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.. .. Polyéthylènes,

. Polyéthylènes-supramoléculaires-fonctionnalisés-thy and . .. Dat,

, Organisation induite par la cristallisation de l'unité supramoléculaire

. .. Modèle,

, Organisation induite par la cristallisation de la chaine, p.95

. Modèle and . .. Dat,

.. .. De-pe-de-faible-masse-molaire, IV. Influence de la structuration sur les propriétés mécaniques

. .. Thy-pe1200-thy,

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. .. Références,

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, Influence de la fraction volumique

. Iii and -. .. Copolymères-multiblocs--pdms-supra,

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.. .. Etude-de-la-morphologie,

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, 11 mmol) a été dissoute dans du DMF (100 mL). La ndodecylamine (1,89 g, 10 mmol), du TBTU (4,54 g, 14 mmol) et de la DIEA (5,2 mL, 30 mmol) sont ensuite ajoutés

, x 30 mL), lavé avec de l'eau (2 x 30 mL), séché avec du sulfate de magnésium, filtré puis séché sous vide une nuit à 120°C. Une poudre blanche est obtenue. Le greffage est total d'après la 1 H RMN. -1662 cm -1 : vibration d'élongation C=O amide

C. Synthèse,

, 10 mmol) a été dissoute dans 80 mL d'un mélange eau/éthanol (50/50 v/v). NaHCO3 (1,01 g, 12 mmol) et du 2-chloro-4,6-diaminotriazine (DAT-Cl, 1,65 g, 11 mmol) sont ajoutés et la suspension obtenue est agitée à 100°C pendant 24 heures. En fin de réaction, le milieu réactionnel est devenu transparent indiquant la réaction du DAT. Le milieu réactionnel est refroidi et le précipité obtenu est filtré

H. Rmn-de-pe1700-dat, TCE/C6D6 363 K)

. Ir-atr-de-pe1700-dat-À-différentes-températures, 3321 cm -1 : vibration d'élongation NH du DAT. -1550 cm -1 : vibrations d'élongation quadrant du cycle triazine. -1366 cm -1 : vibration de déformation C-N aromatique. -814 cm -1 : vibrations d'élongation

, Images en microscopie optique polarisée de DAT-PE1200-DAT à différentes températures obtenues lors du refroidissement de l'échantillon depuis 200°C à 10°C/min (échelle 100 µm)

D. Ir-atr-de and . Températures, 3326 et 3187 cm -1 : vibrations NH et NH2 du DAT. -1557 cm -1 : vibrations d'élongation quadrant du cycle triazine. -1350 cm -1 : vibration de déformation C-N aromatique. -814 cm -1 : vibrations d'élongation

, Modélisation du trou de corrélation de Thy-PE1200-Thy et DAT-PE1200-DAT à 200°C (fThy/DAT = 0,045, N = 43) Paramètres ajustés : Rg = 21,6 Å et ?PE/Thy = 7,2 pour Thy-PE1200-Thy et Rg = 20,5 Å et ?PE/DAT = 7,1 pour DAT-PE1200-DAT

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