chem, vol.31, issue.5, pp.1559-64, 1966. ,
Specific features of the kinetics of addition esterification of epoxide with the carboxyl group, Polym Bull, vol.15, issue.3, pp.215-221, 1986. ,
Reaction of glycidyl benzoate with acid in the presence of tertiary amines as the catalyst, Angew Makromol Chem, vol.12, issue.1, pp.157-65, 1970. ,
Kinetics of esterification of cycloaliphatic epoxies with methacrylic acid, J Appl Polym Sci, vol.86, issue.13, pp.3197-204, 2002. ,
Physical properties of polymers handbook ,
, , vol.1076, 2007.
Toughening elastomers with sacrificial bonds and watching them break, Science, vol.344, issue.6180, pp.186-195, 2014. ,
URL : https://hal.archives-ouvertes.fr/hal-01516045
Characterizing Large Strain Elasticity of Brittle Elastomeric Networks by Embedding Them in a Soft Extensible Matrix, Adv Funct Mater, vol.26, issue.15, pp.2482-92, 2016. ,
URL : https://hal.archives-ouvertes.fr/hal-01443797
Mechanics of elastomeric molecular composites, Proc Natl Acad Sci, 2018. ,
URL : https://hal.archives-ouvertes.fr/hal-02074609
, Handbook of Polymer Synthesis, Characterization, and Processing
, , pp.187-204, 2013.
The physics of rubber elasticity, vol.310, 2005. ,
Statistical Mechanics of Cross-Linked Polymer Networks II. Swelling, J Chem Phys, vol.11, issue.11, p.521, 1943. ,
Handbook of Poylmer-Liquid Interaction Parameters and Solubility Parameters. Routledge, vol.794, 2018. ,
, Problems encountered during the thermal second curing
139 3.1. Presentation of the results ,
, 2.1. Modelling the behavior of dual-cured networks, Comparison to Flory's model
Additional mechanical characterization for the thermal system, vol.152 ,
,
Mechanics of elastomeric molecular composites, Proc Natl Acad Sci, 2018. ,
URL : https://hal.archives-ouvertes.fr/hal-02074609
Color stabilization of amines ,
Mechanism of Yellowing: Carbonyl Formation during Hygrothermal Aging in a Common Amine Epoxy. Polymers, vol.10, p.1017, 2018. ,
Cross-link formation in stretched rubber networks, Trans Faraday Soc, vol.52, pp.1137-1151, 1956. ,
Elasticity of polymer networks cross-linked in states of strain, Trans Faraday Soc, vol.56, issue.0, pp.722-765, 1960. ,
The isotropy of Gaussian molecular networks and the stress-birefringence relations for rubberlike materials cross-linked in stressed states, Kolloid-Z, vol.171, issue.1, pp.46-51, 1960. ,
Crosslinking of oriented rubber, J Polym Sci, vol.25, issue.109, pp.151-159, 1957. ,
Anisotropic elasticity of composite molecular networks formed from non-gaussian chains, J Polym Sci A, vol.2, issue.3, pp.1025-1066, 1964. ,
Elastic properties of networks formed from oriented chain molecules. Part 2.-Composite networks, Trans Faraday Soc, vol.61, pp.2772-2783, 1965. ,
Two Network Model for Vulcanizates Crosslinked under Strain, Rubber Chem Technol, vol.40, issue.4, pp.1060-70, 1967. ,
Non-gaussian elasticity of composite and interpenetrating networks. J Polym Sci Part -2 Polym Phys, vol.10, pp.283-93, 1972. ,
On the Anisotropy of Composite Networks, Macromolecules, vol.8, issue.1, pp.89-89, 1975. ,
Physical properties of polymers handbook ,
, , vol.1076, 2007.
171 2. Preparation process and additional characterization tools ,
, 4.1. Principle of the measurement of fracture energy
2.2. Observation of the small strain regimes ,
, 3.2. The reproducibility issue of the thermal system
, 196 4.2.1. Overall presentation and study of small strain regime
, 3.1. Identification of common trends within each formulation group
Mechanics of elastomeric molecular composites, Proc Natl Acad Sci, 2018. ,
URL : https://hal.archives-ouvertes.fr/hal-02074609
A New Constitutive Relation for Rubber, Rubber Chem Technol, vol.69, issue.1, pp.59-61, 1996. ,
Rupture of rubber. X. The change in stored energy on making a small cut in a test piece held in simple extension, J Appl Polym Sci, vol.7, issue.3, pp.993-1002, 1963. ,
Large Strain and Fracture of Multiple Network Elastomers, 2017. ,
URL : https://hal.archives-ouvertes.fr/tel-02138641
Toughening elastomers with sacrificial bonds and watching them break, Science, vol.344, issue.6180, pp.186-195, 2014. ,
URL : https://hal.archives-ouvertes.fr/hal-01516045
Innovative tough elastomers: Designed sacrificial bonds in multiple networks, 2013. ,
URL : https://hal.archives-ouvertes.fr/tel-01362511
Characterizing Large Strain Elasticity of Brittle Elastomeric Networks by Embedding Them in a Soft Extensible Matrix, Adv Funct Mater, vol.26, issue.15, pp.2482-92, 2016. ,
URL : https://hal.archives-ouvertes.fr/hal-01443797
The Strength of Highly Elastic Materials, Proc R Soc Lond Math Phys Eng Sci, vol.300, pp.108-127, 1460. ,
Quantitative Adjustment to the Molecular Energy Parameter in the Lake-Thomas Theory of Polymer Fracture Energy, Macromolecules, 2019. ,
, Apr, vol.9, issue.7, pp.2772-2779
Quantitative detection of damage in soft materials using mechano-fluorescence, 2019. ,
URL : https://hal.archives-ouvertes.fr/tel-02864025
A Mullins softening criterion for general loading conditions, J Mech Phys Solids, vol.60, issue.7, pp.1257-64, 2012. ,
URL : https://hal.archives-ouvertes.fr/hal-02410145
A review on the Mullins effect, Eur Polym J, vol.45, issue.3, pp.601-613, 2009. ,
URL : https://hal.archives-ouvertes.fr/hal-00773015
, Rubber Chem Technol, vol.84, issue.3, pp.402-416, 2011.
Why are double network hydrogels so tough?, Soft Matter, vol.6, issue.12, pp.2583-90, 2010. ,
Lamellar bilayers as reversible sacrificial bonds to toughen hydrogel: Hysteresis, self-recovery, fatigue resistance, and crack blunting, Macromolecules, vol.44, issue.22, pp.8916-8940, 2011. ,
Improvement of Mechanical Strength and Fatigue Resistance of Double Network Hydrogels by Ionic Coordination Interactions, Chem Mater, vol.28, issue.16, pp.5710-5730, 2016. ,
Fatigue of double-network hydrogels, Eng Fract Mech, vol.187, pp.74-93, 2018. ,
247 2. Materials preparation and characterization ,
, 3.2. Specificities of PMMA samples and slippage phenomenon
Results regarding the materials preparation ,
, Effect of the nature of the crosslinker
, Effect of crosslinker content / UV synthesis / BDMA crosslinker
,
Mechanics of elastomeric molecular composites, Proc Natl Acad Sci, 2018. ,
URL : https://hal.archives-ouvertes.fr/hal-02074609
Innovative tough elastomers: Designed sacrificial bonds in multiple networks, 2013. ,
URL : https://hal.archives-ouvertes.fr/tel-01362511
Large Strain and Fracture of Multiple Network Elastomers, 2017. ,
URL : https://hal.archives-ouvertes.fr/tel-02138641
Quantitative detection of damage in soft materials using mechano-fluorescence, 2019. ,
URL : https://hal.archives-ouvertes.fr/tel-02864025
Interpenetrating Polymer Networks and Related Materials ,
, , 1981.
Microdeformation mechanisms in rubber toughened PMMA and PMMA-based copolymers, Eng Fract Mech, vol.73, issue.16, pp.2413-2439, 2006. ,
Influence of Diluent and of Copolymer Composition on the Glass Temperature of a Polymer System, Bull Am Phys Soc, vol.1, p.123, 1956. ,
Physical properties of polymers handbook ,
, , vol.1076, 2007.